The Products Distribution-Tuned and Inhibiting Cracking of Fatty Acid Hydrogenation Over Co@SiO2 Porous Nanorattles

2021 ◽  
Author(s):  
Min Lin ◽  
Xi Zhang ◽  
Lulu Zhan ◽  
Xiaoxian Li ◽  
Xianliang Song ◽  
...  
Keyword(s):  
Fatty Acid ◽  
Fatty Acid Hydrogenation

C18unsaturated fatty acid hydrogenation patterns of some rumen bacteria and their ability to hydrolyse exogenous phospholipid

1976 ◽  
Vol 35 (2) ◽  
pp. 293-297 ◽  
Author(s):  
G. P. Hazlewood ◽  
P. Kemp ◽  
D. Lander ◽  
R. M. C. Dawson
Keyword(s):  
Fatty Acids ◽  
Fatty Acid ◽  
Polyunsaturated Fatty Acids ◽  
Linolenic Acid ◽  
Phosphatidyl Choline ◽  
Dienoic Acid ◽  
Dietary Fatty Acids ◽  
Rumen Bacteria ◽  
Unusual Pattern ◽  
Fatty Acid Hydrogenation

1. A number of rumen bacteria isolated because of their ability to deacylate phosphatidyl-choline, were found, in addition, to hydrogenate polyunsaturated fatty acids..2. The most active lipolytic organisms had an unusual pattern of hydrogenation of dietary fatty acids in that α-linolenic acid was hydrogenated only as far as trans-11,cis-15-octadeca-dienoic acid.

Mechanism of supported Ru3Sn7 nanocluster-catalyzed selective hydrogenation of coconut oil to fatty alcohols

2018 ◽  
Vol 8 (5) ◽  
pp. 1322-1332 ◽  
Author(s):  
Zhicheng Luo ◽  
Qiming Bing ◽  
Jiechen Kong ◽  
Jing-yao Liu ◽  
Chen Zhao
Keyword(s):  
Fatty Acids ◽  
Fatty Acid ◽  
Selective Hydrogenation ◽  
Active Site ◽  
Coconut Oil ◽  
Fatty Alcohols ◽  
Hydrotreating Catalyst ◽  
Fatty Acid Hydrogenation

As a promising hydrotreating catalyst, it was previously reported that Ru⋯OSn (Ru electronically interacts with Sn oxides) on RuSn/SiO2 was the active site for fatty acid hydrogenation, but here in this work we found that Ru3Sn7 nanoclusters on RuSn/SiO2 were responsible for the selective hydrogenation of diverse fatty acids and coconut oil to fatty alcohols.

scholarly journals Polymeric Ru-containing catalysts in fatty acid hydrogenation

2018 ◽  
Author(s):  
Antonina Stepacheva ◽  
Esfir Sulman ◽  
Yury Lugovoy ◽  
Alexander Sidorov ◽  
Valentina Matveeva
Keyword(s):  
Fatty Acid ◽  
Fatty Acid Hydrogenation

scholarly journals The effects of different amounts and types of fat on the extent of C18 unsaturated fatty acid hydrogenation in the rumen of sheep

2001 ◽  
Vol 10 (Suppl. 2) ◽  
pp. 123-128 ◽  
Author(s):  
A. Cieślak ◽  
M. Szumacher-Strabel ◽  
A. Potkański ◽  
J. Kowalczyk ◽  
M. Czauderna
Keyword(s):  
Fatty Acid ◽  
Unsaturated Fatty Acid ◽  
Fatty Acid Hydrogenation

The effect of dietary N onin vitrolipolysis and fatty acid hydrogenation in rumen digesta from sheep fed diets high in starch

1983 ◽  
Vol 101 (1) ◽  
pp. 97-101 ◽  
Author(s):  
T. Gerson ◽  
A. John ◽  
B. R. Sinclair
Keyword(s):  
Fatty Acids ◽  
Fatty Acid ◽  
Linoleic Acid ◽  
Unsaturated Fatty Acids ◽  
Linear Increase ◽  
Dietary Fatty Acid ◽  
Elevated Concentration ◽  
Microbial Composition ◽  
Fatty Acid Hydrogenation

SUMMARYFive Romney wethers, fitted with rumen fistulae, were each fed five pelleted diets high in starch (30–50%) containing 0·72, 1·22, 1·72, 2·47 and 3·72% N respectively. Samples of rumen liquor were incubated with glycerol-tri-[1-14C]oleate or with [1-14C]- linoleic acid. The rates of lipolysis or hydrogenation of these substrates were measured. In addition rumen contents of the sheep when fed the 1·22% N diet were incubated with radioactive substrates plus 0, 100 and 200 mg finely ground casein.It was found that there was an approximately linear increase in the rate of lipolysis between 0·7 and 2·5% N. The rate of hydrogenation did not increase below l·2% N and tended to decrease above 2·5% N. The potential for hydrogenation of unesterified linoleic acid was calculated to be 4–6 times greater with all diets except that containing 1·2% N. This may be one explanation for the elevated concentration of the rumen unsaturated fatty acids in sheep fed diets containingca.1–1·5% N.It was also established that the addition of finely ground casein to the incubate was without effect.It was concluded that microbial composition is important in regulating the relative rates of lipolysis and hydrogenation which determined the amount of unsaturated dietary fatty acid present in the rumen.

Temperature Dependence of the Critical Electron Dose for Fatty Acid Monolayers

1982 ◽  
Vol 40 ◽  
pp. 78-79
Author(s):  
Kenneth H. Downing ◽  
Robert M. Glaeser
Keyword(s):  
Electron Beam ◽  
Fatty Acid ◽  
Inelastic Scattering ◽  
Temperature Dependence ◽  
Structural Damage ◽  
Direct Result ◽  
Second Step ◽  
Strong Temperature Dependence ◽  
Electron Dose ◽  
Covalent Bonds

The structural damage of molecules irradiated by electrons is generally considered to occur in two steps. The direct result of inelastic scattering events is the disruption of covalent bonds. Following changes in bond structure, movement of the constituent atoms produces permanent distortions of the molecules. Since at least the second step should show a strong temperature dependence, it was to be expected that cooling a specimen should extend its lifetime in the electron beam. This result has been found in a large number of experiments, but the degree to which cooling the specimen enhances its resistance to radiation damage has been found to vary widely with specimen types.

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