High Resolution Nuclear Magnetic Resonance Spectra of the Pentafluorosulfur Group (TR-31) and Nuclear Magnetic Resonance Spectra of Some Hypofluorites (TR-32)

1961 ◽  
Author(s):  
WASHINGTON UNIV SEATTLE DEPT OF CHEMISTRY
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
High Resolution ◽  
Nuclear Magnetic Resonance Spectra ◽  
Magnetic Resonance Spectra ◽  
Nuclear Magnetic

High-resolution nuclear-magnetic-resonance spectra of hydrocarbon groupings - V. ABCX spectra of vinyl fluoride and 3-methylbut-l-ene

1961 ◽  
Vol 263 (1312) ◽  
pp. 136-148 ◽  
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
High Resolution ◽  
Coupling Constants ◽  
Vinyl Fluoride ◽  
General Properties ◽  
Nuclear Magnetic Resonance Spectra ◽  
Magnetic Resonance Spectra ◽  
Nuclear Magnetic

Some general properties of ABCX -type spectra are discussed. It is shown that it is possible to deduce from such spectra the relative signs of all inter-nuclear coupling constants. Analyses are presented of the hydrogen (proton) spectra from the vinyl groups of vinyl fluoride and 3-methylbut-l-ene, and of the fluorine spectrum of the former molecule. It is shown that all HF coupling constants in vinyl fluoride are of the same sign as the cis and trans HH coupling constants.

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