scholarly journals Removal of estrogens and estrogenicity through drinking water treatment

2011 ◽  
Vol 10 (1) ◽  
pp. 43-55 ◽  
Author(s):  
Kathleen Schenck ◽  
Laura Rosenblum ◽  
Thomas E. Wiese ◽  
Larry Wymer ◽  
Nicholas Dugan ◽  
...  
Keyword(s):  
Drinking Water ◽  
Water Treatment ◽  
Estrogenic Activity ◽  
Drinking Water Treatment ◽  
Human Cell Line ◽  
Ohio River ◽  
Before And After ◽  
Proliferation Assays ◽  
By Products

Estrogenic compounds have been shown to be present in surface waters, leading to concerns over their possible presence in finished drinking waters. In this work, two in vitro human cell line bioassays for estrogenicity were used to evaluate the removal of estrogens through conventional drinking water treatment using a natural water. Bench-scale studies utilizing chlorine, alum coagulation, ferric chloride coagulation, and powdered activated carbon (PAC) were conducted using Ohio River water spiked with three estrogens, 17β-estradiol, 17α-ethynylestradiol, and estriol. Treatment of the estrogens with chlorine, either alone or with coagulant, resulted in approximately 98% reductions in the concentrations of the parent estrogens, accompanied by formation of by-products. The MVLN reporter gene and MCF-7 cell proliferation assays were used to characterize the estrogenic activity of the water before and after treatment. The observed estrogenic activities of the chlorinated samples showed that estrogenicity of the water was reduced commensurate with removal of the parent estrogen. Therefore, the estrogen chlorination by-products did not contribute appreciably to the estrogenic activity of the water. Coagulation alone did not result in significant removals of the estrogens. However, addition of PAC, at a typical drinking water plant dose, resulted in removals ranging from approximately 20 to 80%.

Characterization of organic matter and disinfection by-products in membrane backwash water from drinking water treatment

2009 ◽  
Vol 168 (2-3) ◽  
pp. 753-759 ◽  
Author(s):  
Lingling Zhang ◽  
Ping Gu ◽  
Zijie Zhong ◽  
Dong Yang ◽  
Wenjie He ◽  
...  
Keyword(s):  
Drinking Water ◽  
Organic Matter ◽  
Water Treatment ◽  
Drinking Water Treatment ◽  
By Products

New chlorinated amphetamine-type-stimulants disinfection-by-products formed during drinking water treatment

2012 ◽  
Vol 46 (10) ◽  
pp. 3304-3314 ◽  
Author(s):  
Maria Huerta-Fontela ◽  
Oriol Pineda ◽  
Francesc Ventura ◽  
Maria Teresa Galceran
Keyword(s):  
Drinking Water ◽  
Water Treatment ◽  
Drinking Water Treatment ◽  
By Products

Effects of ion exchange resin pre-treatment on GAC adsorption

2008 ◽  
Vol 8 (2) ◽  
pp. 181-187
Author(s):  
B. Sani ◽  
L. Rossi ◽  
C. Lubello ◽  
S. Zacchei
Keyword(s):  
Drinking Water ◽  
Water Treatment ◽  
Ion Exchange ◽  
Drinking Water Treatment ◽  
Life Time ◽  
Ion Exchange Resins ◽  
Dissolved Organics ◽  
Pre Treatment ◽  
Exchange Resins ◽  
By Products

In Italian drinking water treatment plants (DWTP), the problem of chlorination by-products control is very important as the Italian drinking water regulations (Dlgs. 31/2001, as enactment of the CEU directive 98/83) set very strict limits for these compounds. A possible strategy for controlling the concentrations of DBPs (disinfection by-products) is the application of treatment processes able to reduce the concentration of dissolved organic matter, the main precursor of DBPs, before the dosage of chlorine-based disinfectants. Recently, ion exchange resins for the removal of dissolved organics have shown several applications in drinking water treatment. In this experimental study, the treatment with ion exchange resins MIEX®DOC and the treatment with GAC (granular activated carbon) were evaluated for the removal of dissolved organics. Moreover, the effects of MIEX® pre-treatment on the subsequent GAC filtration phase were evaluated, with particular attention to the effects on the life-time of the GAC filter. The GAC filter operation was simulated by rapid small scale column tests (RSSCT), which allow the evaluation of the GAC breakthrough curve in a shorter time with respect to a full plant and pilot plant trials. On the basis of the experimental results, the ion exchange process was very efficient in dissolved organics removal (60–70% UV254 removal). Moreover, the results indicated that the application of ion exchange resins as pre-treatment in a conventional drinking water treatment train could increase the filter life-time in the subsequent GAC adsorption phase (about 200%) resulting in potentially important cost benefits for the overall treatment process.

Progress on Drinking Water Treatment with Chlorine Dioxide

2013 ◽  
Vol 848 ◽  
pp. 255-258 ◽  
Author(s):  
Yu Zhong Guo ◽  
Yan Zhen Yu ◽  
Ming Li ◽  
Guang Yong Yan
Keyword(s):  
Drinking Water ◽  
Water Treatment ◽  
Chlorine Dioxide ◽  
Drinking Water Treatment ◽  
Water Disinfection ◽  
Water Quality Standards ◽  
Water Pretreatment ◽  
Detection Technology ◽  
Filter Water ◽  
By Products

By the reason of strong responses activity and oxidation ability, Chlorine dioxide as oxidant and disinfectant has been applied to peroxidation and disinfection more and more widely.In this paper, it give an account of the preparation of chlorine dioxide, as oxidants to raw water pretreatment, used in filter water disinfection ,the detection technology of chlorine dioxide and disinfection by-products, the water quality standards formulated by domestic and overseas chlorine dioxide in using chlorine dioxide, and summarized progress on drinking water treatment with chlorine dioxide .

Oxidation of odorous and nonodorous algal metabolites by permanganate, chlorine, and chlorine dioxide

1995 ◽  
Vol 31 (11) ◽  
pp. 223-228 ◽  
Author(s):  
A. M. Dietrich ◽  
R. C. Hoehn ◽  
L. C. Dufresne ◽  
L. W. Buffin ◽  
D. M. C. Rashash ◽  
...  
Keyword(s):  
Drinking Water ◽  
Water Treatment ◽  
Chlorine Dioxide ◽  
Profile Analysis ◽  
Drinking Water Treatment ◽  
Phenethyl Alcohol ◽  
Before And After ◽  
Flavor Profile Analysis ◽  
Palmitic Acids ◽  
Flavor Profile

The six algal metabolites, at concentrations of 20-225 μg/l, were oxidized with potassium permanganate, chlorine, or chlorine dioxide at doses of 0.25-3 mg/l. Flavor profile analysis (FPA) was used to determine the odors of the solutions before and after oxidation. Linoleic and palmitic acids, which are odorless compounds, were oxidized to odorous products by all three oxidants. The odor intensity of β-cyclocitral (grape, sweet tobacco) and phenethyl alcohol (rose, floral) was only slightly decreased by any of the oxidants. Oxidation by permanganate or chlorine either eliminated or greatly reduced the odors associated with linolenic acid (watermelon) and 2t,6c-nonadienal (cucumber); chlorine dioxide was ineffective at reducing the cucumber odor of 2t,6c-nonadienal. Oxidation, at doses typically applied for drinking water treatment, can result in the destruction of certain algae-related odors but in the formation of other odors.

Speciation and seasonal variation of various disinfection by-products in a full-scale drinking water treatment plant in East China

2019 ◽  
Vol 19 (6) ◽  
pp. 1579-1586 ◽  
Author(s):  
Xiang-Ren Zhou ◽  
Yi-Li Lin ◽  
Tian-Yang Zhang ◽  
Bin Xu ◽  
Wen-Hai Chu ◽  
...  
Keyword(s):  
Drinking Water ◽  
Water Treatment ◽  
Treatment Plant ◽  
Drinking Water Treatment ◽  
Water Treatment Plant ◽  
Full Scale ◽  
East China ◽  
Raw Water ◽  
Drinking Water Treatment Plant ◽  
By Products

Abstract The objective of this research was to study the occurrence and seasonal variations of disinfection by-products (DBPs), including traditional carbonaceous and emerging nitrogenous DBPs, in a full-scale drinking water treatment plant (DWTP) for nearly 2 years. The removal efficiencies of each DBP through the treatment processes were also investigated. This DWTP takes raw water from the Yangtze River in East China. The quality of the raw water used in this DWTP varied with different seasons. The results suggested that DBP concentrations of the finished water were higher in spring (82.33 ± 15.12 μg/L) and summer (117.29 ± 9.94 μg/L) with higher dissolved organic carbon (DOC) levels, but lower in autumn (41.10 ± 5.82 μg/L) and winter (78.47 ± 2.74 μg/L) with lower DOC levels. Due to the increase of bromide concentration in spring and winter, more toxic brominated DBPs increased obviously and took up a greater proportion. In this DWTP, DBP concentrations increased dramatically after pre-chlorination, especially in summer. It is noteworthy that the removal of DBPs during the subsequent treatment was more obvious in spring than in the other three seasons because the pH value is more beneficial to coagulation in spring.

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