Inhomogeneous Electric Field-Induced Structural Changes in Soft Lead Zirconate Titanate Ferroelectric Ceramics

2021 ◽  
Author(s):  
Jianwei Zhao ◽  
Stephen D. Funni ◽  
Emily R. Molina ◽  
Elizabeth C. Dickey ◽  
Jacob L. Jones
1999 ◽  
Vol 14 (7) ◽  
pp. 2940-2944 ◽  
Author(s):  
Fei Fang ◽  
Wei Yang ◽  
Ting Zhu

Lanthanum-modified lead zirconate titanate ferroelectric ceramics (Pb0.96La0.04)(Zr0.40Ti0.60)0.99O3 were synthesized by the conventional powder processing technique. X-ray diffraction experiments revealed that the samples belong to the tetragonal phase with a = b = 0.4055 nm, c = 0.4109 nm, and c/a = 1.013. After being poled, the samples were indented with a 5-kg Vickers indenter, and lateral electric fields of 0.4 Ec, 0.5 Ec, and 0.6 Ec (Ec = 1100 V/mm) were applied, respectively. Field-emission scanning electron microscopy showed that 90° domain switching appeared near the tip of the indentation crack under a lateral electric field of 0.6 Ec. A mechanism of 90° domain switching near the crack tip under an electric field is discussed.


2001 ◽  
Vol 16 (8) ◽  
pp. 2306-2313 ◽  
Author(s):  
Shan Wan ◽  
Keith Bowman

Preferred domain orientation of a piezoelectric ceramic develops through domain switching under electric poling. In previous investigations the critical free energy required for domain switching has been assumed as a constant. This assumption leads to overestimation of the poling-induced texture and provides no explanation for the switching reversal in ferroelectric ceramics after the poling field is removed. In this paper, the contribution of intergranular stress to critical energy for 90° domain switching is investigated. A criterion including intrinsic threshold energy and an interaction energy, which is related to the intergranular stress and the intergranular depolarization field, is proposed. The texture evolution during poling process is simulated using a computational model starting from an initial random domain orientation distribution. The resulted domain orientation distributions under and after poling are predicted. The remanent domain switching after poling is the result of the balance between the interaction energy and intrinsic threshold energy. The final texture is much weaker than that under the electric field. Pole figures of poled Navy VI lead zirconate titanate measured by x-ray diffraction are consistent with the predicted textures.


2003 ◽  
Vol 82 (10) ◽  
pp. 1583-1585 ◽  
Author(s):  
Y. Wang ◽  
W. Y. Chu ◽  
K. W. Gao ◽  
Y. J. Su ◽  
L. J. Qiao

2010 ◽  
Vol 177 ◽  
pp. 109-113 ◽  
Author(s):  
Li Wei Li ◽  
Jin Xu Li ◽  
Y.J. Su ◽  
W.Y. Chu ◽  
L.J. Qiao

The effect of humidity on delayed propagation of indentation crack in lead zirconate titanate ferroelectric ceramics under sustained electric field was investigated. The results indicated that delayed propagation of indentation crack could occur in humid air at 98%RH without electric field but it did not in air at RH  30%. The threshold electric field and incubation time for delayed propagation of indentation crack increased but the increment of propagation length decreased with decreasing the humidity. When the electric field is large of 0.14 times of the coercive field, the delayed propagation could also occur in vacuum.


2012 ◽  
Vol 112 (3) ◽  
pp. 034103 ◽  
Author(s):  
Julia Glaum ◽  
Yuri A. Genenko ◽  
Hans Kungl ◽  
Ljubomira Ana Schmitt ◽  
Torsten Granzow

1994 ◽  
Vol 75 (3) ◽  
pp. 1699-1704 ◽  
Author(s):  
K. G. Brooks ◽  
J. Chen ◽  
K. R. Udayakumar ◽  
L. E. Cross

2013 ◽  
Vol 113 (4) ◽  
pp. 044104 ◽  
Author(s):  
A. Peláiz-Barranco ◽  
A. C. Garcia-Wong ◽  
Y. González-Abreu ◽  
J. D. S. Guerra

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