POTENTIOMETRIC AND SPECTRAL STUDIES ON MIXED METAL COMPLEXES OF SPARFLOXACIN

2016 ◽  
Vol 2016 (2016) ◽  
pp. 112-127
1977 ◽  
Vol 30 (9) ◽  
pp. 1921 ◽  
Author(s):  
PP Singh ◽  
SP Yadav ◽  
SB Sharma

Complexes of MM?(XCN)4 (M = CoII, NiII; M? = ZnII, CdII, HgII; X = S, Se) with triphenyl-phosphine have been synthesized and characterized by elementary analysis, molar conductance, magnetic moment, infrared and electronic spectral studies. All the complexes are binuclear mixed- metal monomeric bridged of the type (Ph3P)2M(NCX)2M?(XCN)2 except for [Ni(PPh3)4] [Zn(NCS)4] which is cationic-anionic.


1988 ◽  
Vol 43 (8) ◽  
pp. 927-932 ◽  
Author(s):  
Hans-Friedrich Klein ◽  
Michael Gaß ◽  
Ulf Zucha ◽  
Brigitte Eisenmann

AbstractSeveral fortuitous preparations and high yield rational syntheses for [(Me3P)2M(PMe2)]: (1: M = Co; 2: M = Ni) are described. 1 crystallizes in the space group P1̄ (no. 2); a = 975.6(5). b = 943.6(5), c - 904.2(5) pm. α= 63.8(1)°, β = 79.1(1)°, γ = 72.8(1)°. Mixed metal complexes L2Co(PR2)2NiL2 (L = PMe3; R = Me, Ph) evaded detection giving symmetric products exclusively. An improved synthesis of LiP(C6H5)2·dioxane is also described.


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