Genetic Mechanism of Low Resistivity in High-Mature Marine Shale: Insights from Study on Pore Structure and Composition

2021 ◽  
Author(s):  
Zixin Xue ◽  
Zhenxue Jiang ◽  
Xin Wang ◽  
Zhiye Gao ◽  
Jiangqi Chang ◽  
...  
Keyword(s):  
Pore Structure ◽  
Genetic Mechanism ◽  
Low Resistivity ◽  
Marine Shale

Pore structure characteristics and its effect on adsorption capacity of Niutitang marine shale in Sangzhi block, southern China

2019 ◽  
Vol 7 (4) ◽  
pp. T843-T856
Author(s):  
Xinghua Wang ◽  
Arash Dahi Taleghani ◽  
Wenlong Ding
Keyword(s):  
Organic Matter ◽  
Pore Structure ◽  
Adsorption Capacity ◽  
Southern China ◽  
Quartz Content ◽  
Isothermal Adsorption ◽  
Structure Characteristics ◽  
Marine Shale ◽  
Lp Formula ◽  
Organic Pores

Characteristics of shale pore structures may play an important role in natural gas accumulation and consequently estimating the original gas in place. To determine the pore structure characteristics of Niutitang marine shale in the Sangzhi block, we carried out [Formula: see text] adsorption-desorption (LP-[Formula: see text]GA), [Formula: see text] adsorption (LP-[Formula: see text]GA), and methane isothermal adsorption on shale samples to reveal the pore size distribution (PSD) and its impact on the adsorption capacity. Results indicate that the Niutitang Shale is in stages of maturity and overmaturity with good organic matter, and they also indicate well-developed interparticle, intraparticle, and organic pores. Quartz and clay are found to be the main minerals, and the high illite content means that the Niutitang Shale is experiencing the later stage of clay mineral transformation. Various-sized shale pores are well-developed, and most of them are narrow and slit-like. For pores with diameters of 2–300 nm measured with LP-[Formula: see text]GA, mesopores (2–50 nm) contribute most of the total specific surface area (SSA) and total pore volume (TPV) in comparison to macropores (50–300 nm). For micropores ([Formula: see text]) tested by LP-[Formula: see text]GA, the PSD appears to be multimodal; shale pores of 0.50–0.90 nm diameter contribute most of the SSA and TPV. [Formula: see text]-SSA and [Formula: see text]-SSA indicate positive correlations with their corresponding TPV. The total organic matter (TOC) has good correlation with the SSA and TPV of micropores. The Langmuir volume positively correlates with the total SSA. Additionally, the TOC content has a good correlation with the Langmuir volume, which is consistent with the observation of well-developed fossils of diatoms and organic pores. As an important source of organic matter, more diatoms mean more organic matter, larger TOC values and quartz content, larger SSA and TPV of micropores, and, of course, stronger shale adsorption capacity. The results provide important guidance for the exploration and development of shale gas existing in the Sangzhi block.

scholarly journals Experimental Investigation of Evolution of Pore Structure in Longmaxi Marine Shale Using an Anhydrous Pyrolysis Technique

Minerals ◽  
2018 ◽  
Vol 8 (6) ◽  
pp. 226 ◽  
Author(s):  
Zhaodong Xi ◽  
Jing Wang ◽  
Jingang Hu ◽  
Shuheng Tang ◽  
Heqi Xiao ◽  
...  
Keyword(s):  
Experimental Investigation ◽  
Pore Structure ◽  
Marine Shale

Implications of thin laminations on pore structure of marine shale reservoir: Goldwyer Formation case study from Western Australia

2021 ◽  
Vol 61 (1) ◽  
pp. 205
Author(s):  
Muhammad Atif Iqbal ◽  
Reza Rezaee ◽  
Gregory Smith ◽  
Partha Pratim Mandal
Keyword(s):  
Pore Structure ◽  
Western Australia ◽  
Marine Shale ◽  
Shale Reservoir

Fractal Characteristics of the Middle-Upper Ordovician Marine Shale Nano-Scale Porous Structure from the Ordos Basin, Northeast China

2021 ◽  
Vol 21 (1) ◽  
pp. 274-283
Author(s):  
Liang Liu ◽  
Wuling Mo ◽  
Min Wang ◽  
Nengwu Zhou ◽  
Yu Yan ◽  
...  
Keyword(s):  
Fractal Dimension ◽  
Pore Structure ◽  
Pore Size ◽  
Ordos Basin ◽  
Fractal Dimensions ◽  
Upper Ordovician ◽  
Average Pore ◽  
Marine Shale ◽  
Fractal Characteristics ◽  
The Relationship

The fractal characteristics of marine shale from the Middle-Upper Ordovician Wulalike Formation (O2w) in the southwest margin of the Ordos Basin are studied. Based on low-temperature nitrogen adsorption experiments, the FHH (Frenkel-Halsey-Hill) model was employed to investigate the relationship between the marine shale composition, such as TOC, mineral content and shale gas content, and pore structure parameters, such as BET specific surface area, average pore diameter, porosity and fractal dimension. The results show that the pore size distribution curve of shale slowly decreased after the pore size was greater than 50 nm, the pore size distribution showed multiple peaks, and the peak value was mainly in the range of 2–10 nm. Most pores are nanopores, although the pore type and shape are different. Two different fractal dimensions D1 and D2 are obtained from the two segments with relative pressures of 0–0.5 and 0.5–1.0, respectively: the D1 range is 2.77–2.82, and the D2 range is 2.63–2.66. As D1 is larger than D2, the pore structure of small pores is more uniform than that of large pores in the shale samples. The relationship between the fractal dimensions D1 and D2 and the total organic carbon (TOC) content is a convex curve. Fractal dimension D reaches its maximum when TOC is 0.53 wt.%. Fractal dimension D decreases with increasing specific surface area, porosity and average pore size. The fractal dimension has a different influence on the gas storage and migration in shale; the larger the fractal dimension is, the stronger the heterogeneity and the more complex the pore structure, and this outcome is conducive to the storage of gas in shale but not beneficial to the permeability and production of gas.

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