An Overview of LEACHM: A Process Based Model of Water and Solute Movement, Transformations, Plant Uptake and Chemical Reactions in the Unsaturated Zone

Solute Movement in the Rhizosphere

10.1093/oso/9780195124927.001.0001 ◽

2000 ◽

Cited By ~ 12

Author(s):

Peter B. Tinker ◽

Peter Nye

Keyword(s):

Root System ◽

Plant Uptake ◽

Root Zone ◽

Plant Nutrients ◽

Natural Conditions ◽

Solute Movement

This is a completely revised edition of the previously titled Solute Movement in the Soil-Root System. It describes in detail how plant nutrients and other solutes move in the soil in response to plant uptake, and it provides a basis for understanding processes in the root zone so that they can be modeled realistically in order to predict the effects of variations in natural conditions or our own practices.

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Centrifugal Modeling and Validation of Solute Transport within Unsaturated Zone

Water ◽

10.3390/w11030610 ◽

2019 ◽

Vol 11 (3) ◽

pp. 610

Author(s):

Huanhuan Qin

Keyword(s):

Numerical Modeling ◽

Numerical Model ◽

Solute Transport ◽

Chemical Reactions ◽

Unsaturated Zone ◽

Poor Quality ◽

Physical Processes ◽

Transport Simulation ◽

Reactive Solutes

Numerical modeling has been adopted to assess the feasibility of centrifugal simulation of solute transport within the unsaturated zone. A numerical model was developed to study the centrifugal simulation of nonreactive, adsorption, radionuclide, and reactive solutes. The results showed that it is feasible to conduct centrifugal experiments for nonreactive solute transport. For the solute transport containing physical processes or chemical reactions, if the reaction is very rapid or slow, it is feasible to conduct centrifugal experiments. For the solute transport with a product B generated, if the reaction is relatively slow, the centrifugal prediction of solute is suitable. The centrifugal prediction of solute A matches the prototype quite well, but the prediction of B is in poor quality. If B is the focus, it is not feasible to conduct centrifugal experiments; but if B is not important, the centrifugal modeling is suitable. This has significant implications for the centrifugal modeling application to solute transport simulation within the unsaturated zone.

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Surface reactions observed by photoemission electron microscopy (PEEM)

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100121831 ◽

1992 ◽

Vol 50 (1) ◽

pp. 286-287

Author(s):

H.H. Rotermund

Keyword(s):

Electron Microscopy ◽

Electron Microscope ◽

Work Function ◽

Chemical Reactions ◽

Reaction Diffusion ◽

Dynamic Processes ◽

Clean Surface ◽

Crystal Surfaces ◽

Single Crystal Surfaces ◽

Photoemission Electron

Chemical reactions at a surface will in most cases show a measurable influence on the work function of the clean surface. This change of the work function δφ can be used to image the local distributions of the investigated reaction,.if one of the reacting partners is adsorbed at the surface in form of islands of sufficient size (Δ>0.2μm). These can than be visualized via a photoemission electron microscope (PEEM). Changes of φ as low as 2 meV give already a change in the total intensity of a PEEM picture. To achieve reasonable contrast for an image several 10 meV of δφ are needed. Dynamic processes as surface diffusion of CO or O on single crystal surfaces as well as reaction / diffusion fronts have been observed in real time and space.

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Microwaves: Application in Electron Microscopy

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100158248 ◽

1990 ◽

Vol 48 (3) ◽

pp. 140-141

Author(s):

Anthony S-Y Leong ◽

David W Gove

Keyword(s):

Electron Microscopy ◽

Light Microscopy ◽

Chemical Reactions ◽

Electromagnetic Waves ◽

Tissue Fixation ◽

Primary Method ◽

Dipolar Molecules ◽

Wide Range ◽

Time Required ◽

Cryostat Sections

Microwaves (MW) are electromagnetic waves which are commonly generated at a frequency of 2.45 GHz. When dipolar molecules such as water, the polar side chains of proteins and other molecules with an uneven distribution of electrical charge are exposed to such non-ionizing radiation, they oscillate through 180° at a rate of 2,450 million cycles/s. This rapid kinetic movement results in accelerated chemical reactions and produces instantaneous heat. MWs have recently been applied to a wide range of procedures for light microscopy. MWs generated by domestic ovens have been used as a primary method of tissue fixation, it has been applied to the various stages of tissue processing as well as to a wide variety of staining procedures. This use of MWs has not only resulted in drastic reductions in the time required for tissue fixation, processing and staining, but have also produced better cytologic images in cryostat sections, and more importantly, have resulted in better preservation of cellular antigens.

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Fine structure and properties of defects in naturally occurring silicates and oxides

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s0424820100175430 ◽

1990 ◽

Vol 48 (4) ◽

pp. 460-461

Author(s):

David R. Veblen

Keyword(s):

Chemical Reactions ◽

High Resolution Electron Microscopy ◽

Extended Defects ◽

Single Chain ◽

Naturally Occurring ◽

Resolution Electron ◽

Fine Structures ◽

Image Simulations ◽

Similar Crystal Structure

Extended defects and interfaces control many processes in rock-forming minerals, from chemical reactions to rock deformation. In many cases, it is not the average structure of a defect or interface that is most important, but rather the structure of defect terminations or offsets in an interface. One of the major thrusts of high-resolution electron microscopy in the earth sciences has been to identify the role of defect fine structures in reactions and to determine the structures of such features. This paper will review studies using HREM and image simulations to determine the structures of defects in silicate and oxide minerals and present several examples of the role of defects in mineral chemical reactions. In some cases, the geological occurrence can be used to constrain the diffusional properties of defects.The simplest reactions in minerals involve exsolution (precipitation) of one mineral from another with a similar crystal structure, and pyroxenes (single-chain silicates) provide a good example. Although conventional TEM studies have led to a basic understanding of this sort of phase separation in pyroxenes via spinodal decomposition or nucleation and growth, HREM has provided a much more detailed appreciation of the processes involved.

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