Resiliency of Long Chains under Plant Disruptions

2021 ◽  
Author(s):  
Dan Zhu ◽  
Napat Rujeerapaiboon
Keyword(s):  
Soft Matter ◽  
2021 ◽  
Vol 17 (10) ◽  
pp. 2872-2882
Author(s):  
Muhammad Anwar ◽  
Richard S. Graham

Modelling of flow-induced nucleation in polymers suggest that long chains are enriched in nuclei, relative to their melt concentration.


1930 ◽  
Vol 3 (3) ◽  
pp. 483-484
Author(s):  
Thomas Midgley ◽  
Albert L. Henne

Abstract Isoprene has been ethylated; 4-methyl-4-octene was formed exclusively. The structure of this nonene is in agreement with the usual behavior of a conjugated double bond system. This type of addition is further evidence in favor of the hypothesis which regards the polymerization of isoprene to synthetic rubber as the formation of long chains of isoprene units linked together- by ordinary valences in the 1,4-position.


10.37236/7124 ◽  
2018 ◽  
Vol 25 (1) ◽  
Author(s):  
Stefan David ◽  
Hunter Spink ◽  
Marius Tiba

We ask if there exists a symmetric chain decomposition of the cuboid $Q_k \times n$ such that no chain is taut, i.e. no chain has a subchain of the form $(a_1,\ldots, a_k,0)\prec \cdots\prec (a_1,\ldots,a_k,n-1)$. In this paper, we show this is true precisely when $k \ge 5$ and $n\ge 3$. This question arises naturally when considering products of symmetric chain decompositions which induce orthogonal chain decompositions — the existence of the decompositions provided in this paper unexpectedly resolves the most difficult case of previous work by the second author on almost orthogonal symmetric chain decompositions (2017), making progress on a conjecture of Shearer and Kleitman (1979). In general, we show that for a finite graded poset $P$, there exists a canonical bijection between symmetric chain decompositions of $P \times m$ and $P \times n$ for $m, n\ge rk(P) + 1$, that preserves the existence of taut chains. If $P$ has a unique maximal and minimal element, then we also produce a canonical $(rk(P) +1)$ to $1$ surjection from symmetric chain decompositions of $P \times (rk(P) + 1)$ to symmetric chain decompositions of $P \times rk(P)$ which sends decompositions with taut chains to decompositions with taut chains.


1984 ◽  
Vol 45 (24) ◽  
pp. 1183-1187 ◽  
Author(s):  
R.G. Petschek ◽  
P. Pfeuty ◽  
J.C. Wheeler
Keyword(s):  

1936 ◽  
Vol 9 (3) ◽  
pp. 422-425
Author(s):  
Kurt H. Meyer

Abstract Two inorganic substances with elasticity similar to that of rubber are described in the literature of the subject, viz., elastic sulfur and polyphosphonitrilic chloride. In this paper we shall deal with investigations of both. It is common knowledge that sulfur heated to 170° becomes highly viscous; if then cooled, e. g., by plunging into water, it yields an amorphous elastic product. If threads of this amorphous product are stretched, they show a double refraction, and, as Trilat has found, develop a fiber-diagram. With Go the author has examined this diagram, and deduced from it the following arrangement of the sulfur atoms: long chains of sulfur atoms, linked by strong homeopolar valences, are arranged parallel to the direction of stretching. Their special position in the elementary cell is shown in Fig. 1. In a recent publication, Warren has made it clear that ordinary sulfur is made up of 8-atom rings. The molecular weight of the elastic form Sn is not known, but seems to be very high. We know from earlier work that the melting of sulfur produces an equilibrium between the two forms, and this shifts, at higher temperatures, in favor of the chain-sulfur. About 1000 calories per gram atom S are consumed in the transformation of S8 into Sn.


Author(s):  
John Emsley

You may think of polymers as entirely manufactured and therefore unnatural, but they are often the chemists’ attempts to supplement and improve on the biological polymers that nature produces. Cotton, ivory, leather, linen, paper, rubber, silk, wood and wool are wonderful materials made from the biological polymers that plants and animals produce, and which have evolved to serve such useful ends as providing protective outer layers, insulation, reinforcement, weaponry and so on. Humans learned that with a little modification they could turn these polymers into quite useful articles, such as briefs and briefcases, condoms and tea cosies, tickets and toothpicks. Sometimes we want polymers with features that never evolved in nature, such as non-cracking insulation for electric cable, clothes that can be unpacked after a long voyage and still be without creases, or pans in which to fry eggs without them sticking. For these polymers we have had to look to chemists. Most of the portraits in this Gallery are of these kinds of polymers—materials that do not have natural equivalents. Polymers are rather special kinds of molecules consisting of long chains, usually made up of carbon atoms, to which other atoms, such as hydrogen, fluorine and chlorine, are attached. The older name for polymers is plastics, and you probably know several of them by name— polythene, polystyrene, Teflon, Orion—but these are only a few of the many that now play an important role in our lives. Whatever role polymers play, they cause many of us to adopt quite strong attitudes towards them. A few of us admire them, many of us ignore them, but a growing number despise them and a few abhor them and will avoid them at all costs. To a chemist, this opposition to polymers seems rather strange. By the time you come to the end of this exhibition I hope that visitors with strong views will have seen enough to persuade them to change their mind. Attitudes towards plastics have changed over the past half-century. In the 19305, when cellophane, PVC, polystyrene, Perspex and nylon were launched, plastics were welcomed.


Soft Matter ◽  
2021 ◽  
Author(s):  
Olga Vassiliadou ◽  
Varvara Chrysostomou ◽  
Stergios Pispas ◽  
Panagiotis A. Klonos ◽  
Apostolos Kyritsis

Synthesis, crystallization, and molecular dynamics investigation on oligo-ethylene glycol methacrylate (OEGMA) of short and long chains, in the linear and nanostructured comb-like forms.


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