Probing the Intermolecular Hydrogen Bonding of Water Molecules at the CCl sub 4 Water Interface in the Presence of Charged Soluble Surfactant.

1998 ◽  
Author(s):  
D. E. Gragson ◽  
G. L. Richmond
Keyword(s):  
Hydrogen Bonding ◽  
Water Molecules ◽  
Intermolecular Hydrogen Bonding ◽  
Water Interface ◽  
Soluble Surfactant

A trinuclear copper(II) complex: triaquachlorotriperchloratobis[μ2-3-(2-pyridylmethylamino)butyrato]tricopper(II) dihydrate

2006 ◽  
Vol 62 (4) ◽  
pp. m690-m692
Author(s):  
Ki-Young Choi ◽  
Kyu-Chul Lee ◽  
Han-Hyoung Lee ◽  
Jaejung Ko ◽  
Won-Sik Han
Keyword(s):  
Hydrogen Bonding ◽  
Title Compound ◽  
Water Molecules ◽  
Intermolecular Hydrogen Bonding ◽  
Carboxylate Groups ◽  
Square Planar

In the title compound, [Cu3(C10H13N2O2)2Cl(ClO4)3(H2O)3]·2H2O, the Cu atoms exhibit octahedral, square-pyramidal and square-planar coordination environments, and they are linked by carboxylate groups to form a trinuclear structure. The five water molecules participate in intra- and intermolecular hydrogen bonding.

scholarly journals catena-Poly[[diaqua(1,10-phenanthroline-κ2N,N′)nickel(II)]-μ-1H-benzimidazole-5,6-dicarboxylato-κ2N3:O6]

2009 ◽  
Vol 65 (6) ◽  
pp. m701-m701 ◽  
Author(s):  
Wen-Dong Song ◽  
Hao Wang ◽  
Shi-Wei Hu ◽  
Pei-Wen Qin ◽  
Shi-Jie Li
Keyword(s):  
Hydrogen Bonding ◽  
Crystal Packing ◽  
Title Complex ◽  
Water Molecules ◽  
Zigzag Chain ◽  
Intermolecular Hydrogen Bonding ◽  
Hydrogen Bonding Interactions ◽  
Phenanthroline Ligand

In the title complex, [Ni(C9H4N2O4)(C12H8N2)(H2O)2]n, the NiIIatom is hexacoordinated by one N and one O atom from two different 1H-benzimidazole-5,6-dicarboxylate ligands, two N atoms from one 1,10-phenanthroline ligand and two water molecules. The flexible 1H-benzimidazole-5,6-dicarboxylate ligands link the NiIIcentres, forming an infinite zigzag chain parallel to [001]. The crystal packing is governed by intermolecular hydrogen-bonding interactions of the O—H...O, N—H...O and C—H...O types.

Chlorobis(1,10-phenanthroline-κ2 N,N′)copper(II) 4-aminobenzenesulfonate trihydrate

2006 ◽  
Vol 62 (7) ◽  
pp. m1592-m1594 ◽  
Author(s):  
Ai-Xiang Sui ◽  
Gang Zhu ◽  
Zong-Xun Tang
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Title Compound ◽  
Chloride Anion ◽  
Water Molecules ◽  
Intermolecular Hydrogen Bonding ◽  
Phenanthroline Ligands

The crystal structure of the title compound, [CuCl(C12H8N2)2](C6H6NO3S)·3H2O, contains CuII cations five-coordinated by one chloride anion and four N atoms of two 1,10-phenanthroline ligands. Between the the 4-aminobenzenesulfonate anions and the uncoordinated water molecules intermolecular hydrogen bonding is found.

Disodium 5,5′-diamino-2,2′-ethylenedibenzenesulfonate tetrahydrate

2007 ◽  
Vol 63 (11) ◽  
pp. m2714-m2714 ◽  
Author(s):  
Stéphane Dufresne ◽  
Michael Gaultois ◽  
W. G. Skene
Keyword(s):  
Hydrogen Bonding ◽  
Geometric Isomer ◽  
Disodium Salt ◽  
Water Molecules ◽  
Intermolecular Hydrogen Bonding ◽  
Π Stacking ◽  
Benzene Rings ◽  
The Mean ◽  
Unsaturated Group

In the title disodium salt, 2Na+·C14H12N2O6S2 2−·4H2O, the two aryl units of the centrosymmetric anion are coplanar. The E geometric isomer was exclusively found, while the mean plane of the unsaturated group is twisted by 10.1 (2)° from the mean plane described by the two aminobenzenes. Four water molecules cocrystallize and participate in intermolecular hydrogen bonding. The anions lie in parallel planes separated by 3.367 (16) Å and their symmetry-related benzene rings are separated by 3.84 (1) Å, leading to weak intermolecular π-stacking.

scholarly journals Tetraaqua[2,6-diacetylpyridine bis(semicarbazone)]samarium(III) trinitrate

IUCrData ◽  
2018 ◽  
Vol 3 (10) ◽  
Author(s):  
Michael Gioia ◽  
Guy Crundwell ◽  
Barry L. Westcott
Keyword(s):  
Hydrogen Bonding ◽  
Metal Cation ◽  
Nitrate Group ◽  
Trigonal Prism ◽  
Water Molecules ◽  
Intermolecular Hydrogen Bonding ◽  
Lanthanide Nitrate ◽  
Tricapped Trigonal Prism ◽  
Nitrate Salts ◽  
Coordinated Water

The structure of tetraaqua[2,6-diacetylpyridine bis(semicarbazone)]samarium(III) trinitrate, [Sm(C11H15N7O2)(H2O)4](NO3)3, has monoclinic (P21/c) symmetry. The 2,6-diacetylpyridine (DAPSC) ligand is pentadentate. The coordination of the DAPSC ligand and four coordinated water molecules around the metal cation is best described as a distorted tricapped trigonal prism. The structure displays intermolecular hydrogen bonding. The structure is isomorphous with many other published lanthanide(III) nitrate salts with the DAPSC ligand, 2,6-diacetylpyridinebis(semicarbazone). One of the three nitrate counter-anions is disordered, which is consistent with the structures of other +3 lanthanide nitrate salts with DAPSC. Refinement of occupancies for the disordered nitrate group gave major and minor occupancies of 54.9 (14) and 45.1 (14)%, respectively.

Three new quinuclidine-based structures: second harmonic generation response for 1,2-bis(1-azoniabicyclo[2.2.2]octan-3-ylidene)hydrazine dichloride

2019 ◽  
Vol 75 (6) ◽  
pp. 728-733
Author(s):  
Liang Qiao ◽  
Xiao-Gang Chen ◽  
Ji-Xing Gao ◽  
Yong Ai
Keyword(s):  
Hydrogen Bonding ◽  
Second Harmonic ◽  
Three Dimensional ◽  
Water Molecules ◽  
Intermolecular Hydrogen Bonding ◽  
Two Dimensional ◽  
Hydrazine Monohydrate ◽  
Space Group ◽  
Dimensional Network ◽  
C And N

The crystal structures of three quinuclidine-based compounds, namely (1-azabicyclo[2.2.2]octan-3-ylidene)hydrazine monohydrate, C7H13N3·H2O (1), 1,2-bis(1-azabicyclo[2.2.2]octan-3-ylidene)hydrazine, C14H22N4 (2), and 1,2-bis(1-azoniabicyclo[2.2.2]octan-3-ylidene)hydrazine dichloride, C14H24N4 2+·2Cl− (3), are reported. In the crystal structure of 1, the quinuclidine-substituted hydrazine and water molecules are linked through N—H...O and O—H...N hydrogen bonds, forming a two-dimensional array. The compound crystallizes in the centrosymmetric space group P21/c. Compound 2 was refined in the space group Pccn and exhibits no hydrogen bonding. However, its hydrochloride form 3 crystallizes in the noncentrosymmetric space group Pc. It shows a three-dimensional network structure via intermolecular hydrogen bonding (N—H...C and N/C—H...Cl). Compound 3, with its acentric structure, shows strong second harmonic activity.

scholarly journals Protonation sites and hydrogen bonding in mono-hydrobromide salts of two N,4-diheteroaryl 2-aminothiazoles

2021 ◽  
Author(s):  
Denise Böck ◽  
Andreas Beuchel ◽  
Richard Goddard ◽  
Adrian Richter ◽  
Peter Imming ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Hydrogen Bonds ◽  
Three Dimensional ◽  
Water Molecules ◽  
Monoclinic Space Group ◽  
Intermolecular Hydrogen Bonding ◽  
Molecular Conformations ◽  
Space Group ◽  
Hydrogen Bonded

AbstractThe synthesis and structural characterization of N-(6-methoxypyridin-3-yl)-4-(pyridin-2-yl)thiazol-2-amine mono-hydrobromide monohydrate (3) and N-(6-methoxypyridin-3-yl)-4-(pyrazin-2-yl)thiazol-2-amine mono-hydrobromide 0.35 methanol solvate (4) are reported. The crystal structures of 3 (monoclinic, space group P21/n, Z = 4) and 4 (monoclinic, space group, C2/c, Z = 8) feature N,4-diheteroaryl 2-aminothiazoles showing similar molecular conformations but different sites of protonation and thus distinctly different intermolecular hydrogen bonding patterns. In 3, Namine–H⋯Br−, N+pyridine–H⋯Owater, and Owater–H⋯Br− hydrogen bonds link protonated N-(6-methoxypyridin-3-yl)-4-(pyridin-2-yl)thiazol-2-amine and water molecules and bromide anions into a three-dimensional hydrogen-bonded network, whereas intermolecular N+methoxypyridine–H⋯Npyrazine hydrogen bonds result in hydrogen-bonded zigzag chains of protonated N-(6-methoxypyridin-3-yl)-4-(pyrazin-2-yl)thiazol-2-amine molecules in 4.

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