scholarly journals Interactions between ammonia, iron and manganese removal using pilot-scale biofilters

2017 ◽  
Vol 66 (3) ◽  
pp. 157-165 ◽  
Author(s):  
Qingfeng Cheng ◽  
Lichao Nengzi ◽  
Linlin Bao ◽  
Yijing Wang ◽  
Jianxing Yang ◽  
...  
2015 ◽  
Vol 16 (3) ◽  
pp. 766-774 ◽  
Author(s):  
Qingfeng Cheng

In this study, the competitive mechanism of ammonia, iron and manganese for dissolved oxygen (DO) in a biofilter was investigated, and a new start-up method of a biofilter for ammonia, iron and manganese removal was approved, which can effectively shorten the start-up period from 3–4 months to 51 days. The results demonstrated that when DO was sufficient (about 8 mg · L−1), ammonia, iron and manganese could be completely removed. When DO decreased from 6.5 to 4 mg · L−1, the concentration of ammonia in the effluent increased accordingly, though iron and manganese were removed efficiently. When DO was as low as 3 mg · L−1, only iron was removed, whereas most of the ammonia and manganese still existed in the effluent. In addition, the oxidizing rates of the pollutants were not affected significantly with DO decrease. Turbidity removal in the biofilter was also investigated, and the results demonstrated that the turbidity decreased to less than 0.5 NTU at 0.4 m depth of the filter.


2015 ◽  
Vol 0 (0) ◽  
Author(s):  
Daniela-Elena Pascu ◽  
Mihaela Pascu(Neagu) ◽  
Gina Alina Traistaru ◽  
Aurelia Cristina Nechifor ◽  
Alexandra Raluca Miron

2001 ◽  
Vol 1 (5-6) ◽  
pp. 357-364 ◽  
Author(s):  
Y. Jimbo ◽  
K. Goto

The design standards of the iron and manganese removal system by membrane filtration were investigated. The membrane filtration after pre-chlorination could remove iron completely and could remove around 70% of manganese. In the case of manganese concentration being more than 0.05 mg/l, the membrane filtration could remove them completely after the deposition in the oxidation tank. The concentrations of iron and manganese were reduced more than 90% by the oxidation tank and were reduced until under the detection limit after the membrane filtration. The economic comparisons between the rapid sand filtration system and this membrane filtration system in a small capacity and a middle capacity were investigated. The 15 years total costs of the membrane filtration system were estimated to be smaller than or around equal to the rapid sand filtration system in both capacities.


Minerals ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 99
Author(s):  
Shigeshi Fuchida ◽  
Shota Tajima ◽  
Takuro Nishimura ◽  
Chiharu Tokoro

Manganese (Mn) is a major element in various aqueous and soil environments that is sometimes highly concentrated in mine water and other mineral processing wastewater. In this study, we investigated Mn removal from alkaline mine water (pH > 9) with an Mn-coated silica sand packed into a pilot-scale column reactor and examined the specific reaction mechanism using X-ray absorption near-edge structure (XANES) analysis and geochemical kinetic modeling. The kinetic effect of dissolved Mn(II) removal by birnessite (δ-Mn(IV)O2) at pH 6 and 8 was evaluated at different Mn(II)/Mn(IV) molar ratios of 0.1–10. Our results confirmed the positive effect of the presence of δ-MnO2 on the short-term removal (60 min) of dissolved Mn. XANES analysis results revealed that δ-MnO2 was more abundant than Mn(III)OOH in the reactor, which may have accumulated during a long-term reaction (4 months) after the reactor was turned on. A gradual decrease in dissolved Mn(II) concentration with depth was observed in the reactor, and comparison with the kinetic modeling result confirmed that δ-MnO2 interaction was the dominant Mn removal mechanism. Our results show that δ-MnO2 contents could play a significant role in controlling Mn removability from mine water in the reactor.


Author(s):  
Yingming Guo ◽  
Ben Ma ◽  
Jianxiong Huang ◽  
Jing Yang ◽  
Ruifeng Zhang

Abstract The iron and manganese oxide filter film (MeOx) were used to research the simultaneous removal of bisphenol A (BPA), manganese (Mn2+) and ammonium (NH4+) in a pilot-scale filter system. We found that 0.52 mg/L of BPA could be removed while consuming 5.44 mg/L of dissolved oxygen (DO). Since the oxidation process of NH4+ and BPA both consume the DO in water, the presence of NH4+ can hinder the removal of BPA. The presence of Mn2+ in water had a synergy effect on the BPA removal. The filter film was characterized by SEM, XRD and XPS. Some substances were generated to block the pores of the oxide film, and a small amount of film was found to crack and fall off. The elemental composition of C and O were both increased by about 9%, the composition of Mn was decreased from 63.48% to 44.55%, and the reduced manganese substance might affect the activity of the oxide film. The main chemical forms of MeOx are Mn6O12·3H2O, MnFe2O4 or Mn3O4. The decrease in the removal efficiency of BPA was mainly due to the C-containing intermediate [−CH2C − H(OH)]n covering the surface of the oxide film and blocking the pore size of the film.


2010 ◽  
Vol 113-116 ◽  
pp. 1316-1319 ◽  
Author(s):  
Hui Ping Zeng ◽  
Dong Li ◽  
Jie Zhang

“aged” biofilter media was adopted as the inoculum to accelerate the maturation of biofilter for iron and manganese removal in the start-up of filter column. morphology of “aged” biofilter media and new quartz sand was observed with SEM. The results indicate that the “aged” biofilter media coated by a large quantity of bacteria which reduces the start-up time to 30 daysand affords strong Mn-removal efficiency at the beginning of the process. This method probably can be used for the start-up of new filters when there are well-established biofilters around.


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