Determination of Trivalent Chromium in Chromium Plating Solutions Using a Redox Titration and Indicator

1992 ◽  
Author(s):  
Samuel Sopok
1995 ◽  
Vol 93 (5) ◽  
pp. 12-18 ◽  
Author(s):  
S. Nikolova ◽  
T. Dobrev ◽  
M. Monev

1980 ◽  
Vol 6 (3) ◽  
pp. 222-222 ◽  
Author(s):  
D. Burrows ◽  
M. A. Cooke

2018 ◽  
Vol 65 (5) ◽  
pp. 499-505 ◽  
Author(s):  
Vyacheslav Protsenko ◽  
Lina Bobrova ◽  
Felix Danilov

Purpose This paper aims to investigate the electrolytic deposition of corrosion-resistant chromium coatings from a trivalent chromium plating bath based on deep eutectic solvent, a new generation of room temperature ionic liquids. Design/methodology/approach The electrolyte contained chromium (III) chloride, choline chloride and the additive of extra water. The surface morphology was estimated by means of SEM technique. The microstructure of as-deposited and annealed coatings was studied using X-ray diffraction method. The kinetics of the chromium electrodeposition and the corrosion electrochemical behavior of the coatings were investigated by cyclic voltammetry technique. Findings Chromium coatings with an amorphous type of microstructure are electroplated from this bath. Some carbon and oxygen are included in deposits obtained. The step-wise mechanism of the electrochemical reduction of Cr(III) ions to Cr(0) is detected. The current efficiency in this system sufficiently exceeds that typical of usual aqueous electrolytes. The coatings fabricated using plating bath based on deep eutectic solvent showed enhanced corrosion resistance in an acidic medium: there is no current peak of active dissolution in polarization curve and the corrosion potential shifts to more positive values as compared with “usual” chromium. Originality/value The electrodeposition of chromium coatings from an environmentally acceptable trivalent chromium electrolyte, a deep eutectic solvent containing chloride choline and extra water additive has been investigated for the first time.


2020 ◽  
Vol MA2020-01 (20) ◽  
pp. 1247-1247
Author(s):  
German Orozco ◽  
Julieta Torres-González ◽  
Dennys Fernandez

1991 ◽  
Vol 7 (Supple) ◽  
pp. 1205-1206
Author(s):  
Keiji KANEKO ◽  
Hiroko KANEKO ◽  
Hideo IHARA ◽  
Norio TERADA ◽  
Masatashl JHO ◽  
...  

Talanta ◽  
1979 ◽  
Vol 26 (4) ◽  
pp. 330-332 ◽  
Author(s):  
A Godbole
Keyword(s):  

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