Steady-State Measurements of Relative Permeability for Polymer/Oil Systems

1982 ◽  
Vol 22 (01) ◽  
pp. 79-86 ◽  
Author(s):  
F.N. Schneider ◽  
W.W. Owens

Abstract Means for increasing tertiary oil recoveries from previously waterflooded viscous oil reservoirs are receiving added attention today as a result of industry-wide efforts to improve U.S. oil producing rates and reserves. Injection of a bank of polymer solution that precedes injection of a miscible slug (e.g., a micellar fluid) can reduce reservoir permeability contrasts and result in improvement of the sweep efficiency of the process. To evaluate the potential magnitude of improved recovery and economics of prior polymer slug injection, there is a need for basic polymer/oil relative permeability data for use in performance evaluation calculations. Such relative permeability data were measured by steady-state procedures on a suite of 18 out-crop and formation core samples ranging, in permeability from about 50 to 1,200 md. Six different polyacrylamide polymers were tested, and resistance and residual resistance data were obtained on each. Data were obtained in both oil-wet and water-wet systems. The observation in these studies was that the presence of polymers in the water phase had a significant and consistent effect, lowering water relative permeability over the entire water saturation range. In many of the tests, the presence of flowing polymer or its residual effect during subsequent brine flow had no effect on oil relative permeability. In several tests, polymer contact actually improved oil mobility through increases in oil relative permeability at all levels of oil saturation. Permeability level and polymer type produced no clear-cut differences in flow behavior. The obvious differences in core wettability resulted in widely varying relative permeability characteristics, but again the effect of polymer contact was about the same, qualitatively, as obtained on the water-wet cores. Introduction The steady decline of U.S. oil reserves and rapidly, increasing, prices obtained for each barrel of crude produced are strong incentives to maximize recoveries for all reservoirs. Various enhanced oil recovery techniques are being tested and used for recovering some of the oil left behind after conventional waterflooding. The added recovery achievable with such processes, however, is influenced to a large degree by one of the same factors leading to inefficient waterflooding - i.e., reservoir heterogeneity. Numerous laboratory studies using, both physical and mathematical models, plus numerous field projects, have shown that when contrasts in reservoir permeability increase, recovered by any external injection recovery process decreases as a result of reduced sweep efficiency. Thus, if recoveries from the more heterogeneous reservoirs are to be maximized, procedures must be developed for reducing the permeability contrasts before application of an EOR process or by mobility adjustment within the process itself. Preinjection of polymers in advance of a micellar flood has been proposed as a means for improving reservoir sweep efficiency by reducing permeability contrasts. Laboratory tests of this process demonstrated that, in both linear and five-spot stratified systems, the residual resistance effect achieved by preinjection of poly-acrylamide polymers resulted in improved sweep and additional recovery by subsequent micellar flooding. In the one reported field test of this process, tertiary oil was mobilized and recovered, but insufficient data are available to indicate whether the preinjected polymer resulted in improved sweep efficiency. Mathematical model studies provide a reliable means for evaluating potential benefits of polymer preinjection. However, such studies require input data that permit the model to simulate the physical processes that may occur in the reservoir. This laboratory study was conducted to provide such data. SPEJ P. 79^

2014 ◽  
Vol 18 (02) ◽  
pp. 273-283 ◽  
Author(s):  
W. R. Rossen ◽  
C. S. Boeije

Summary Foam improves sweep in miscible and immiscible gas-injection enhanced-oil-recovery processes. Surfactant-alternating-gas (SAG) foam processes offer many advantages over coinjection of foam for both operational and sweep-efficiency reasons. The success of a foam SAG process depends on foam behavior at very low injected-water fraction (high foam quality). This means that fitting data to a typical scan of foam behavior as a function of foam quality can miss conditions essential to the success of an SAG process. The result can be inaccurate scaleup of results to field application. We illustrate how to fit foam-model parameters to steady-state foam data for application to injection of a gas slug in an SAG foam process. Dynamic SAG corefloods can be unreliable for several reasons. These include failure to reach local steady state (because of slow foam generation), the increased effect of dispersion at the core scale, and the capillary end effect. For current foam models, the behavior of foam in SAG depends on three parameters: the mobility of full-strength foam, the capillary pressure or water saturation at which foam collapses, and the parameter governing the abruptness of this collapse. We illustrate the fitting of these model parameters to coreflood data, and the challenges that can arise in the fitting process, with the published foam data of Persoff et al. (1991) and Ma et al. (2013). For illustration, we use the foam model in the widely used STARS (Cheng et al. 2000) simulator. Accurate water-saturation data are essential to making a reliable fit to the data. Model fits to a given experiment may result in inaccurate extrapolation to mobility at the wellbore and, therefore, inaccurate predicted injectivity: for instance, a model fit in which foam does not collapse even at extremely large capillary pressure at the wellbore. We show how the insights of fractional-flow theory can guide the model-fitting process and give quick estimates of foam-propagation rate, mobility, and injectivity at the field scale.


2021 ◽  
pp. 1-29
Author(s):  
Eric Sonny Mathew ◽  
Moussa Tembely ◽  
Waleed AlAmeri ◽  
Emad W. Al-Shalabi ◽  
Abdul Ravoof Shaik

Two of the most critical properties for multiphase flow in a reservoir are relative permeability (Kr) and capillary pressure (Pc). To determine these parameters, careful interpretation of coreflooding and centrifuge experiments is necessary. In this work, a machine learning (ML) technique was incorporated to assist in the determination of these parameters quickly and synchronously for steady-state drainage coreflooding experiments. A state-of-the-art framework was developed in which a large database of Kr and Pc curves was generated based on existing mathematical models. This database was used to perform thousands of coreflood simulation runs representing oil-water drainage steady-state experiments. The results obtained from the corefloods including pressure drop and water saturation profile, along with other conventional core analysis data, were fed as features into the ML model. The entire data set was split into 70% for training, 15% for validation, and the remaining 15% for the blind testing of the model. The 70% of the data set for training teaches the model to capture fluid flow behavior inside the core, and then 15% of the data set was used to validate the trained model and to optimize the hyperparameters of the ML algorithm. The remaining 15% of the data set was used for testing the model and assessing the model performance scores. In addition, K-fold split technique was used to split the 15% testing data set to provide an unbiased estimate of the final model performance. The trained/tested model was thereby used to estimate Kr and Pc curves based on available experimental results. The values of the coefficient of determination (R2) were used to assess the accuracy and efficiency of the developed model. The respective crossplots indicate that the model is capable of making accurate predictions with an error percentage of less than 2% on history matching experimental data. This implies that the artificial-intelligence- (AI-) based model is capable of determining Kr and Pc curves. The present work could be an alternative approach to existing methods for interpreting Kr and Pc curves. In addition, the ML model can be adapted to produce results that include multiple options for Kr and Pc curves from which the best solution can be determined using engineering judgment. This is unlike solutions from some of the existing commercial codes, which usually provide only a single solution. The model currently focuses on the prediction of Kr and Pc curves for drainage steady-state experiments; however, the work can be extended to capture the imbibition cycle as well.


1964 ◽  
Vol 4 (01) ◽  
pp. 49-55 ◽  
Author(s):  
Pietro Raimondi ◽  
Michael A. Torcaso

Abstract The distribution of the oil phase in Berea sandstone resulting from increasing and decreasing the water saturation by imbibition was investigated Three types of distribution were recognized: trapped, normal and lagging. The amount of oil in each of these distributions was determined as a function of saturation by carrying out a miscible displacement in the oil phase under steady-state conditions of saturation. These conditions were maintained by flowing water and oil simultaneously in given ratios and by using a displacing solvent having essentially the same density and viscosity as the oil.A correlation shows the amount of trapped oil at any saturation to be directly proportional to the conventional residual oil saturation Sir The factor of proportionality is related to the fractional permeability to the water phase. Part of the oil which was not trapped was displaced in a piston- like manner (normal part) and part was eluted gradually (lagging part). The observed phenomena are more than of mere academic importance. Oil which is trapped may well provide the fuel essential for forward combustion and thus be beneficial. On the contrary, in tertiary recovery operations, it is this trapped oil which seems to make current techniques uneconomic. Introduction A typical oilfield may initially contain connate water and oil. After a period of primary production water often enters the field either from surrounding aquifers or from surface injection. During primary production evolution and establishment of a free gas saturation usually occurs. The effect and importance of this third phase is fully recognized. However, this investigation is limited to a two- phase system, one wetting phase (water) and one non-wetting phase (oil). The increase in water content of a water-wet system is termed imbibition. In a relative permeability-saturation diagram such as the one shown in Fig. 1, the initial conditions of the field would he represented by a point below a water saturation of about 35 per cent, i.e., where the imbibition and the drainage curves to the non-wetting phase nearly coincide. When water enters the field the relative permeability to oil decreases along the imbibition curve. At watered-out conditions the relative permeability to the oil becomes zero. At this point a considerable amount of oil, called residual oil, (about 35 per cent in Fig. 1) remains unrecovered. Any attempt to produce this oil will require that its saturation be increased. In Fig. 1 this would mean retracing the imbibition curve upwards. In addition, processes like alcohol and fire flooding, which can be employed at any stage of production, involve the complete displacement of connate water and an increase, or imbibition, of water saturation ahead of the displacing front. Thus, in several types of oil production it is the imbibition-relative permeability curve which rules the flow behavior. For this reason a knowledge of the distribution of the non-wetting phase, as obtained through imbibition, whether "coming down" or "going up" on the imbibition curve, is important. SPEJ P. 49^


Energies ◽  
2019 ◽  
Vol 12 (19) ◽  
pp. 3663
Author(s):  
Lindsey Rasmussen ◽  
Tianguang Fan ◽  
Alex Rinehart ◽  
Andrew Luhmann ◽  
William Ampomah ◽  
...  

The efficiency of carbon utilization and storage within the Pennsylvanian Morrow B sandstone, Farnsworth Unit, Texas, is dependent on three-phase oil, brine, and CO2 flow behavior, as well as spatial distributions of reservoir properties and wettability. We show that end member two-phase flow properties, with binary pairs of oil–brine and oil–CO2, are directly dependent on heterogeneity derived from diagenetic processes, and evolve progressively with exposure to CO2 and changing wettability. Morrow B sandstone lithofacies exhibit a range of diagenetic processes, which produce variations in pore types and structures, quantified at the core plug scale using X-ray micro computed tomography imaging and optical petrography. Permeability and porosity relationships in the reservoir permit the classification of sedimentologic and diagenetic heterogeneity into five distinct hydraulic flow units, with characteristic pore types including: macroporosity with little to no clay filling intergranular pores; microporous authigenic clay-dominated regions in which intergranular porosity is filled with clay; and carbonate–cement dominated regions with little intergranular porosity. Steady-state oil–brine and oil–CO2 co-injection experiments using reservoir-extracted oil and brine show that differences in relative permeability persist between flow unit core plugs with near-constant porosity, attributable to contrasts in and the spatial arrangement of diagenetic pore types. Core plugs “aged” by exposure to reservoir oil over time exhibit wettability closer to suspected in situ reservoir conditions, compared to “cleaned” core plugs. Together with contact angle measurements, these results suggest that reservoir wettability is transient and modified quickly by oil recovery and carbon storage operations. Reservoir simulation results for enhanced oil recovery, using a five-spot pattern and water-alternating-with-gas injection history at Farnsworth, compare models for cumulative oil and water production using both a single relative permeability determined from history matching, and flow unit-dependent relative permeability determined from experiments herein. Both match cumulative oil production of the field to a satisfactory degree but underestimate historical cumulative water production. Differences in modeled versus observed water production are interpreted in terms of evolving wettability, which we argue is due to the increasing presence of fast paths (flow pathways with connected higher permeability) as the reservoir becomes increasingly water-wet. The control of such fast-paths is thus critical for efficient carbon storage and sweep efficiency for CO2-enhanced oil recovery in heterogeneous reservoirs.


SPE Journal ◽  
2018 ◽  
Vol 23 (03) ◽  
pp. 998-1018 ◽  
Author(s):  
Bin Yuan ◽  
Rouzbeh Ghanbarnezhad Moghanloo

Summary Prediction of how nanofluid applications can potentially control fines migration in porous media saturated with two immiscible fluids requires a mechanistic modeling approach. We develop analytic solutions to evaluate the efficiency of nanofluid utilization to reduce fines migration in systems saturated with two immiscible fluids. In this study, fines migration in the radial-flow system saturated with two immiscible fluids (oil and water) is considered; two capture mechanisms of fine particles—fines attachment and straining—are incorporated into the modeling work. The analytic solution is derived by implementing the splitting method and stream-function transformation to convert a 2 × 2 (nonhomogeneous) system of equations into an equation with a fine-particle component (nanoparticle effects) and a lifting equation in which only water saturation appears. Through quantitative comparison of suspended fines and water-saturation-profile plots, the accuracy of the analytic solution is verified with finite-difference numerical solutions. Saturation c-shock and saturation s-shock appear in the analytical solutions. The fines migration and consequent phenomena (fines attachment, fines straining, and fines suspension) decelerate the breakthrough of the injected fluids (better sweep efficiency) and increase the corresponding front saturation of the injected fluid near the wellbore—i.e., larger relative permeability (better injectivity). The results suggest that fines attachment onto the grain surface and well injectivity are enhanced after nanofluid pretreatment; moreover, the smallest radius to be pretreated by nanofluid is approximated to maintain its benefits. In practice, our analytic approach provides a valuable mathematical structure to evaluate how nanoparticle usage can enhance performance of water-based enhanced-oil-recovery (EOR) techniques in reservoirs with a fines-migration issue.


2014 ◽  
Vol 1010-1012 ◽  
pp. 1676-1683 ◽  
Author(s):  
Bin Li ◽  
Wan Fen Pu ◽  
Ke Xing Li ◽  
Hu Jia ◽  
Ke Yu Wang ◽  
...  

To improve the understanding of the influence of effective permeability, reservoir temperature and oil-water viscosity on relative permeability and oil recovery factor, core displacement experiments had been performed under several experimental conditions. Core samples used in every test were natural cores that came from Halfaya oilfield while formation fluids were simulated oil and water prepared based on analyze data of actual oil and productive water. Results from the experiments indicated that the shape of relative permeability curves, irreducible water saturation, residual oil saturation, width of two-phase region and position of isotonic point were all affected by these factors. Besides, oil recovery and water cut were also related closely to permeability, temperature and viscosity ratio.


1961 ◽  
Vol 1 (02) ◽  
pp. 61-70 ◽  
Author(s):  
J. Naar ◽  
J.H. Henderson

Introduction The displacement of a wetting fluid from a porous medium by a non-wetting fluid (drainage) is now reasonably well understood. A complete explanation has yet to be found for the analogous case of a wetting fluid being spontaneously imbibed and the non-wetting phase displaced (imbibition). During the displacement of oil or gas by water in a water-wet sand, the porous medium ordinarily imbibes water. The amount of oil recovered, the cost of recovery and the production history seem then to be controlled mainly by pore geometry. The influence of pore geometry is reflected in drainage and imbibition capillary-pressure curves and relative permeability curves. Relative permeability curves for a particular consolidated sand show that at any given saturation the permeability to oil during imbibition is smaller than during drainage. Low imbibition permeabilities suggest that the non-wetting phase, oil or gas, is gradually trapped by the advancing water. This paper describes a mathematical image (model) of consolidated porous rock based on the concept of the trapping of the non-wetting phase during the imbibition process. The following items have been derived from the model.A direct relation between the relative permeability characteristics during imbibition and those observed during drainage.A theoretical limit for the fractional amount of oil or gas recoverable by imbibition.An expression for the resistivity index which can be used in connection with the formula for wetting-phase relative permeability to check the consistency of the model.The limits of flow performance for a given rock dictated by complete wetting by either oil or water.The factors controlling oil recovery by imbibition in the presence of free gas. The complexity of a porous medium is such that drastic simplifications must be introduced to obtain a model amenable to mathematical treatment. Many parameters have been introduced by others in "progressing" from the parallel-capillary model to the randomly interconnected capillary models independently proposed by Wyllie and Gardner and Marshall. To these a further complication must be added since an imbibition model must trap part of the non-wetting phase during imbibition of the wetting phase. Like so many of the previously introduced complications, this fluid-block was introduced to make the model performance fit the observed imbibition flow behavior.


2020 ◽  
Vol 146 ◽  
pp. 05001
Author(s):  
Denis Dzhafarov ◽  
Benjamin Nicot

Relative permeability is a concept used to convey the reduction in flow capability due to the presence of multiple fluids. Relative permeability governs the multiphase flow, therefore it has a significant importance in understanding the reservoir behavior. These parameters are routinely measured on conventional rocks, however their measurement becomes quite challenging for low permeability rocks such as tight gas formations. This study demonstrates a methodology for relative permeability measurements on tight gas samples. The gas permeability has been measured by the Step Decay method and two different techniques have been used to vary the saturations: steady state flooding and vapor desorption. Series of steady-state gas/water simultaneous injection have been performed on a tight gas sample. After stabilization at each injection ratio, NMR T2, NMR Saturation profile and low pressure Step Decay gas permeability have been measured. In parallel, progressive desaturation by vapor desorption technique has been performed on twin plugs. After stabilization at each relative humidity level the NMR T2 and Step Decay gas permeability have been measured in order to compare and validate the two approaches. The techniques were used to gain insight into the tight gas two phase relative permeability of extremely low petrophysical properties (K<100 nD, phi < 5 pu) of tight gas samples of Pyrophyllite outcrop. The two methods show quite good agreement. Both methods demonstrate significant permeability degradation at water saturation higher than irreducible. NMR T2 measurements for both methods indicates bimodal T2-distributions, and desaturation first occurs on low T2 signal (small pores). Comparison of humidity drying and steady-state desaturation technique has shown a 12-18 su difference between critical water saturation (Swc) measured in gas/water steady-state injection and irreducible saturation (Swirr) measured by vapor desorption.


Author(s):  
Christos D. Tsakiroglou

The steady-state gas, k rg, and water, k rw, relative permeabilities are measured with experiments of the simultaneous flow, at varying flow rates, of nitrogen and brine (aqueous solution of NaCl brine) on a homogeneous sand column. Two differential pressure transducers are used to measure the pressure drop across each phase, and six ring electrodes are used to measure the electrical resistance across five segments of the sand column. The electrical resistances are converted to water saturations with the aid of the Archie equation for resistivity index. Both k rw and k rg are regarded as power functions of water, Caw, and gas, Cag, capillary numbers, the exponents of which are estimated with non-linear fitting to the experimental datasets. An analogous power law is used to express water saturation as a function of Caw, and Cag. In agreement to earlier studies, it seems that the two-phase flow regime is dominated by connected pathway flow and disconnected ganglia dynamics for the wetting fluid (brine), and only disconnected ganglia dynamics for the non-wetting fluid (gas). The water saturation is insensitive to changes of water and gas capillary numbers. Each relative permeability is affected by both water and gas capillary numbers, with the water relative permeability being a strong function of water capillary number and gas relative permeability depending strongly on the gas capillary number. The slope of the water relative permeability curve for a gas/water system is much higher than that of an oil/water system, and the slope of the gas relative permeability is lower than that of an oil/water system.


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