Synergistic Properties of Phosphonate and Polymeric Scale Inhibitor Blends for Barium Sulphate Scale Inhibition

2014 ◽  
Author(s):  
S.S.. S. Shaw ◽  
K.S.. S. Sorbie
Keyword(s):  
Oil And Gas ◽  
Production Systems ◽  
Barium Sulphate ◽  
Gas Production ◽  
Test Results ◽  
Oil And Gas Production ◽  
Scale Inhibition ◽  
Inhibition Performance ◽  
The Individual ◽  
Better Than

Abstract Barium sulphate is one of the most difficult types of scale to inhibit in oil and gas production systems, due to its physical hardness and its chemical and thermal stability. Barium sulphate is most commonly inhibited using either phosphonate or polymeric scale inhibitors (SIs) deployed at sub-stoichiometric concentrations. What is less well known in the oil industry is the effect of using combinations of two (or more) SIs synergistically for enhanced scale inhibition performance. A positive “synergistic” effect would be where, for example, 5ppm of A + 5ppm of B performed better than 10ppm of either A or B. In this paper, a series of static barium sulphate inhibition efficiency (IE) test results are presented, in which a series of pairs of SIs have been tested to determine their synergistic properties at pH 5.5 and 95°C. Polymers can be blended with phosphonates, or alternatively pairs of phosphonates or polymers may be applied. In all cases, the synergistic IE is compared with the IE of each SI tested independently at the mass dosage (i.e. the same concentration in mg/L or ppm). Each separate single SI used in the work has been tested previously for barium sulphate IE at pH 5.5, 95°C in order to determine the minimum inhibitor concentration (MIC) for each species (Shaw et al, 2012a, 2012b). Previously, 9 phosphonate and 9 polymeric SIs have been tested individually and, in this work, 34 SI combinations have been tested to examine their synergistic properties. The MICs of the synergistic blends are compared with the normal MICs of the individual SIs. Surprisingly, in most cases, the IE of the blends is usually higher over the range of SI concentrations tested (i.e. the MIC of the blend is lower), compared to that of each SI tested separately. Certain “pairs” of SIs used together yield a significantly beneficial effect, e.g. DETPMP and HMTPMP. Some mechanistic reasons why these synergistic pairs work particularly well are suggested.

Characterization and Prediction of Chemical Inhibition Performance for Erosion-Corrosion Conditions in Sweet Oil and Gas Production

CORROSION ◽  
10.5006/0546 ◽  
2012 ◽  
Vol 68 (10) ◽  
pp. 885-896 ◽  
Author(s):  
Sh. Hassani ◽  
K.P. Roberts ◽  
S.A. Shirazi ◽  
J.R. Shadley ◽  
E.F. Rybicki ◽  
...  
Keyword(s):  
Oil And Gas ◽  
Gas Production ◽  
Oil And Gas Production ◽  
Erosion Corrosion ◽  
Chemical Inhibition ◽  
Inhibition Performance

scholarly journals Evaluation of Calcium Carbonate Inhibitors Using Sintered Metal Filter in a Pressurized Dynamic System

Materials ◽  
2019 ◽  
Vol 12 (11) ◽  
pp. 1849 ◽  
Author(s):  
Adriana Velloso Alves de Souza ◽  
Francisca Rosário ◽  
João Cajaiba
Keyword(s):  
Calcium Carbonate ◽  
Dynamic System ◽  
Heterogeneous Nucleation ◽  
Oil And Gas ◽  
Production Systems ◽  
Dynamic Test ◽  
Gas Production ◽  
Oil And Gas Production ◽  
Sintered Metal ◽  
Organophosphorus Inhibitors

Calcium carbonate scale is formed during oil and gas production. Tube-blocking tests (TBTs) are used to define the minimum inhibitory concentration (MIC) in order to prevent scale adhesion in the petroleum production system equipment. However, non-adhered crystals may favor heterogeneous nucleation to other deposits such as calcium naphthenates, causing a more severe scale problem, increasing production losses and treatment costs. The objective of the present work was to develop a new dynamic test methodology to determine the MIC for CaCO3 using a sintered metal filter. Organophosphorus inhibitors were selected for comparison with the conventional dynamic tube-blocking system. The results demonstrated that the use of the filter allowed an MIC of the inhibitors to be obtained considering the precipitation prevention. The inhibitor concentration in the conventional tube-blocking system does not prevent precipitation, acting only on adhesion and crystal growth on the capillary wall. Tests to evaluate the potential of calcium naphthenates formation in a naphthenate flow rig dynamic system demonstrated the influence of heterogeneous nucleation from non-adhered carbonate crystals, potentially aggravating deposition problems in oil and gas production systems.

Exergoeconomic Optimization of Oil and Gas Production Systems

2020 ◽  
Author(s):  
Meziane Akchiche ◽  
Jean-Louis Beauquin ◽  
Sabine Sochard ◽  
Sylvain Serra ◽  
Jean-Michel Reneaume ◽  
...  
Keyword(s):  
Oil And Gas ◽  
Production Systems ◽  
Gas Production ◽  
Oil And Gas Production

Erosion of Elbows in Oil and Gas Production Systems

2012 ◽  
Vol 479-481 ◽  
pp. 1129-1132
Author(s):  
Wang Ming Bo
Keyword(s):  
Oil And Gas ◽  
Production Systems ◽  
Oil And Gas Industry ◽  
Gas Production ◽  
Gas Industry ◽  
Oil And Gas Production ◽  
Sand Erosion ◽  
The Subject ◽  
Erosion Mechanisms ◽  
Definitive Methods

This paper gives an overview of erosion mechanisms in elbows in oil and gas production systems. The nature of the erosion process itself makes it very difficult to develop some definitive methods or models to prevent or predict the erosion in elbows in all conditions. This paper provides a review of the subject which will help petroleum engineers to handle the erosion problems in oil and gas industry. This review is given of different erosion mechanisms connected with sand erosion and the factors that influence them, and then the review goes on to look at particulate erosion in elbows in more details. Conclusions are then drawn based on the above analyses.

A Method for the Verification of Subsea Equipment Subject to Hydrogen Induced Stress Cracking

2010 ◽  
Author(s):  
Michelangelo Fabbrizzi ◽  
Paolo Di Sisto ◽  
Roberto Merlo
Keyword(s):  
Oil And Gas ◽  
Production Systems ◽  
Local Stress ◽  
Gas Production ◽  
Stress And Strain ◽  
3D Analysis ◽  
Oil And Gas Production ◽  
Safety Issues ◽  
Stress Cracking ◽  
Induced Stress

Subsea oil and gas production systems can be subject to Hydrogen Induced Stress Cracking (“HISC”) depending on the material, cathodic protection and other factors. A failure in this kind of systems can lead to safety issues as well as environmental hazards and high repair costs. The analysis of recent failures has led to the recognition of HISC as a very important issue related to local stress and strain. This has necessitated the extensive use of Finite Elements Methods for the analysis of all system components. Since HISC is a recent issue, there are very few cases of such assessments reported in the literature. This paper is based on the assessment of the susceptibility of subsea piping manifolds of Duplex stainless steel to Hydrogen Induced Stress Cracking, which was conducted during the Skarv project by General Electric Oil & Gas. A variety of cases consisting of different loads and configurations were considered to give a broad assessment using a recently developed code (DNV-RP-F112-October2008). This work has led to the development of a set of procedures and models for the assessment of the entire system which is described in the current paper. The proposed methodology is useful for both design purposes and also for the verification of parts, which, if found to be non-compliant, would require redesign. In general, parts that were determined to be non-compliant using a linear assessment were found to be compliant through non-linear analysis, in fact 3D plastic analysis leads to a redistribution of stress and strain and hence, to lower values. “Cold creep” was not considered since the levels of stress and strain were considered to be low enough to avoid this phenomenon. As a consequence of this experience, a new methodology was developed, which is able to speed up the analysis process and to predict local stresses from only pipe elements. The latter permits the use of a linear assessment for bends, T junctions and weldolet even with misalignment and erosion, avoiding the need to perform 3D analysis. The second part of the paper describes this method.

Experience With Qualification and Use of Stainless Steels in Subsea Pipelines

2004 ◽  
Author(s):  
Per Egil Kvaale ◽  
Tore Ha˚brekke ◽  
Gisle Ro̸rvik
Keyword(s):  
Stainless Steels ◽  
Oil And Gas ◽  
Production Systems ◽  
Gas Production ◽  
Inconel 625 ◽  
Oil And Gas Production ◽  
Internal Corrosion ◽  
Carbon Manganese Steels ◽  
Subsea Pipelines ◽  
Incoloy 825

Use of stainless steels in subsea oil and gas production systems have been common through the development of remote controlled subsea oil and gas production systems. Stainless steels are mainly selected to minimize the corrosion due to unprocessed oil and gas and thereby simplifying the internal corrosion protection challenges. Different materials and principles have been implemented from cladding of Carbon Manganese steels to the use of solid stainless steels. For cladding Incoloy 825 or Inconel 625 is common, while the solid stainless steels have been duplex, superduplex or 13%Cr steels in pipes and pipe fittings. Experience from service has shown that these materials have limits in their use, and it is reported various cases where the stainless steels have failed. The present paper will deal with a few examples of failures and possible reasons for these failures.

Evaluation of TG202 inhibitor for tubing steels in 15% hydrochloric acid by electrochemical noise technology

2021 ◽  
Author(s):  
Mi-feng Zhao ◽  
Juantao Zhang ◽  
Fangting Hu ◽  
Anqing Fu ◽  
Kelin Wang ◽  
...  
Keyword(s):  
Hydrochloric Acid ◽  
Corrosion Rate ◽  
Oil And Gas ◽  
Electrochemical Noise ◽  
Gas Production ◽  
Inhibition Mechanism ◽  
Oil And Gas Production ◽  
Effective Technology ◽  
Steel Tubing ◽  
Inhibition Performance

Abstract Acid fracturing is an effective technology for increasing oil and gas production. However, acid will cause serious corrosion to the tubing. In this paper, the inhibition performance of TG202 inhibitor for acidizing of high temperature and high pressure gas wells on N80 carbon steel and 13Cr martensitic stainless steel tubing in 15% hydrochloric acid was studied by electrochemical noise technology. The results showed that with the increase of TG202 inhibitor content, the noise resistance increased and the corrosion rate of tubing steel decreased. Under the same condition, the order of corrosion rate of tubing steels: 13Cr > HP-13Cr > N80 > P110. The pitting corrosion of HP-13Cr and 13Cr is significant. The research showed that TG202 inhibitor had a protective effect on tubing during acidizing. The inhibition mechanism of TG202 inhibitor was discussed.

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