Miscible Displacement and Theoretical Techniques for Simultaneous Study of Pesticide Sorption and Degradation During Transport

2015 ◽  
pp. 115-123
Author(s):  
A. P. Gamerdinger ◽  
Kathryn C. Dowling ◽  
A. T. Lemley
Keyword(s):  
Miscible Displacement ◽  
Simultaneous Study ◽  
Pesticide Sorption

Pesticide Sorption on Geologic Material of Varying Organic Carbon Content

1988 ◽  
Vol 4 (3) ◽  
pp. 341-349 ◽  
Author(s):  
Dermont C. Bouchard ◽  
Alvin L. Wood
Keyword(s):  
Organic Carbon ◽  
Carbon Content ◽  
Carbon Materials ◽  
Miscible Displacement ◽  
Organic Carbon Content ◽  
Soil Columns ◽  
Water Partitioning ◽  
Pesticide Sorption

Sorption of three pesticides on geologic material ranging in organic carbon content from 0.33 to 6.9 g kg-1 was measured in soil columns using a miscible displacement technique. An octanol-water partitioning model was shown to be inappropriate for predicting sorption of the less hydrophobic pesticides on the low organic carbon materials.

Automated Development of Clinical Strategies Using Multistage Decision Analysis

1986 ◽  
Vol 25 (04) ◽  
pp. 207-214 ◽  
Author(s):  
P. Glasziou
Keyword(s):  
Decision Tree ◽  
Decision Analysis ◽  
Decision Trees ◽  
Optimal Strategy ◽  
Cholestatic Jaundice ◽  
Clinical Strategies ◽  
Simultaneous Study

SummaryThe development of investigative strategies by decision analysis has been achieved by explicitly drawing the decision tree, either by hand or on computer. This paper discusses the feasibility of automatically generating and analysing decision trees from a description of the investigations and the treatment problem. The investigation of cholestatic jaundice is used to illustrate the technique.Methods to decrease the number of calculations required are presented. It is shown that this method makes practical the simultaneous study of at least half a dozen investigations. However, some new problems arise due to the possible complexity of the resulting optimal strategy. If protocol errors and delays due to testing are considered, simpler strategies become desirable. Generation and assessment of these simpler strategies are discussed with examples.

Simulation of Miscible Displacement in Full-Diameter Carbonate Cores

1982 ◽  
Vol 22 (05) ◽  
pp. 647-657 ◽  
Author(s):  
J.P. Batycky ◽  
B.B. Maini ◽  
D.B. Fisher
Keyword(s):  
Oil Recovery ◽  
Water Saturation ◽  
Accurate Determination ◽  
Miscible Displacement ◽  
Carbonate Reservoir ◽  
Core Material ◽  
Immiscible Fluid ◽  
Displacement Efficiency ◽  
Carbonate Cores ◽  
Capacitance Model

Abstract Miscible gas displacement data obtained from full-diameter carbonate reservoir cores have been fitted to a modified miscible flow dispersion-capacitance model. Starting with earlier approaches, we have synthesized an algorithm that provides rapid and accurate determination of the three parameters included in the model: the dispersion coefficient, the flowing fraction of displaceable volume, and the rate constant for mass transfer between flowing and stagnant volumes. Quality of fit is verified with a finite-difference simulation. The dependencies of the three parameters have been evaluated as functions of the displacement velocity and of the water saturation within four carbonate cores composed of various amounts of matrix, vug, and fracture porosity. Numerical simulation of a composite core made by stacking three of the individual cores has been compared with the experimental data. For comparison, an analysis of Berea sandstone gas displacement also has been provided. Although the sandstone displays a minor dependence of gas recovery on water saturation, we found that the carbonate cores are strongly affected by water content. Such behavior would not be measurable if small carbonate samples that can reflect only matrix properties were used. This study therefore represents a significant assessment of the dispersion-capacitance model for carbonate cores and its ability to reflect changes in pore interconnectivity that accompany water saturation alteration. Introduction Miscible displacement processes are used widely in various aspects of oil recovery. A solvent slug injected into a reservoir can be used to displace miscibly either oil or gas. The necessary slug size is determined by the rate at which deterioration can occur as the slug is Another commonly used miscible process involves addition of a small slug within the injected fluids or gases to determine the nature and extent of inter well communication. The quantity of tracer material used is dictated by analytical detection capabilities and by an understanding of the miscible displacement properties of the reservoir. We can develop such understanding by performing one-dimensional (1D) step-change miscible displacement experiments within the laboratory with selected reservoir core material. The effluent profiles derived from the experiments then are fitted to a suitable mathematical model to express the behavior of each rock type through the use of a relatively small number of parameters. This paper illustrates the efficient application of the three-parameter, dispersion-capacitance model. Its application previously has been limited to use with small homogeneous plugs normally composed of intergranular and intencrystalline porosity, and its suitability for use with cores displaying macroscopic heterogeneity has been questioned. Consequently, in addition to illustrating its use with a homogeneous sandstone, we fit data derived from previously reported full-diameter carbonate cores. As noted earlier, these cores were heterogeneous, and each of them displayed different dual or multiple types of porosity characteristic of vugular and fractured carbonate rocks. Dispersion-Capacitance Model The displacement efficiency of one fluid by a second immiscible fluid within a porous medium depends on the complexity of rock and fluid properties. SPEJ P. 647^

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