scholarly journals Construction of coordination polymers based on mixed-ligand synthetic strategy

2018 ◽  
Vol 35 (part 1) ◽  
pp. 561-572
Author(s):  
Huda Alkhalaf
Keyword(s):  
Coordination Polymers ◽  
Mixed Ligand ◽  
Synthetic Strategy

Design and construction of coordination polymers with mixed-ligand synthetic strategy

2013 ◽  
Vol 257 (7-8) ◽  
pp. 1282-1305 ◽  
Author(s):  
Miao Du ◽  
Cheng-Peng Li ◽  
Chun-Sen Liu ◽  
Shao-Ming Fang
Keyword(s):  
Coordination Polymers ◽  
Mixed Ligand ◽  
Synthetic Strategy ◽  
Design And Construction

scholarly journals From a Well-Defined Organozinc Precursor to Diverse Luminescent Coordination Polymers Based on Zn(II)-Quinolinate Building Units Interconnected by Mixed Ligand Systems

Molecules ◽  
2021 ◽  
Vol 26 (23) ◽  
pp. 7402
Author(s):  
Katarzyna Sołtys-Brzostek ◽  
Kamil Sokołowski ◽  
Iwona Justyniak ◽  
Michał K. Leszczyński ◽  
Natalia Olejnik-Fehér ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Coordination Polymers ◽  
Self Assembly ◽  
Rational Design ◽  
Building Blocks ◽  
Mixed Ligand ◽  
Direct Reaction ◽  
Synthetic Strategy ◽  
Secondary Building Units ◽  
Additional Base

Introduction of photoactive building blocks into mixed-ligand coordination polymers appears to be a promising way to produce new advanced luminescent materials. However, rational design and self-assembly of the multi-component supramolecular systems is challenging from both a conceptual and synthetic perspective. Here, we report exploratory studies that investigate the potential of [Zn(q)2]2[tBuZn(OH)]2 complex (q = deprotonated 8-hydroxyquinoline) as an organozinc precursor as well as a mixed-ligand synthetic strategy for the preparation of new luminescent coordination polymers (CPs). As a result we present three new 2D mixed-ligand Zn(II)-quinolinate coordination polymers which are based on various zinc quinolinate secondary building units interconnected by two different organic linker types, i.e., deprotonated 4,4′-oxybisbenzoic acid (H2obc) as a flexible dicarboxylate linker and/or selected bipyridines (bipy). Remarkably, using the title organozinc precursors in a combination with H2obc and 4,4′-bipyridine, a novel molecular zinc quinolinate building unit, [Zn4(q)6(bipy)2(obc)2], was obtained which self-assembled into a chain-type hydrogen-bonded network. The application of the organometallic precursor allowed for its direct reaction with the selected ligands at ambient temperature, avoiding the use of both solvothermal conditions and additional base reagents. In turn, the reaction involving Zn(NO3)2, as a classical inorganic precursor, in a combination with H2obc and bipy led to a novel 1D coordination polymer [Zn2(q)2(NO3)2(bipy)]. While the presence of H2obc was essential for the formation of this coordination polymer, this ditopic linker was not incorporated into the isolated product, which indicates its templating behavior. The reported compounds were characterized by single-crystal and powder X-ray diffraction, elemental analysis as well as UV-Vis and photoluminescence spectroscopy.

scholarly journals Dual-Fluorescent Nanoscale Coordination Polymers via a Mixed-Ligand Synthetic Strategy and Their Use for Multichannel Imaging

ChemNanoMat ◽  
2017 ◽  
Vol 4 (2) ◽  
pp. 183-193 ◽  
Author(s):  
Fabiana Nador ◽  
Karolina Wnuk ◽  
Javier García-Pardo ◽  
Julia Lorenzo ◽  
Rubén Solorzano ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Mixed Ligand ◽  
Synthetic Strategy ◽  
Nanoscale Coordination Polymers

Assembly of a series of d10 coordination polymers of pamoic acid through a mixed-ligand synthetic strategy: syntheses, structures and fluorescence properties

CrystEngComm ◽  
2014 ◽  
Vol 16 (46) ◽  
pp. 10658-10673 ◽  
Author(s):  
Tingting Cao ◽  
Yanqiang Peng ◽  
Ting Liu ◽  
Suna Wang ◽  
Jianmin Dou ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Coordination Compounds ◽  
Mixed Ligand ◽  
Fluorescence Properties ◽  
Donor Ligands ◽  
Synthetic Strategy ◽  
Pamoic Acid

Eight fluorescent coordination compounds were obtained based on H2PA and N-donor ligands through a mixed-ligand synthetic strategy.

Assembly of ZnIIand CdIIcoordination polymers based on a flexible multicarboxylate ligand and nitrogen-containing auxiliary ligands through a mixed-ligand synthetic strategy: syntheses, structures and fluorescence properties

2016 ◽  
Vol 72 (2) ◽  
pp. 99-104 ◽  
Author(s):  
Ji-Tao Lu ◽  
Dan-Dan Meng ◽  
Qing-Guo Meng
Keyword(s):  
Metal Ions ◽  
Coordination Polymers ◽  
Mixed Ligand ◽  
Fluorescence Properties ◽  
X Ray Diffraction ◽  
One Dimensional ◽  
X Ray ◽  
Synthetic Strategy ◽  
Layer Structures ◽  
Weak Hydrogen Bonds

The structures of coordination polymers are strongly influenced by the organic ligands and metal ions used for their construction, so it is important to choose suitable ligands and metal ions and appropriate synthetic processes. Two noveld10coordination polymers, namely poly[[diaquabis(2,2′-bipyridine)[μ4-4,4′-(1,4-phenylenedioxy)bis(benzene-1,2-dicarboxylato)]dizinc(II)] dihydrate], {[Zn2(C22H10O10)(C10H8N2)2(H2O)2]·2H2O}n, (1), and poly[[diaquabis(1,10-phenanthroline)[μ4-4,4′-(1,4-phenylenedioxy)bis(benzene-1,2-dicarboxylato)]dicadmium(II)] dimethylformamide disolvate], {[Cd2(C22H10O10)(C12H8N2)2(H2O)2]·2C3H7NO}n, (2), have been synthesized from 4,4′-(1,4-phenylenedioxy)bis(benzene-1,2-dicarboxylic acid) (H4L) and two different N-containing auxiliary ligands through a mixed-ligand synthetic strategy under a solvothermal environment. The structures were characterized by single-crystal X-ray diffraction, powder X-ray diffraction, elemental analysis and IR spectroscopy. Compounds (1) and (2) both present one-dimensional chain structures and two-dimensional supramolecular layer structures constructed by weak hydrogen bonds. It is interesting to note that the carboxylate ligands reveal stabletransconfigurations in both compounds. The fluorescence properties of (1) and (2) in the solid state were also investigated.

scholarly journals Two mixed-ligand coordination polymers based on 2,5-thiophenedicarboxylic acid and flexible N-donor ligands: the protective effect on periodontitis via reducing the release of IL-1β and TNF-α

2020 ◽  
Vol 18 (1) ◽  
pp. 391-398
Author(s):  
Shao-Hsuan Wu ◽  
Jun-Hui Huang
Keyword(s):  
Coordination Polymers ◽  
Gingival Crevicular Fluid ◽  
Mixed Ligand ◽  
Donor Ligands ◽  
X Ray Diffraction ◽  
Functional Studies ◽  
Tnf Α ◽  
Mucosal Cells ◽  
Ligand Coordination ◽  
Crevicular Fluid

AbstractTwo novel mixed-ligand coordination polymers, {[Co(tdc)(btrp)]·0.67DMF}n (1) and {[Zn2(bimb)2(tdc)2]·2H2O}n (2) involving 2,5-thiophenedicarboxylate (H2tdc), and bitopic flexible N-donor ligands, 1,3-bis(1,2,4-triazol-1-yl)propane (btrp) and 1,4-bis((1H-benzo[d]imidazol-1-yl)methyl)benzene (bimb), have been synthesized by the hydrothermal method and characterized via IR, elemental analysis, thermal analysis, and powder X-ray diffraction. The biological functional studies were performed; the treatment activity of the compounds on periodontitis and the specific mechanism was explored. First, the real-time RT-PCR was carried out to determine the inflammatory genes nf-κb and p53 relative expression in periodontal mucosal cells after treating with compounds 1 and 2. Then, the level of the inflammatory cytokine in the gingival crevicular fluid after treating with compounds was also determined by the ELISA detection kit.

Synthesis, Crystal Structure and Fluorescence of Two Novel Mixed-Ligand Cadmium Coordination Polymers with Different Structural Motifs

2003 ◽  
Vol 2003 (14) ◽  
pp. 2705-2710 ◽  
Author(s):  
Junhua Luo ◽  
Maochun Hong ◽  
Ruihu Wang ◽  
Rong Cao ◽  
Lei Han ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Coordination Polymers ◽  
Mixed Ligand ◽  
Structural Motifs
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