Arsenic speciation in the Riotinto Mining area (SW Spain) during a hydrological year

2011 ◽  
Vol 6 (1) ◽  
Author(s):  
J.A. Grande ◽  
M.L. de la Torre ◽  
J.C. Ceron ◽  
D. Sanchez-Rodas ◽  
R. Beltran
Keyword(s):  
Mine Drainage ◽  
Arsenic Speciation ◽  
Statistical Treatment ◽  
Arsenic Species ◽  
Mining Area ◽  
Iberian Pyrite Belt ◽  
Daily Basis ◽  
Mean Values ◽  
Tinto River ◽  
High Concentrations

An arsenic speciation study has been performed in the headwaters of the Tinto River, representing an environment heavily polluted in Acid Mine Drainage originated by the Iberian Pyrite Belt. The variables considered in this study were arsenic species, pH, redox potential, conductivity, temperature, rainfall and concentrations of metals such as Fe, Cu and Zn. The results obtained from the classical statistical treatment confirm the extreme acidity and high concentrations of metals, sulfates and arsenic species (mean values of 2.3 for pH, 1.10 mg L−1 for Cd, 325.4 mg L−1 for Cu, 1241.1 mg L−1 for Fe, 241.2 mg L−1 for Zn, 91.1 mg L−1 for Mn, 0.1 mg L−1 for As(III) and 0.3 mg L−1 for As(V), 5000 mg L−1 of sulfate). Additionally, the speciation of arsenic showed As(V) concentrations always twice or thrice higher than As(III). This distribution of arsenic species was followed along the whole hydrological year, on a daily basis. An increment of the mean concentrations and variability of the arsenic species concentration was also observed in relation to temperature increase during the Spring time.

Dissolved and particulate metals and arsenic species mobility along a stream affected by Acid Mine Drainage in the Iberian Pyrite Belt (SW Spain)

2012 ◽  
Vol 27 (10) ◽  
pp. 1944-1952 ◽  
Author(s):  
Aguasanta M. Sarmiento ◽  
Manuel A. Caraballo ◽  
Daniel Sanchez-Rodas ◽  
José Miguel Nieto ◽  
Annika Parviainen
Keyword(s):  
Acid Mine Drainage ◽  
Mine Drainage ◽  
Arsenic Species ◽  
Iberian Pyrite Belt ◽  
Sw Spain ◽  
Acid Mine ◽  
Particulate Metals ◽  
Species Mobility

Diel cycles of arsenic speciation due to photooxidation in acid mine drainage from the Iberian Pyrite Belt (Sw Spain)

Chemosphere ◽  
2007 ◽  
Vol 66 (4) ◽  
pp. 677-683 ◽  
Author(s):  
Aguasanta M. Sarmiento ◽  
Vanessa Oliveira ◽  
José Luis Gómez-Ariza ◽  
José Miguel Nieto ◽  
Daniel Sánchez-Rodas
Keyword(s):  
Acid Mine Drainage ◽  
Mine Drainage ◽  
Arsenic Speciation ◽  
Iberian Pyrite Belt ◽  
Sw Spain ◽  
Acid Mine ◽  
Diel Cycles

scholarly journals Acid mine drainage in semi-arid regions: the extent of the problem in the waters of reservoirs in the Iberian Pyrite Belt (SW Spain)

2013 ◽  
Vol 46 (1) ◽  
pp. 156-167 ◽  
Author(s):  
M. Santisteban ◽  
J. A. Grande ◽  
M. L. de la Torre ◽  
T. Valente ◽  
J. C. Cerón
Keyword(s):  
Acid Mine Drainage ◽  
Mine Drainage ◽  
Chemical Characterization ◽  
Iberian Pyrite Belt ◽  
Climatic Conditions ◽  
Sw Spain ◽  
Acid Mine ◽  
General Functioning ◽  
High Concentrations ◽  
Semi Arid

There are many reservoirs in the Iberian Pyrite Belt (IPB), SW Spain, which receive contributions from watercourses affected by acid mine drainage processes, characterised by low pH values and high concentrations of heavy metals and sulphates. When they reach the reservoirs, the waters increase its pH, which will cause most of the metal load carried by the mining channel to precipitate into the reservoir itself and accumulate on its floor. The silting of reservoirs is an environmental problem which can affect the loss of storage capacity, their general functioning and aquatic ecosystems. A study of these is vital to allow both preventative and corrective measures to be established. Climatic conditions are the most significant external controlling factors in terms of the degree and type of mining pollution. The study area presents characteristics typical of the semi-arid Mediterranean climate, with annual precipitation of around 630 mm/year; moderate temperatures with average annual values of 17.1 °C and a temperature range of 50 °C. The aim of this study is to carry out a physical–chemical characterization of the waters where they enter the reservoirs located in the IPB over the course of a hydrological year and to establish possible interdependencies between the various parameters.

scholarly journals Hydrochemical characterization and evaluation of the impact of AMD processes on river basin areas in the Iberian Pyrite Belt

Water Policy ◽  
2017 ◽  
Vol 20 (1) ◽  
pp. 146-157 ◽  
Author(s):  
J. A. Grande ◽  
M. L. de la Torre ◽  
M. Santisteban ◽  
J. C. Fortes
Keyword(s):  
River Basin ◽  
Mine Drainage ◽  
Iberian Pyrite Belt ◽  
Mining Activity ◽  
Ph Values ◽  
South West ◽  
High Concentrations ◽  
Definition Of ◽  
The Impact ◽  
Hydrographic Network

Abstract The hydrographic network in the Iberian Pyrite Belt (IPB) (south-west Europe) is intensively affected by acid mine drainage (AMD) processes. This represents a unique worldwide scenario of extractive mining activity for more than 4,000 years. In order to be able to achieve possible restorations, it is necessary to reduce the scale of possible actions for future environmental improvements, at the river basin level. Therefore, the delineation of watersheds and subwatersheds in the IPB has been carried out, as well as the definition of the degree of impact by AMD processes in these basins in the dry season and in the rainy season. The results show that all basins are affected by AMD processes during the entire hydrological year, with pH values between 2 and 3, for most cases, and high concentrations of sulfates, metals and arsenic.

scholarly journals Arsenic Retention on Technosols Prepared with Nanoparticles and Ferric Soil from Mine Drainage Water

2018 ◽  
Vol 2018 ◽  
pp. 1-8 ◽  
Author(s):  
Darío R. Bolaños-Guerrón ◽  
Viviana P. Sánchez-Gómez ◽  
Johanna Paz ◽  
Andrés R. Izquierdo ◽  
Carina Stael ◽  
...  
Keyword(s):  
Iron Nanoparticles ◽  
Mine Drainage ◽  
Orange Peel ◽  
Mining Area ◽  
Drainage Water ◽  
Contaminated Water ◽  
Gold Mines ◽  
Southern Ecuador ◽  
High Concentrations ◽  
Arsenic Retention

Mining activities generate a large amount of solid waste and acid drains that contain heavy metals in high concentrations. In wastewater of gold mines from Southern Ecuador (Portovelo), arsenic concentrations between 4.8 and 27.5 μg/L have been detected. In this context, the objective of this study is to prepare a technosol, which was used in the capture of arsenic dissolved in the acid drains. Technosol was elaborated using a clay-silty soil (iron-rich soil), collected in the mining area, and iron nanoparticles synthetized with the extract of orange peel. The technosol was experimentally characterized using adsorption isotherms and uptake kinetics. Besides, a mathematical model was developed using Vensim® to scale the process and predict the dynamic behavior of the adsorbent. Results indicate that adsorption behavior of technosol can be fitted to Langmuir isotherms (R2 > 0.9), with 95% of adsorption of As from an input of 4.5 mg/L. The model will be useful to predict the time needed to remedy contaminated water and the duration of the adsorbent (until its saturation).

scholarly journals Spatial Variation of Water Chemistry in Aries River Catchment Western Romania

2021 ◽  
Vol 11 (14) ◽  
pp. 6592
Author(s):  
Ana Moldovan ◽  
Maria-Alexandra Hoaghia ◽  
Anamaria Iulia Török ◽  
Marius Roman ◽  
Ionut Cornel Mirea ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Water Quality ◽  
Water Chemistry ◽  
Water Samples ◽  
Mine Drainage ◽  
Pollution Indices ◽  
Mining Activities ◽  
River Catchment ◽  
High Concentrations ◽  
The Impact

This study aims to investigate the quality and vulnerability of surface water (Aries River catchment) in order to identify the impact of past mining activities. For this purpose, the pollution and water quality indices, Piper and Durov plots, as well vulnerability modeling maps were used. The obtained results indicate that the water samples were contaminated with As, Fe, Mn, Pb and have relatively high concentrations of SO42−, HCO3−, TDS, Ca, K, Mg and high values for the electrical conductivity. Possible sources of the high content of chemicals could be the natural processes or the inputs of the mine drainage. Generally, according to the pollution indices, which were correlated to high concentrations of heavy metals, especially with Pb, Fe and Mn, the water samples were characterized by heavy metals pollution. The water quality index classified the studied water samples into five different classes of quality, namely: unsuitable for drinking, poor, medium, good and excellent quality. Similarly, medium, high and very high vulnerability classes were observed. The Durov and Piper plots classified the waters into Mg-HCO3− and Ca-Cl− types. The past and present mining activities clearly change the water chemistry and alter the quality of the Aries River, with the water requiring specific treatments before use.

scholarly journals Bioactive Compounds in Salicornia patula Duval-Jouve: A Mediterranean Edible Euhalophyte

Foods ◽  
2021 ◽  
Vol 10 (2) ◽  
pp. 410
Author(s):  
Irene Sánchez-Gavilán ◽  
Esteban Ramírez ◽  
Vicenta de la Fuente
Keyword(s):  
Fatty Acids ◽  
Bioactive Compounds ◽  
Mediterranean Area ◽  
Biological Properties ◽  
Total Phenolic ◽  
Tinto River ◽  
New Findings ◽  
High Concentrations ◽  
Salicornia Patula ◽  
First Time

Many halophytes have great nutritional and functional potential, providing chemical compounds with biological properties. Salicornia patula Duval-Jouve is a common euhalophyte from saline Mediterranean territories (Spain, Portugal, France, and Italy). In the present work we quantified for the first time the bioactive compounds in S. patula (total phenolic compounds and fatty acids), from Iberian Peninsula localities: littoral-coastal Tinto River basin areas (southwest Spain, the Huelva province), and mainland continental territories (northwest and central Spain, the Valladolid and Madrid provinces). Five phenolic acids including caffeic, coumaric, veratric, salicylic, and transcinnamic have been found with differences between mainland and coastal saltmarshes. S. patula contain four flavonoids: quercetin-3-O-rutinoside, kaempferol/luteolin, apigenin 7-glucoside, and pelargonidin-3-O-rutinoside. These last two glycosylated compounds are described for the first time in this genus of Chenopodiaceae. The fatty acid profile described in S. patula stems contains palmitic, oleic, and linoleic acids in high concentrations, while stearic and long-chain fatty acids were detected in low amounts. These new findings confirm that S. patula is a valuable source of bioactive compounds from Mediterranean area.

Arsenic speciation in rice consumed in south-western Nigeria, and estimation of dietary intake of arsenic species through rice consumption

2017 ◽  
Vol 99 (5-6) ◽  
pp. 999-1006 ◽  
Author(s):  
Joseph A. Adeyemi ◽  
Chris O. Adedire ◽  
Airton da Cunha Martins-Junior ◽  
Ana Carolina Paulelli ◽  
Akinsola F. Awopetu ◽  
...  
Keyword(s):  
Dietary Intake ◽  
Arsenic Speciation ◽  
Arsenic Species ◽  
Rice Consumption

scholarly journals Indium and selenium distribution in the Neves-Corvo deposit, Iberian Pyrite Belt, Portugal

2018 ◽  
Vol 82 (S1) ◽  
pp. S5-S41 ◽  
Author(s):  
J. R. S. Carvalho ◽  
J. M. R. S. Relvas ◽  
A. M. M. Pinto ◽  
M. Frenzel ◽  
J. Krause ◽  
...  
Keyword(s):  
Massive Sulfide ◽  
Iberian Pyrite Belt ◽  
Sulfide Deposit ◽  
Massive Sulfide Deposit ◽  
Actual Distribution ◽  
Shear Structures ◽  
Ore Minerals ◽  
High Concentrations ◽  
Ore Types ◽  
Zinc Concentrate

ABSTRACTHigh concentrations of indium (In) and selenium (Se) have been reported in the Neves-Corvo volcanic-hosted massive sulfide deposit, Portugal. The distribution of these ore metals in the deposit is complex as a result of the combined effects of early ore-forming processes and late tectonometamorphic remobilization. The In and Se contents are higher in Cu-rich ore types, and lower in Zn-rich ore types. At the deposit scale, both In and Se correlate positively with Cu, whereas their correlations with Zn are close to zero. This argues for a genetic connection between Cu, In and Se in terms of metal sourcing and precipitation. However, re-distribution and re-concentration of In and Se associated with tectonometamorphic deformation are also processes of major importance for the actual distribution of these metals throughout the whole deposit. Although minor roquesite and other In-bearing phases were recognized, it is clear that most In within the deposit is found incorporated within sphalerite and chalcopyrite. When chalcopyrite and sphalerite coexist, the In content in sphalerite (avg. 1400 ppm) is, on average, 2–3 times higher than in chalcopyrite (avg. 660 ppm). The In content in stannite (avg. 1.3 wt.%) is even higher than in sphalerite, but the overall abundance of stannite is subordinate to either sphalerite or chalcopyrite. Selenium is dispersed widely between many different ore minerals, but galena is the main Se-carrier. On average, the Se content in galena is ~50 times greater than in either chalcopyrite (avg. 610 ppm) or sphalerite (avg. 590 ppm). The copper concentrate produced at Neves-Corvo contains very significant In (+Se) content, well above economic values if the copper smelters recovered it. Moreover, the high In content of sphalerite from some Cu-Zn ores, or associated with shear structures, could possibly justify, in the future, a selective exploitation strategy for the production of an In-rich zinc concentrate.

scholarly journals Metal Removal from Acid Waters by an Endemic Microalga from the Atacama Desert for Water Recovery

Minerals ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 378 ◽  
Author(s):  
Marcela Martínez ◽  
Yanett Leyton ◽  
Luis Cisternas ◽  
Carlos Riquelme
Keyword(s):  
Mine Drainage ◽  
Metal Removal ◽  
Atacama Desert ◽  
Mining Industry ◽  
Mining Activity ◽  
Water Recovery ◽  
Metallic Ions ◽  
Mineral Extraction ◽  
High Concentrations ◽  
Acid Waters

The environmental problems generated by waste from the mining industry in the mineral extraction for business purposes are known worldwide. The aim of this work is to evaluate the microalga Muriellopsis sp. as a potential remover of metallic ions such as copper (Cu2+), zinc (Zn2+) and iron (Fe2+), pollutants of acid mine drainage (AMD) type waters. For this, the removal of these ions was verified in artificial acid waters with high concentrations of the ions under examination. Furthermore, the removal was evaluated in waters obtained from areas contaminated by mining waste. The results showed that Muriellopsis sp. removed metals in waters with high concentrations after 4–12 h and showed tolerance to pH between 3 and 5. These results allow proposing this species as a potential bioremediator for areas contaminated by mining activity. In this work, some potential alternatives for application in damaged areas are proposed as a decontamination plan and future prevention.

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