Phosphorus Adsorption by Ceramic Suction Lysimeters

2010 ◽  
Vol 9 (4) ◽  
pp. 1092-1099 ◽  
Author(s):  
Nicholas Kiggundu ◽  
Yuncong Li ◽  
Kati W. Migliaccio
Keyword(s):  
Phosphorus Adsorption ◽  
Suction Lysimeters

QM/MM Simulations of Organic Phosphorus Adsorption at the Diaspore-Water Interface

2019 ◽  
Author(s):  
Prasanth Babu Ganta ◽  
Oliver Kühn ◽  
Ashour Ahmed
Keyword(s):  
Interaction Energy ◽  
Dynamics Simulation ◽  
Water Molecules ◽  
Hydroxyl Groups ◽  
Water Interface ◽  
Mineral Surfaces ◽  
Soil Mineral ◽  
Phosphorus Adsorption ◽  
Covalent Bonds ◽  
Binding Mechanisms

The phosphorus (P) immobilization and thus its availability for plants are mainly affected by the strong interaction of phosphates with soil components especially soil mineral surfaces. Related reactions have been studied extensively via sorption experiments especially by carrying out adsorption of ortho-phosphate onto Fe-oxide surfaces. But a molecular-level understanding for the P-binding mechanisms at the mineral-water interface is still lacking, especially for forest eco-systems. Therefore, the current contribution provides an investigation of the molecular binding mechanisms for two abundant phosphates in forest soils, inositol hexaphosphate (IHP) and glycerolphosphate (GP), at the diaspore mineral surface. Here a hybrid electrostatic embedding quantum mechanics/molecular mechanics (QM/MM) based molecular dynamics simulation has been applied to explore the diaspore-IHP/GP-water interactions. The results provide evidence for the formation of different P-diaspore binding motifs involving monodentate (M) and bidentate (B) for GP and two (2M) as well as three (3M) monodentate for IHP. The interaction energy results indicated the abundance of the GP B motif compared to the M one. The IHP 3M motif has a higher total interaction energy compared to its 2M motif, but exhibits a lower interaction energy per bond. Compared to GP, IHP exhibited stronger interaction with the surface as well as with water. Water was found to play an important role in controlling these diaspore-IHP/GP-water interactions. The interfacial water molecules form moderately strong H-bonds (HBs) with GP and IHP as well as with the diaspore surface. For all the diaspore-IHP/GP-water complexes, the interaction of water with diaspore exceeds that with the studied phosphates. Furthermore, some water molecules form covalent bonds with diaspore Al atoms while others dissociate at the surface to protons and hydroxyl groups leading to proton transfer processes. Finally, the current results confirm previous experimental conclusions indicating the importance of the number of phosphate groups, HBs, and proton transfers in controlling the P-binding at soil mineral surfaces.

Samples disturbance overestimates phosphorus adsorption capacity in soils under long-term application of pig slurry

2019 ◽  
Vol 65 (9) ◽  
pp. 1262-1272 ◽  
Author(s):  
Luciano Colpo Gatiboni ◽  
Djalma Eugênio Schmitt ◽  
Paulo Cezar Cassol ◽  
Jucinei José Comin ◽  
Joice Crescêncio Heidemann ◽  
...  
Keyword(s):  
Adsorption Capacity ◽  
Pig Slurry ◽  
Phosphorus Adsorption

scholarly journals Organic residue, limestone, gypsum, and phosphorus adsorption by lowland soils

2002 ◽  
Vol 59 (2) ◽  
pp. 349-355 ◽  
Author(s):  
Alex Teixeira Andrade ◽  
Luiz Arnaldo Fernandes ◽  
Valdemar Faquin
Keyword(s):  
Low Cost ◽  
Phosphate Adsorption ◽  
Organic Residue ◽  
Organic Residues ◽  
Phosphorus Adsorption ◽  
P Adsorption ◽  
Randomized Design ◽  
Exchangeable Al ◽  
Completely Randomized Design ◽  
Gypsum Application

Organic residue application is a low cost alternative to reduce the use of inorganic fertilizers and correctives. In order to study the effect of organic residues, limestone and gypsum application on phosphorus adsorption by lowland soils, four experiments were carried out. A Mesic Organosol (OY), a Melanic Gleysol (MG), a Haplic Gleysol (GX), and a Fluvic Neosol (RU) were used in a completely randomized design and factorial scheme (3 x 2), with five replicates: three soil amendment practices (limestone, gypsum and no corrective) and two levels of organic residue (with and without corral manure). Soil samples were incubated for 60 days, with and without organic residue incorporation. After this period, we applied the corrective and incubated the soil for 30 days, then P and basic fertilization (macro and micronutrients) were applied and the soil was incubated for additional 60 days. Equilibrium phosphorus, maximum phosphate adsorption capacity, pH, exchangeable Al and phosphorus-buffering index were measured. Organic residue and limestone application increased soil pH and reduced exchangeable Al, decreasing P adsorption. Gypsum application did not increase the pH but reduced exchangeable Al and P adsorption.

scholarly journals Mineralogy and phosphorus adsorption in soils of south and central-west Brazil under conventional and no-tillage systems

2014 ◽  
Vol 36 (3) ◽  
pp. 379 ◽  
Author(s):  
Jessé Rodrigo Fink ◽  
Alberto Vasconcellos Inda ◽  
Cimélio Bayer ◽  
José Torrent ◽  
Vidal Barrón
Keyword(s):  
No Tillage ◽  
Tillage Systems ◽  
Phosphorus Adsorption
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