Multi-Disciplinary Research for High Energy Chemical Lasers, Closed-Cycle ElectricOIL Technology

Combustion of high-energy chemical fuels containing chlorine in the element structure can lead to formation in the particles of smoke of super eco toxicants—the polychlorinated dioxins and furans. The numerical experiment conducted was based on solution of the equations of chemical kinetics. The computational and theoretical researches directed to the solution of a problem of determination of parameters of combustion products of chemical fuels taking into account formation of harbingers of the polychlorinated dioxins were executed. The main data on the accepted method of determination of disequilibrium structures of products of burning the chlorine-containing chemical fuels were represented. Based on the analysis of references about mechanisms and speeds of chemical reactions of transformations of chlorine-containing connections, the kinetic model of formation of predecessors of dioxins is constructed. The carried-out calculations showed (assuming chemical balance) that process of formation of dioxins is significantly disequilibrious. The results of kinetic researches on emission of harbingers of dioxins showed the nature of the influence of different components of combustion products of chemical fuels on time for the different levels of temperatures.

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Organocatalyzed Birch Reduction Driven by Visible Light

10.26434/chemrxiv.11860221 ◽

2020 ◽

Author(s):

Justin P. Cole ◽

Dian-Feng Chen ◽

Max Kudisch ◽

Ryan M. Pearson ◽

Chern-Hooi Lim ◽

...

Keyword(s):

Visible Light ◽

Alkali Metals ◽

High Energy ◽

Cryogenic Liquid ◽

Solvated Electrons ◽

Mole Percent ◽

Birch Reduction ◽

Application Potential ◽

Molecular Complexity ◽

High Energy Chemical

<p>The Birch reduction is a powerful synthetic methodology that uses solvated electrons to convert inert arenes to 1,4-cyclohexadienes—valuable intermediates for building molecular complexity. This reaction historically requires dangerous alkali metals and cryogenic liquid ammonia as the solvent, severely limiting application potential and scalability. Here, we introduce benzo[ghi]perylene imides as new organic photoredox catalysts for Birch reductions performed at ambient temperature and driven by visible light. Using low catalyst loadings (<1 mole percent), benzene and other functionalized arenes can be selectively transformed to 1,4-cyclohexadienes in good yields. Mechanistic studies support that this unprecedented visible light induced reactivity is enabled by the ability of the organic photoredox catalyst to harness the energy from two visible light photons to affect a single, high energy chemical transformation, likely proceeding through a solvated electron.</p>

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