Kaolinite transformation into dickite during burial diagenesis

2014 ◽  
Vol 99 (4) ◽  
pp. 681-695 ◽  
Author(s):  
J. Cuadros ◽  
R. Vega ◽  
A. Toscano ◽  
X. Arroyo
Keyword(s):  
Burial Diagenesis

Illite-smectites and the influence of burial diagenesis on the geochemical cycling of nitrogen

Clay Minerals ◽  
1998 ◽  
Vol 33 (4) ◽  
pp. 539-546 ◽  
Author(s):  
P. A. Schroeder ◽  
A. A. McLain
Keyword(s):  
Reaction Mechanisms ◽  
Ostwald Ripening ◽  
Precipitation Reaction ◽  
Oil Well ◽  
Burial Diagenesis ◽  
Fixed Nitrogen ◽  
Geochemical Cycling ◽  
Oil Generation ◽  
Fraction Increase ◽  
Changing Rate

AbstractFixed nitrogen in illite-smectites (I-S) has been measured for Miocene shales from a Gulf of Mexico oil well. Fixed N values for the <0.2 µm fraction increase with depth from 150 ppm (1000 m) to a maximum of 360 ppm (3841 m). This increase is coincident with illitization from 41% I in I-S to 75% I in I-S. Below 3841 m, fixed N values decrease to 190 ppm (4116 m) while I-S is maintained with a slight increase from 77 to 82%. The changes in fixed N with increasing illitization are consistent with the notion that illitization proceeds via both transformation and dissolution/ precipitation reaction mechanisms. The trend of decreasing fixed N in illitic I-S is compatible with surface-controlled crystal growth and Ostwald ripening mechanisms for illitization. The trend may also be linked to the timing of maximum NH] release from kerogen maturation during oil generation. The changing rate of NH+4 liberation from organic matter and multiple illitization reaction mechanisms can result in complex N geochemical cycling pathways throughout early diagenesis to metamorphism.

Closely spaced twin lamellae in limestones as an indicator of deep-burial diagenesis

1992 ◽  
Vol 7 (1) ◽  
pp. 38-47 ◽  
Author(s):  
Jeffrey M. Simonsen ◽  
Gerald M. Friedman
Keyword(s):  
Burial Diagenesis ◽  
Deep Burial

scholarly journals Chemical remagnetization and burial diagenesis: Testing the hypothesis in the Pennsylvanian Belden Formation, Colorado

1997 ◽  
Vol 102 (B11) ◽  
pp. 24825-24842 ◽  
Author(s):  
Sanjay Banerjee ◽  
R. Douglas Elmore ◽  
M. H. Engel
Keyword(s):  
Burial Diagenesis

Zn-Pb mineralisation in the Silvermines district, Ireland: a product of burial diagenesis

2004 ◽  
Vol 39 (1) ◽  
pp. 87-102 ◽  
Author(s):  
Christopher P. Reed ◽  
Malcolm W. Wallace
Keyword(s):  
Burial Diagenesis

Geochemistry of diagenetic non-silicate minerals: kinetic considerations

1985 ◽  
Vol 315 (1531) ◽  
pp. 39-56 ◽  
Keyword(s):  
Organic Matter ◽  
Ferric Iron ◽  
Local Equilibrium ◽  
Reducing Agent ◽  
Chemical Environment ◽  
Iron Sulphide ◽  
Burial Diagenesis ◽  
Vertical Zonation ◽  
Silicate Minerals ◽  
Dissolution And Precipitation

The early stages of burial diagenesis involve the reactions of various oxidizing agents with organic matter, which is the only reducing agent buried with the sediment. In a system in which a local equilibrium is established, thermodynamic principles indicate that, inter alia , manganese, iron and sulphate should each be consumed successively to give rise to a clearly characterized vertical zonation. However, ferric iron may not react fast enough and the relative rates of reduction of Fe III and sulphate not only control the formation of iron sulphide and associated carbonate but also may lead to extreme chemical and isotopic dis-equilibrium. This produces kinetically controlled ‘micro -environments’. On a larger scale, sulphide will diffuse upward to a zone in which its oxidation leads to a reduction of pH. The various dramatic changes in chemical environment across such an interface cause both dissolution and precipitation reactions. These explain common geological observations: the occurrence of flint nodules (and their restriction to chalk hosts) and the association of phosphate with glauconite.

Relating Acoustic Anisotropy to Kerogen Content in Unconventional Formations - A Case Study in A Kerogen-Rich Unconventional Carbonate

2021 ◽  
Author(s):  
Yair Gordin ◽  
Thomas Bradley ◽  
Yoav O. Rosenberg ◽  
Anat Canning ◽  
Yossef H. Hatzor ◽  
...  
Keyword(s):  
Wave Velocity ◽  
Water Saturation ◽  
Well Logs ◽  
Rock Properties ◽  
Thermal Maturity ◽  
Burial Diagenesis ◽  
S Wave ◽  
Velocity Anisotropy ◽  
Thermal Maturation ◽  
Wide Range

Abstract The mechanical and petrophysical behavior of organic-rich carbonates (ORC) is affected significantly by burial diagenesis and the thermal maturation of their organic matter. Therefore, establishing Rock Physics (RP) relations and appropriate models can be valuable in delineating the spatial distribution of key rock properties such as the total organic carbon (TOC), porosity, water saturation, and thermal maturity in the petroleum system. These key rock properties are of most importance to evaluate during hydrocarbon exploration and production operations when establishing a detailed subsurface model is critical. High-resolution reservoir models are typically based on the inversion of seismic data to calculate the seismic layer properties such as P- and S-wave impedances (or velocities), density, Poisson's ratio, Vp/Vs ratio, etc. If velocity anisotropy data are also available, then another layer of data can be used as input for the subsurface model leading to a better understanding of the geological section. The challenge is to establish reliable geostatistical relations between these seismic layer measurements and petrophysical/geomechanical properties using well logs and laboratory measurements. In this study, we developed RP models to predict the organic richness (TOC of 1-15 wt%), porosity (7-35 %), water saturation, and thermal maturity (Tmax of 420-435⁰C) of the organic-rich carbonate sections using well logs and laboratory core measurements derived from the Ness 5 well drilled in the Golan Basin (950-1350 m). The RP models are based primarily on the modified lower Hashin-Shtrikman bounds (MLHS) and Gassmann's fluid substitution equations. These organic-rich carbonate sections are unique in their relatively low burial diagenetic stage characterized by a wide range of porosity which decreases with depth, and thermal maturation which increases with depth (from immature up to the oil window). As confirmation of the method, the levels of organic content and maturity were confirmed using Rock-Eval pyrolysis data. Following the RP analysis, horizontal (HTI) and vertical (VTI) S-wave velocity anisotropy were analyzed using cross-dipole shear well logs (based on Stoneley waves response). It was found that anisotropy, in addition to the RP analysis, can assist in delineating the organic-rich sections, microfractures, and changes in gas saturation due to thermal maturation. Specifically, increasing thermal maturation enhances VTI and azimuthal HTI S-wave velocity anisotropies, in the ductile and brittle sections, respectively. The observed relationships are quite robust based on the high-quality laboratory and log data. However, our conclusions may be limited to the early stages of maturation and burial diagenesis, as at higher maturation and diagenesis the changes in physical properties can vary significantly.

Depositional facies, diagenetic clay minerals and reservoir quality of Rotliegend sediments in the Southern Permian Basin (North Sea): a review

Clay Minerals ◽  
1982 ◽  
Vol 17 (1) ◽  
pp. 55-67 ◽  
Author(s):  
U. Seemann
Keyword(s):  
Clay Minerals ◽  
North Sea ◽  
Effective Porosity ◽  
Hydrocarbon Exploration ◽  
Reservoir Quality ◽  
Burial Diagenesis ◽  
Permian Basin ◽  
Northern Margin ◽  
The North

AbstractThe Southern Permian Basin of the North Sea represents an elongate E-W oriented depo-centre along the northern margin of the Variscan Mountains. During Rotliegend times, three roughly parallel facies belts of a Permian desert developed, these following the outline of the Variscan Mountains. These belts were, from south to north, the wadi facies, the dune and interdune facies, and the sabkha and desert lake facies. The bulk of the gas reservoirs of the Rotliegend occur in the aeolian dune sands. Their recognition, and the study of their geometry, is therefore important in hydrocarbon exploration. Equally important is the understanding of diagenesis, particularly of the diageneticaily-formed clay minerals, because they have an important influence on the reservoir quality of these sands. Clay minerals were introduced to the aeolian sands during or shortly after their deposition in the form of air-borne dust, which later formed thin clay films around the grains. During burial diagenesis, these clay films may have acted as crystallization nuclei for new clay minerals or for the transformation of existing ones. Depending on their crystallographic habit, the clay minerals can seriously affect the effective porosity and permeability of the sands.

scholarly journals Isotopic approaches for quantifying the rates of marine burial diagenesis

2010 ◽  
Vol 48 (3) ◽  
Author(s):  
M. S. Fantle ◽  
K. M. Maher ◽  
D. J. DePaolo
Keyword(s):  
Burial Diagenesis

Short course in burial diagenesis

1990 ◽  
Vol 54 (2) ◽  
pp. 489
Author(s):  
Lynton S. Land
Keyword(s):  
Burial Diagenesis ◽  
Short Course
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