Innovation, multi-utility service businesses and sustainable cities: where might be the next breakthrough?

2012 ◽  
Vol 7 (4) ◽  
Author(s):  
R. Villarroel Walker ◽  
M. B. Beck
Keyword(s):  
Food Waste ◽  
Environmental Sustainability ◽  
Flow Analysis ◽  
Nitrogen And Phosphorus ◽  
Policy Interventions ◽  
Social Nature ◽  
Financial Benefits ◽  
Waste Handling ◽  
Service Businesses ◽  
Nitrogen Phosphorus

A Multi-sectoral Systems Analysis (MSA) model has been constructed for exploring and managing cross-sectoral impacts (both synergies and antagonisms) resulting from technology and policy interventions in the design and stewardship of city infrastructures. This MSA is based on Substance Flow Analysis. It accounts for the flows of water, nitrogen, phosphorus, carbon, and energy into, around, and out of the water, energy, food, waste-handling, and forestry sectors of city-watershed systems. Applications of the MSA to two case studies of the Metropolitan Atlanta Area in Georgia, USA, and the Greater London Area, UK, are compared. The impacts and financial benefits are assessed for four candidate technological innovations in the water sector: urine-separating toilets; pyrolysis of sewage sludge; combined food-waste and wastewater conveyance/treatment; and production of algae-based biofuels from sewage. System-wide environmental sustainability is gauged on four accounts, of attaining progressively more ambitious targets of resource savings/recovery in respect of water, energy, and nutrients (both nitrogen- and phosphorus-based). The paper closes by demonstrating how the MSA can provide assistance in framing questions of a more financial and social nature, i.e., those of ‘Who reaps the rewards?’ and ‘Who bears the costs?’ of the various prospective technological changes and (possibly) breakthroughs.

scholarly journals The Role of Biochar in Regulating the Carbon, Phosphorus, and Nitrogen Cycles Exemplified by Soil Systems

2021 ◽  
Vol 13 (10) ◽  
pp. 5612
Author(s):  
Shu-Yuan Pan ◽  
Cheng-Di Dong ◽  
Jenn-Feng Su ◽  
Po-Yen Wang ◽  
Chiu-Wen Chen ◽  
...  
Keyword(s):  
Environmental Sustainability ◽  
Soil Amendment ◽  
Environmental Control ◽  
Current Knowledge ◽  
Soil Environment ◽  
Nitrogen And Phosphorus ◽  
Soil Systems ◽  
P Mineralization ◽  
Rich Material ◽  
Pyrolysis Of Biomass

Biochar is a carbon-rich material prepared from the pyrolysis of biomass under various conditions. Recently, biochar drew great attention due to its promising potential in climate change mitigation, soil amendment, and environmental control. Obviously, biochar can be a beneficial soil amendment in several ways including preventing nutrients loss due to leaching, increasing N and P mineralization, and enabling the microbial mediation of N2O and CO2 emissions. However, there are also conflicting reports on biochar effects, such as water logging and weathering induced change of surface properties that ultimately affects microbial growth and soil fertility. Despite the voluminous reports on soil and biochar properties, few studies have systematically addressed the effects of biochar on the sequestration of carbon, nitrogen, and phosphorus in soils. Information on microbially-mediated transformation of carbon (C), nitrogen (N), and phosphorus (P) species in the soil environment remains relatively uncertain. A systematic documentation of how biochar influences the fate and transport of carbon, phosphorus, and nitrogen in soil is crucial to promoting biochar applications toward environmental sustainability. This report first provides an overview on the adsorption of carbon, phosphorus, and nitrogen species on biochar, particularly in soil systems. Then, the biochar-mediated transformation of organic species, and the transport of carbon, nitrogen, and phosphorus in soil systems are discussed. This review also reports on the weathering process of biochar and implications in the soil environment. Lastly, the current knowledge gaps and priority research directions for the biochar-amended systems in the future are assessed. This review focuses on literatures published in the past decade (2009–2021) on the adsorption, degradation, transport, weathering, and transformation of C, N, and P species in soil systems with respect to biochar applications.

scholarly journals The SN2 reaction and its relationship with the Walden inversion, the Finkelstein and Menshutkin reactions together with theoretical calculations for the Finkelstein reaction

2021 ◽  
Author(s):  
Ibon Alkorta ◽  
José Elguero
Keyword(s):  
Linear Models ◽  
Theoretical Calculations ◽  
Computational Method ◽  
Basis Set ◽  
Free Energies ◽  
Nitrogen And Phosphorus ◽  
Atom Pairs ◽  
Leaving Groups ◽  
First Time ◽  
Nitrogen Phosphorus

AbstractThis communication gives an overview of the relationships between four reactions that although related were not always perceived as such: SN2, Walden, Finkelstein, and Menshutkin. Binary interactions (SN2 & Walden, SN2 & Menshutkin, SN2 & Finkelstein, Walden & Menshutkin, Walden & Finkelstein, Menshutkin & Finkelstein) were reported. Carbon, silicon, nitrogen, and phosphorus as central atoms and fluorides, chlorides, bromides, and iodides as lateral atoms were considered. Theoretical calculations provide Gibbs free energies that were analyzed with linear models to obtain the halide contributions. The M06-2x DFT computational method and the 6-311++G(d,p) basis set have been used for all atoms except for iodine where the effective core potential def2-TZVP basis set was used. Concerning the central atom pairs, carbon/silicon vs. nitrogen/phosphorus, we reported here for the first time that the effect of valence expansion was known for Si but not for P. Concerning the lateral halogen atoms, some empirical models including the interaction between F and I as entering and leaving groups explain the Gibbs free energies.

scholarly journals Food Waste in Da Nang City of Vietnam: Trends, Challenges, and Perspectives toward Sustainable Resource Use

2021 ◽  
Vol 13 (13) ◽  
pp. 7368
Author(s):  
Ngoc-Bao Pham ◽  
Thu-Nga Do ◽  
Van-Quang Tran ◽  
Anh-Duc Trinh ◽  
Chen Liu ◽  
...  
Keyword(s):  
Food Waste ◽  
Environmental Sustainability ◽  
African Swine Fever ◽  
Modern Society ◽  
Critical Issue ◽  
Typical Feature ◽  
City Government ◽  
Willingness To Participate ◽  
Waste Generation ◽  
Pig Feed

Food waste has become a critical issue in modern society, especially in the urbanized and fast-growing cities of Asia. The increase in food waste has serious negative impacts on environmental sustainability, water and land resources, and food security, as well as climate and greenhouse gas emissions. Through a specific case study in Da Nang City, Vietnam, this paper examines the extent of food waste generation at the consumption stages, the eating habits of consumers, food waste from households and service establishments, as well as prospects for the reuse of food waste as pig feed. The results of this study indicate that per capita food waste generation in Da Nang has increased from 0.39 to 0.41kg in 2016, 0.46 in 2017, and reached 0.52kg in 2018. According to the results of our consumer survey, 20% of respondents stated that they often generate food waste, 67% stated they sometimes do, and 13% stated they rarely do. Furthermore, 66% of surveyed households stated that their food waste is collected and transported by pig farmers to be used as feed for pigs. The use of food waste as feed for pigs is a typical feature in Da Nang. The study also found that there is a high level of consumer awareness and willingness to participate in the 3Rs (reduce, reuse, recycle) program, which was being initiated by the city government. In service facilities such as resorts and hotels, daily food waste reached 100–200 kg in large facilities and 20–120 kg in small facilities. This waste was also collected for use in pig farming. However, there has been a fall in demand for pig feed in line with a decrease in the number of pig farms due to the African swine fever epidemic that occurred during the implementation of this study. This paper suggests that there is a strong need to take both consumer-oriented waste prevention and waste management measures, such as waste segregation at source and introduction of effective food waste recycling techniques, to ensure that food waste can be safely and sustainably used as a “valuable resource” rather than “wasted.”

Long-term effect of cropping system and nitrogen and phosphorus fertilizer on production and nitrogen economy of grain crops in a Brown Chernozem

2005 ◽  
Vol 85 (1) ◽  
pp. 81-93 ◽  
Author(s):  
C. A. Campbell ◽  
R. P. Zentner ◽  
F. Selles ◽  
P. G. Jefferson ◽  
B. G. McConkey ◽  
...  
Keyword(s):  
Water Use ◽  
Environmental Sustainability ◽  
Crop Production ◽  
N Uptake ◽  
Yield Response ◽  
Average Response ◽  
Nitrogen And Phosphorus ◽  
N Yield ◽  
P Fertilizer

Assessment of the long-term impact of fertilizers and other management factors on crop production and environmental sustainability of cropping systems in the semi-arid Canadian prairies is needed. This paper discusses the long-term influence of N and P fertilizers on crop production, N uptake and water use of hard red spring wheat (Triticum aestivum L.), and the effect of the preceding crop type [flax (Linum usitatissimum L.) and fall rye (Secale cereale L.)] on wheat grown on a medium-textured, Orthic Brown Chernozem at Swift Current, Saskatchewan. We analysed 36 yr of results (1967–2002) from eight crop rotation-fertility treatments: viz., fallow-wheat receiving N and P (F-W, N + P), three F-W-W treatments fertilized with (i) N + P, (ii) P only, and (iii) N only; two other 3-yr mixed rotations with N + P (i) F-flax-W (F-Flx-W) and (ii) F-fall rye-W (F-Rye-W); and two continuous wheat rotations (Cont W), one receiving N + P and the other only P. Growing season weather conditions during the 36-yr period were near the long-term mean, but the first 22 yr were generally drier than normal while the last 14 yr (1989–2002) had average to above-average growing conditions. This was partly responsible for grain and N yield being greater in the latter period than in the first 22 yr. The 36-yr average response of wheat grown on fallow to P fertilizer was 339 kg ha-1, while the response to N fertilizer over this period was only 123 kg ha-1. The 36-yr average response of wheat grown on stubble to N was 344 kg ha-1 for F-W-(W) and 393 kg ha-1 for Cont W. Neither flax nor fall rye influenced the yield response of the following wheat crops. Annualized grain production for F-W (N + P), F-W-W (+ N) and F-W-W (+ P) rotations were similar (1130 kg ha-1 yr-1); this was about 15% lower than for F-W-W (N + P), 40% lower than for Cont W (N + P), and 5% lower than for Cont W (+ P). Annualized aboveground N yield for Cont W (N + P) was 57% higher than for Cont W (+ P). Regressions were developed relating straw to grain yields for wheat, flax and fall rye. The amount of NO3-N left in the soil was directly related to amount of N applied and inversely to N removed in the crop. Thus, F-(W)-W (+ N) left about 28% more NO3-N in the rooting zone than F-(W)-W (N + P), while F-W-(W) (N + P) left 20% more than F-W-(W) (+ P), and Cont W (N + P) left 39% more than Cont W (+ P). F-Rye-W (N + P) left much less NO3-N in the soil than any other fallow-containing system and similar amounts to Cont W (N + P). Key words: Yields, grain protein, N and P fertilizer, straw/grain regressions, water use, soil nitrate

Water-Fertilizer Coupling Effects and Efficient Utilization under Peanut-Millet Interplanting Conditions

2013 ◽  
Vol 742 ◽  
pp. 272-277
Author(s):  
Liang Shan Feng ◽  
Zhan Xiang Sun ◽  
Jia Ming Zheng
Keyword(s):  
Soil Moisture ◽  
Moisture Content ◽  
Soil Moisture Content ◽  
Coupling Effect ◽  
Field Capacity ◽  
Nitrogen And Phosphorus ◽  
Application Rates ◽  
Optimal Value ◽  
Factor Interactions ◽  
Nitrogen Phosphorus

In this study, the results showed that water is the most important factor to affect crop yields and optimum soil moisture is lower under the conditions of peanut-and-millet interplanting. Thus, peanut-and-millet interplanting is generally able to fit most of the semi-arid region. In the interaction of various factors, the coupling effect of water and phosphorus was stronger than the coupling effect of fertilizers, following by the coupling effect of water and nitrogen. Among peanuts factors of water, nitrogen, and multi-factorial interaction of water, nitrogen, and phosphorus, water and nitrogen showed a negative effect, whereas the two-factor interactions had a positive effect. There were some differences between peanut and millet in the need for water and fertilizer, in which peanut required more nitrogen and millet needed slightly higher soil moisture and phosphorus. When other factors were in rich level, both of the optimal value for single factors of water, nitrogen, and phosphorus and the optimal value for two-factor interactions of water-nitrogen, water-phosphorus, and nitrogen-phosphorus, were higher than the optimal value for the interaction of water, nitrogen, and phosphorus. The tiny demand difference on moisture in peanut-millet interplanting could be compromised by configuring a reasonable interplanting population structure and the corresponding demand difference on fertilizer could be resolved by uneven crop planting strips. Under the condition of water-nitrogen-phosphorus interaction, the soil moisture content optimal for peanut accounted for 57.3% of the field capacity, and the related appropriate application rates of nitrogen and phosphorus were 0.98 g/pot (81.18 kg/hm2) and 0.39g/pot (32.18 kg/hm2), respectively. Likewise, the soil moisture content optimal for millet was 59.1% of the field capacity, and the counterpart appropriate application rates of nitrogen and phosphorus were 0.57 g/pot (47.03 kg/hm2) and 0.45g / pot (37.13 kg/hm2), respectively.

Distribution of Biomass, Nitrogen, Phosphorus and Other Nutrients in Banksia marginata and B. ornata Shoots of Different Ages After Fire.

1986 ◽  
Vol 34 (6) ◽  
pp. 709 ◽  
Author(s):  
RH Groves ◽  
PJ Hocking ◽  
A Mcmahon
Keyword(s):  
National Park ◽  
Dry Matter ◽  
Lateral Roots ◽  
South Australia ◽  
Distribution Patterns ◽  
Nutrient Accumulation ◽  
Nitrogen And Phosphorus ◽  
Vegetative Organs ◽  
Western Victoria ◽  
Nitrogen Phosphorus

The heathland form of Banksia marginata Cav. regenerates rarely from seed but commonly by resprout- ing from buds on lateral roots, whereas Banksia ornata F. Muell. regenerates only from seed, usually released after fire. The two species co-occur in heath vegetation on nutrient-poor soils in south-eastern South Australia and western Victoria. Shoots were sampled from stands of B. marginata aged from 1 to 25 years and of B. ornata aged from 1 to 50+ years after fire in the Little Desert National Park, western Victoria. B. marginata, the resprouter, distributed a greater proportion of the total shoot dry matter and content of all nutrients to vegetative growth over its shorter life span than B. ornata, the non-sprouter. About 50% of the total phosphorus in B. ornata shoots at 50+ years was present in cones (including seeds) compared with only about 20% in B. marginata shoots at a comparable stage of senescence (25 years). This difference between the species was also true to a lesser degree for nitrogen. There were considerable differences between other nutrients in their distribution patterns in shoots. Nutrients could be grouped together on the basis of distribution in shoots more satisfactorily than on presumed physio- logical roles. Stems were major sites of nutrient accumulation in both species. The content of a particular nutrient in seeds as a proportion of the content in the living parts of the shoot ranged from 0.03% (Na, Mn) to 2.0% (P) in B. marginata, and from 0.3% (Na) to as high as 31% (P) in B. ornata. Concen- trations of all nutrients except sodium were much higher in seeds than in the woody cones or vegetative organs of both species; seeds of B. ornata were particularly rich in calcium and manganese. We conclude that the different patterns of distribution of biomass and nutrients, especially nitrogen and phosphorus, within shoots of the two species reflect their different regenerative modes after fire. Introduction Phosphorus and, to a lesser extent, nitrogen limit the growth of sclerophyllous shrubs on nutrient-poor soils in southern Australia

scholarly journals Effect of Intercropping and Fertility Levels on the Nitrogen, Phosphorus and Potash Content and Uptake by Summer Pearlmillet (Pennisetum glaucum L.) under South Gujarat Condition

2021 ◽  
Vol 9 (3) ◽  
pp. 174-179
Author(s):  
K. R. Patel ◽  
Keyword(s):  
Pearl Millet ◽  
Phosphorus Content ◽  
Pennisetum Glaucum ◽  
P Uptake ◽  
Green Gram ◽  
Treatment Combination ◽  
K Uptake ◽  
Nitrogen And Phosphorus ◽  
College Of Agriculture ◽  
Nitrogen Phosphorus

A field experiment was conducted at College Agronomy Farm, N. M. College of Agriculture, Navsari Agricultural University, Navsari during summer, 2019 and 2020 comprising four intercropping treatments i.e. pearlmillet sole, pearlmillet+greengram, pearlmillet+cowpea, pearlmillet+clusterbean and three fertility levels viz., 75 % RDF, 100 % RDF and 125 % RDF. Among the different intercropping system examined, sole pearl millet (I1) accumulated significantly less content of N and P in pearl millet grain and straw as compared to intercropping with pulses treatments. Pearl millet + green gram (I2) recorded significantly higher N and P uptake by pearl millet straw than other intercropping systems. The sole pearl millet (I1) was at par with pearl millet intercropped with green gram (I2) had significantly higher K content and uptake in pearl millet grain and straw. In case of fertility levels, nitrogen and phosphorus content and uptake in pearl millet grain and straw were recorded significantly higher by application of 100 % RDF. Significantly higher N, P and K uptake by pearl millet grain and straw in pooled results were produced by treatment combination of pearl millet + green gram (I2) intercropping along with 75 % RDF (F1).

scholarly journals Laboratory study on the effects of nutrient enrichment on a phytoplankton population in Sawa Lake, Iraq

2008 ◽  
Vol 5 (2) ◽  
pp. 230-236 ◽  
Author(s):  
Baghdad Science Journal
Keyword(s):  
Population Dynamics ◽  
Lake Water ◽  
Nutrient Enrichment ◽  
Cell Number ◽  
Shannon Index ◽  
Nitrogen And Phosphorus ◽  
Phytoplankton Population ◽  
Phytoplankton Cell ◽  
Nitrogen Phosphorus ◽  
Index Of Diversity

Nutrient enrichment of Sawa lake water was made using different nitrogen and phosphorus concentrations during autumn and spring at three stations. Different concentrations of nitrogen, phosphorus and N: P ratios were used to test variations in phytoplankton population dynamics. Nitrogen at a concentration of 25 µmole.l-1 and N: P ratio of 10:1 gave highest phytoplankton cell number at all stations and seasons. A total of 64 algal taxa dominated by Bacillariophyceae followed by Cyanophyceae and Chlorophyceae were identified. The values of Shannon index of diversity were more than one in the studied stations.

Interactive Effects of Nutrient Availability and Light Levels on the Periphyton Composition of a Large Oligotrophic Lake

1993 ◽  
Vol 50 (6) ◽  
pp. 1270-1278 ◽  
Author(s):  
Jane Claire Marks ◽  
Rex L. Lowe
Keyword(s):  
Interactive Effect ◽  
Oligotrophic Lake ◽  
Interactive Effects ◽  
Nitrogen And Phosphorus ◽  
Phosphorus Enrichment ◽  
Blue Green Algae ◽  
Nitzschia Palea ◽  
Nitrogen Levels ◽  
Light Levels ◽  
Nitrogen Phosphorus

We investigated the effects of nitrogen, phosphorus, and light on periphyton in a clear oligotrophic lake. Experimental treatments consisted of three levels each of nitrogen, phosphorus, and light in a three-way factorial design. Nitrogen and phosphorus concentrations were manipulated using nutrient-diffusing clay substrates; light levels were manipulated with shade cloth. Periphyton biovolume and cell densities increased significantly with both nitrogen and phosphorus enrichment but were not affected by shading. Phosphorus enrichment increased periphyton accumulation only when nitrogen levels were high, indicating a significant interactive effect between nitrogen and phosphorus. Differences in species composition among treatments were mostly due to changes in the diatoms Nitzschia palea and Rhopalodia gibba. Ambient and phosphorus-enriched substrates were dominated by R. gibba, which contains a nitrogen-fixing endosymbiont, and blue-green algae. Nitrogen enrichment and nitrogen and phosphorus in combination resulted in an assemblage dominated by N. palea. Unshaded and highly shaded substrates were dominated by N. palea and Achnanthes minutissima, but the medium-shade substrates were dominated by R. gibba.

Kinetic modelling of microalgal growth and fucoxanthin synthesis in photobioreactor

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Xiaojuan Zhang ◽  
Junru Zhao ◽  
Jie Zhang ◽  
Shijing Su ◽  
Luqiang Huang ◽  
...  
Keyword(s):  
Experimental Data ◽  
Mathematical Model ◽  
Kinetic Parameters ◽  
Kinetic Modelling ◽  
Inhibitory Effect ◽  
Rate Equations ◽  
Phosphorus Concentration ◽  
Model Output ◽  
Nitrogen And Phosphorus ◽  
Nitrogen Phosphorus

Abstract This paper presented a mathematical model to describe the production of fucoxanthin by alga Thalassiosira weissflogi ND-8 in photobioreactor. Our interest was focused on characterizing the effects of nitrogen and phosphorus on the growth of microalgae and on the synthesis of fucoxanthin. The rate equations of microalgal growth, fucoxanthin synthesis and substrate consumptions were formulated. Kinetic parameters of the model and their sensitivities with respect to model output were estimated. The predicted results were compared with experimental data, which showed that this model closely agrees with actual experiment and is able to reflect the growth and metabolism characteristics of microalgae. Our results also indicated that nitrogen plays a major role in the synthesis of fucoxanthin, and the synthesis of fucoxanthin is partially linearly related to the consumption of nitrogen. Phosphorus is primarily consumed in the growth and metabolism of microalgal cells, while excessive phosphorus concentration has an inhibitory effect on the growth of microalgae.

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