Exploration of Lower Critical Solution Temperature DES in a Thermoreversible Aqueous Two-Phase System for Integrating Glucose Conversion and 5-HMF Separation

2021 ◽  
Author(s):  
Shanshan Tu ◽  
Xiaojie Yu ◽  
Cunshan Zhou ◽  
Li Chen
Keyword(s):  
Lower Critical Solution Temperature ◽  
Solution Temperature ◽  
Phase System ◽  
Two Phase ◽  
Critical Solution Temperature ◽  
Aqueous Two Phase System

The Effect of Molecular Architecture on the Phase Diagram and Mobility of a Polymer Blend Exhibiting a Lower Critical Solution Temperature: Cycles Mixed with Linear Chains.

1991 ◽  
Vol 248 ◽  
Author(s):  
Maria M. Santore ◽  
Gregory McKenna ◽  
Charles Han
Keyword(s):  
Phase Diagram ◽  
Phase Separation ◽  
Lower Critical Solution Temperature ◽  
Phase Region ◽  
Solution Temperature ◽  
Free Energy Function ◽  
Molecular Architecture ◽  
Two Phase ◽  
Critical Solution Temperature ◽  
Linear Chains

AbstractWe examine the role of molecular architecture on the phase diagram of the PS/PVME (poly[styrenel /poly[vinyl methyl ether]) blend, a mixture which in previous studies with linear chains exhibited a lower critical solution temperature, (LCST) i.e. it phase separated on heating. In this investigation, two blends with components exceeding the critical molecular weight for entanglement were compared: one consisting of linear PS and PVME and a second with cyclic PS and linear PVME. Cloud point experiments over a broad composition range reveal that the blend containing cyclic PS undergoes phase separation at temperatures 7-8 °C higher than the analogous linear blend. In other words, the mixture of cycles and linear chains is more thermodynamically stable than the mixture of two linear chains.The LCST nature of the system facilitates examining chain mobility by considering the phase separation kinetics. Time-resolved light scattering studies of blends near their critical compositions tracked the spinodal decomposition following a rapid temperature jump from the one-phase to the two-phase region. An analysis of the scattering intensity growth ultimately led to mutual diffusion coefficients whose temperature dependence confirmed the observed cloud points. An approximation of the second derivative of the free energy function based on SANS studies of the linear PS/PVME blend allowed us to estimate mutual mobilities. The values determined for the cycle-containing blend were considerably lower than those for the blend of linear chains at these molecular weights.

Enhancing the Sensitivity of DNA and Aptamer Probes in the Dextran/PEG Aqueous Two-Phase System

2021 ◽  
Author(s):  
Qiaoshu Chen ◽  
Yanwen Zhang ◽  
Hui Chen ◽  
Jianbo Liu ◽  
Juewen Liu
Keyword(s):  
Phase System ◽  
Two Phase ◽  
Aqueous Two Phase System

Continuous Purification of an Enveloped and Non-enveloped Viral Particle Using an Aqueous Two-Phase System

2021 ◽  
pp. 118753
Author(s):  
Dylan G. Turpeinen ◽  
Pratik U. Joshi ◽  
Seth A. Kriz ◽  
Supreet Kaur ◽  
Natalie M. Nold ◽  
...  
Keyword(s):  
Viral Particle ◽  
Phase System ◽  
Two Phase ◽  
Aqueous Two Phase System

scholarly journals Partitioning of bovine lactoferrin in aqueous two-phase system containing poly(ethylene glycol) and sodium citrate

2015 ◽  
Vol 95 ◽  
pp. 118-124 ◽  
Author(s):  
Angélica Ribeiro da Costa ◽  
Jane Sélia dos Reis Coimbra ◽  
Luísa Alexandre Ferreira ◽  
João Carlos Marcos ◽  
Igor José Boggione Santos ◽  
...  
Keyword(s):  
Ethylene Glycol ◽  
Sodium Citrate ◽  
Bovine Lactoferrin ◽  
Phase System ◽  
Poly Ethylene Glycol ◽  
Two Phase ◽  
Aqueous Two Phase System ◽  
Poly Ethylene

Characterization of alcohol/salt aqueous two-phase system for optimal separation of gallic acids

2021 ◽  
Vol 131 (5) ◽  
pp. 537-542
Author(s):  
Hui Suan Ng ◽  
Phei Er Kee ◽  
Hip Seng Yim ◽  
Joo Shun Tan ◽  
Yin Hui Chow ◽  
...  
Keyword(s):  
Phase System ◽  
Two Phase ◽  
Aqueous Two Phase System ◽  
Optimal Separation
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