ABSORPTION COEFFICIENTS OF SEVERAL ATMOSPHERIC GASES

Author(s):  
K. Watanabe ◽  
Murray Zelikoff ◽  
Edward C. Inn
1874 ◽  
Vol 22 (148-155) ◽  
pp. 192-196 ◽  

Until lately it was believed that the atmospheric gases dissolved in sea-water could be extracted from it, as from fresh water, by boiling in vacuo . The merit of the discovery that such is not the case is due to Dr. Jacobsen, of Kiel, who found that, in order to drive out the whole of the carbonic acid, the water must be evaporated almost to dryness, and that no amount of boiling in vacuo will suffice to eliminate it. Being particularly interested in the matter, I immediately commenced a series of experiments to determine, if possible, the salt or salts to which sea-water owes this property. Preliminary observations satisfied me, in the first place, that sea-water has this property, and, secondly, that solutions of the sulphates of magnesia and of lime possess the same property. In order to gain more precise information, two series of experiments were made, the one analytical, the other synthetical. The former consisted in saturating saline solutions with carbonic acid, and then distilling them, the carbonic acid passing in the various fractions being determined; the latter, in determining the absorption coefficients of two solutions, the one of sulphate of magnesia, the other of sulphate of lime.


1962 ◽  
Vol 40 (1) ◽  
pp. 122-127 ◽  
Author(s):  
R. Heastie ◽  
D. H. Martin

The recent development of spectroscopic techniques for extreme infrared frequencies, below 100 cm−1, has enabled us to observe collision-induced absorption in non-polar gases, viz. oxygen, nitrogen, air, and helium–argon mixtures. This absorption results from the modulation of the distortion dipole moment of each pair of colliding molecules by their rotational and translational motions. It is of the kind observed previously at higher frequencies by Kiss, Gush, and Welsh using hydrogen gas. By making measurements at pressures up to 120 atmospheres, the absorption coefficients have been determined over the frequency range 30–100 cm−1.Attention is drawn to the possibilities that such processes may play a role in atmospheric energy balance and might give rise to significant attenuation if beams of infrared radiation were used for communications.


Author(s):  
M. E. Twigg ◽  
B. R. Bennett ◽  
J. R. Waterman ◽  
J. L. Davis ◽  
B. V. Shanabrook ◽  
...  

Recently, the GaSb/InAs superlattice system has received renewed attention. The interest stems from a model demonstrating that short period Ga1-xInxSb/InAs superlattices will have both a band gap less than 100 meV and high optical absorption coefficients, principal requirements for infrared detector applications. Because this superlattice system contains two species of cations and anions, it is possible to prepare either InSb-like or GaAs-like interfaces. As such, the system presents a unique opportunity to examine interfacial properties.We used molecular beam epitaxy (MBE) to prepare an extensive set of GaSb/InAs superlattices grown on an GaSb buffer, which, in turn had been grown on a (100) GaAs substrate. Through appropriate shutter sequences, the interfaces were directed to assume either an InSb-like or GaAs-like character. These superlattices were then studied with a variety of ex-situ probes such as x-ray diffraction and Raman spectroscopy. These probes confirmed that, indeed, predominantly InSb-like and GaAs-like interfaces had been achieved.


Author(s):  
Leonid E. Paramonov

A method for retrieving the absorption coefficients of Spirulina platensis pigments using absorption spectra of native cells and excluding the use of extracts is considered. Estimates of the intracellular concentration of chlorophyll a, С-phycoerythrin, С- phycocyanin and allophycocyanin in native cells are discussed.


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