Experimental and Numerical Studies of Gas/Oil Multicontact Miscible Displacements in Homogeneous and Crossbedded Porous Media

SPE Journal ◽  
2007 ◽  
Vol 12 (01) ◽  
pp. 62-76 ◽  
Author(s):  
Yahya Mansoor Al-Wahaibi ◽  
Ann Helen Muggeridge ◽  
Carlos Atilio Grattoni

Summary We investigate oil recovery from multicontact miscible (MCM) gas injection into homogeneous and crossbedded porous media, using a combination of well-characterized laboratory experiments and detailed compositional flow simulation. All simulator input data, including most EOS parameters, were determined experimentally or from the literature produced fluids in all experiments were found not to be in compositional equilibrium. This was not predicted by the simulator, giving a poor match between experimental and simulated oil recoveries. The match was significantly improved for the cross-bedded displacements by using alpha factors derived from the MCM displacements in the homogeneous pack. Introduction The recovery of oil by miscible gas injection has been a subject of interest and research in petroleum engineering for more than 40 years (Stalkup 1983). In a first-contact, miscible (FCM) displacement, the gas and oil mix instantly in all proportions. No capillary forces exist, so, in principle, residual oil saturation is zero, and 100% oil recovery should be achieved. In practice, many phenomena conspire to limit the efficiency of the miscible flooding process, including viscous fingering, gravity override, and permeability heterogeneity. Moreover, it is often not economical, and sometimes not technically feasible, to inject a gas that is first-contact miscible with the oil. Instead, the injected gas is designed to develop miscibility with the oil by mass transfer during the displacement. This is a so-called MCM gas injection. If the bulk of the mass transfer is from the gas to the oil, then the displacement is termed a condensing drive. If most of the mass transfer is from the oil to the gas, then it is termed a vaporizing drive. In most cases, however, because of the multicomponent nature of oil and gas, the mass transfer is actually a mixture of both these cases, and the displacement is termed a condensing-vaporizing drive. Small-scale heterogeneities can have a significant impact on recovery efficiency (Jones et al. 1995; Jones et al. 1994; Kjonsvik et al. 1994), yet they cannot be modeled explicitly in field-scale simulations. Some of the most common small-scale heterogeneities found in sandstone reservoirs are laminations. However, because laminations have a small size and are generally at an angle to the principal flow direction, their influence onfluid flow is one of the most difficult features to predict numerically. There is a significant amount of literature describing systematic investigations of first-contact miscible and immiscible displacement processes in laminated sandstones (Huang et al. 1995, 1996; Ringrose et al. 1993; Kortekaas 1985; Honarpour et al. 1994; Hartkamp-Bakker 1991, 1993; McDougall and Sorbie 1993; Marcelle-DeSilva and Dawe 2003; Borresen and Graue 1996; Roti and Dawe 1993; Dawe et al. 1992; Caruana and Dawe 1996; Caruana 1997). Both experimental and simulation studies show that significant volumes of oil can be trapped by capillary forces during immiscible displacements (Huang et al. 1995, 1996; Ringrose et al. 1993; Kortekaas 1985; Honarpour et al. 1994; Hartkamp-Bakker 1991, 1993; McDougall and Sorbie 1993; Marcelle-DeSilva and Dawe 2003; Borresen and Graue 1996; Roti and Dawe 1993; Dawe et al. 1992; Caruana and Dawe 1996; Caruana 1997). However, the influence of these heterogeneities on MCM displacements, during which capillary forces change from being very significant when gas is first injected to negligible once miscibility has developed, has not yet been investigated. Indeed, the only comparisons of well-characterized MCM displacement experiments and detailed simulations reported in anywhere in the literature are those of Burger and colleagues (Burger and Mohanty 1997; Burger et al. 1996; Burger et al. 1994).

Energies ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1405
Author(s):  
Bita Bayestehparvin ◽  
S.M. Farouq Ali ◽  
Mohammad Kariznovi ◽  
Jalal Abedi

A need for a reduction in energy intensity and greenhouse gas emissions of bitumen and heavy oil recovery processes has led to the invention of several methods where mass-transfer-based recovery processes in terms of cold or heated solvent injection are used to reduce bitumen viscosity rather than steam injection. Despite the extensive numerical and experimental investigations, the field results are not always aligned to what is predicted unless several history matches are done. These discrepancies can be explained by investigating the mechanisms involved in mass transfer and corresponding viscosity reduction at the pore level. A two-phase multicomponent pore-scale simulator is developed to be used for realistic porous media simulation. The simulator developed predicts the chamber front velocity and chamber propagation in agreement with 2D experimental data in the literature. The simulator is specifically used for vapor extraction (VAPEX) modelling in a 2D porous medium. It was found that the solvent cannot reach its equilibrium value everywhere in the oleic phase confirming the non-equilibrium phase behavior in VAPEX. The equilibrium assumption is found to be invalid for VAPEX processes even at a small scale. The model developed can be used for further investigation of mass transfer-based processes in porous media.


Author(s):  
Boming Yu

In the past three decades, fractal geometry and technique have received considerable attention due to its wide applications in sciences and technologies such as in physics, mathematics, geophysics, oil recovery, material science and engineering, flow and heat and mass transfer in porous media etc. The fractal geometry and technique may become particularly powerful when they are applied to deal with random and disordered media such as porous media, nanofluids, nucleate boiling heat transfer. In this paper, a summary of recent advances is presented in the areas of heat and mass transfer in fractal media by fractal geometry technique. The present overview includes a brief summary of the fractal geometry technique applied in the areas of heat and mass transfer; thermal conductivities of porous media and nanofluids; nucleate boiling heat transfer. A few comments are made with respect to the theoretical studies that should be made in the future.


1979 ◽  
Vol 19 (03) ◽  
pp. 164-174 ◽  
Author(s):  
Chi U. Ikoku ◽  
Henry J. Ramey

Abstract The transient flow behavior of non-Newtonian fluids in petroleum reservoirs is studied. A new partial differential equation is derived. The diffusivity equation is a special case of the new equation. The new equation describes the flow of a slightly compressible, non-Newtonian, power-law fluid in a homogeneous porous medium. This equation should govern the flow of most non-Newtonian oil-displacement agents used in secondary and tertiary oil-recovery projects, such as polymer solutions, micellar projects, such as polymer solutions, micellar solutions, and surfactant solutions. Analytical solutions of the new partial differential equation are obtained that introduce new methods of well-test analysis for non-Newtonian fluids. An example is presented for using the new techniques to analyze injection well-test data in a polymer injection project. project. Graphs of the dimensionless pressure function also are presented. These may be used to investigate the error when using Newtonian fluid-flow equations to model the flow of non-Newtonian fluids in porous media. Introduction Non-Newtonian fluids, especially polymer solutions, microemulsions, and macroemulsions, often are injected into the reservoir in various enhanced oil-recovery processes. In addition, foams sometimes are circulated during drilling. Thermal recovery of oil by steam and air injection may lead to the flow of natural emulsions and foams through porous media. Some enhanced oil-recovery projects involving the injection of non-Newtonian fluids have been successful, but most of these projects either failed or performed below expectation. These results suggest the need for a thorough study of the stability of non-Newtonian fluids at reservoir conditions, and also a new look at the flow of non-Newtonian fluids in porous media. porous media. Many studies of the rheology of non-Newtonian fluids in porous media exist in the chemical engineering, rheology, and petroleum engineering literature. In 1969, Savins presented an important survey on the flow of non-Newtonian fluids through porous media. In some cases, he interpreted porous media. In some cases, he interpreted published data further and compared results of published data further and compared results of different investigators. van Poollen and Jargon presented a numerical study of the flow of presented a numerical study of the flow of non-Newtonian fluids in homogeneous porous media using finite-difference techniques. They considered steady-state and unsteady-state flows and used the Newtonian fluid-flow equation. They considered non-Newtonian behavior by using a viscosity that varied with position. No general method was developed for analyzing flow data. Bondor et al. presented a numerical simulation of polymer presented a numerical simulation of polymer flooding. Much useful information on polymer flow was presented, but transient flow was not considered.At present, there is no standard method in the petroleum engineering literature for analyzing petroleum engineering literature for analyzing welltest data obtained during injection of non-Newtonian fluids into petroleum reservoirs. However, injection of several non-Newtonian oil-displacement agents is an important oilfield operation. Interpretation of well-test data for these operations should also be important. Obviously, procedures developed for Newtonian fluid flow are not appropriate. SPEJ P. 164


2014 ◽  
Vol 2014 ◽  
pp. 1-7 ◽  
Author(s):  
Ping Wang

Discrete element method (DEM) is used to produce dense and fixed porous media with rigid mono spheres. Lattice Boltzmann method (LBM) is adopted to simulate the fluid flow in interval of dense spheres. To simulating the same physical problem, the permeability is obtained with different lattice number. We verify that the permeability is irrelevant to the body force and the media length along flow direction. The relationships between permeability, tortuosity and porosity, and sphere radius are researched, and the results are compared with those reported by other authors. The obtained results indicate that LBM is suited to fluid flow simulation of porous media due to its inherent theoretical advantages. The radius of sphere should have ten lattices at least and the media length along flow direction should be more than twenty radii. The force has no effect on the coefficient of permeability with the limitation of slow fluid flow. For mono spheres porous media sample, the relationship of permeability and porosity agrees well with the K-C equation, and the tortuosity decreases linearly with increasing porosity.


2012 ◽  
Vol 516-517 ◽  
pp. 790-796
Author(s):  
Huai Jun Yang ◽  
Wei Dong Liu ◽  
Hui Hui Kou

Inducting dissolution speed constant and multistage reaction series to the alkaline solution transmission equation, this article established the alkaline solution transmission equation with multistage reaction dynamics in the porous media of stratum mineral and calculated one-dimensional alkaline solution concentration distribution. Experimental results verified the correctness of transmission equation, moreover, it further analyzed the alkaline solution regularity in the porous media. The model will be used to predict alkali loss, optimize alkaline solution concentration and slug size, thereby alkaline waterflooding or combination drive can obtain better displacement characteristics and improve the oil recovery.


Energies ◽  
2021 ◽  
Vol 14 (16) ◽  
pp. 4739
Author(s):  
Riyaz Kharrat ◽  
Mehdi Zallaghi ◽  
Holger Ott

The enhanced oil recovery mechanisms in fractured reservoirs are complex and not fully understood. It is technically challenging to quantify the related driving forces and their interaction in the matrix and fractures medium. Gravity and capillary forces play a leading role in the recovery process of fractured reservoirs. This study aims to quantify the performance of EOR methods in fractured reservoirs using dimensionless numbers. A systematic approach consisting of the design of experiments, simulations, and proxy-based optimization was used in this work. The effect of driving forces on oil recovery for water injection and several EOR processes such as gas injection, foam injection, water-alternating gas (WAG) injection, and foam-assisted water-alternating gas (FAWAG) injection was analyzed using dimensionless numbers and a surface response model. The results show that equilibrium between gravitational and viscous forces in fracture and capillary and gravity forces in matrix blocks determines oil recovery performance during EOR in fractured reservoirs. When capillary forces are dominant in gas injection, fluid exchange between fracture and matrix is low; consequently, the oil recovery is low. In foam-assisted water-alternating gas injection, gravity and capillary forces are in equilibrium conditions as several mechanisms are involved. The capillary forces dominate the water cycle, while gravitational forces govern the gas cycle due to the foam enhancement properties, which results in the highest oil recovery factor. Based on the performed sensitivity analysis of matrix–fracture interaction on the performance of the EOR processes, the foam and FAWAG injection methods were found to be more sensitive to permeability contrast, density, and matrix block highs than WAG injection.


1965 ◽  
Vol 5 (01) ◽  
pp. 51-59 ◽  
Author(s):  
P. Raimondi ◽  
M.A. Torcaso

Abstract To study mass transport in systems simulating oil recovery processes, different porous media were saturated with a mobile (carrier phase) and a stationary phase. Slugs of carrier phase containing a small amount of solute were displaced with pure carrier phase. By analogy to the chromatographic processes, the velocity of the solute can be predicted from a knowledge of the partition coefficient and the saturation provided that equilibrium between the two phases exists. Equilibrium was found to exist for different porous media, solutes and rates. The conditions were varied over the range normally encountered in the laboratory and in the field. The longitudinal dispersion of a solute undergoing interphase mass transfer was also investigated. Introduction The production of hydrocarbons by gas cycling, enriched gas drive and CO2 or alcohol displacement involves, among other factors, relative motion between two phases and compounds, hereafter called solute, which are soluble in both phases. The solute is carried forward by the faster flowing phase at a lower velocity than the average velocity of that phase. Retardation of the solute is caused by chromatographic absorption and desorption in the slower flowing phase and by the degree of departure from equilibrium. At equilibrium the concentration of solute in the two phases can be related by the equation* (1) where Csw and Cso are the concentration of solute in the aqueous and oleic phases respectively and K is the equilibrium ratio, or partition coefficient. Displacement theories must contain an explicit assumption with regard to equilibrium, i.e., whether the compositions can be related by Eq. 1. The existance of equilibrium depends, in general on the relative velocity between the phases. Unfortunately, other factors such as gravity segregation and viscous fingering, also depend on velocity. For this reason, whenever effects of rate on displacement were observed, it was practically impossible to discern what caused them - lack of equilibrium or the factors mentioned above. Equilibrium between phases has been the subject of extensive studies in fields such as extraction or chromatography. It has received only small attention in flow through the type of porous media encountered in oil production. For this reason a method was developed which makes it possible to study the movement of a solute as it is affected by rate, type of porous media, partition coefficient and carrier phase, but in the absence of segregation or fingering. The information obtained enables one to determine when the assumption of equilibrium can be made. Briefly, the method consists of (1) saturating the core with a mobile and an immobile phase, (2) injecting a slug made up of the same fluid as the mobile phase and a small concentration of mutually soluble solute, (3) measuring the lag and the peak height of the slug at arrival and (4) correlating these variables with fluid properties such as partition coefficient and mixing constants of the medium. PROPOSED MECHANISM The principles of chromatography are combined with the equation of longitudinal mixing to predict the velocity of a solute slug compared to the bulk velocity and the peak height of a slug. The equation so obtained is valid under equilibrium conditions only. Therefore, a comparison between experimental and predicted results will give a measure of departure from equilibrium. This work was done with either the oleic or the aqueous phase being immobile. For simplicity, the following development is based on the case where the oleic phase is immobile. However, the treatment is the same in either case. SPEC P. 51ˆ


1999 ◽  
Vol 2 (06) ◽  
pp. 558-564 ◽  
Author(s):  
Philip L. Wylie ◽  
Kishore K. Mohanty

Summary Oil can become bypassed during gas injection as a result of gravitational, viscous, and heterogeneity effects. Mass transfer from the bypassed region to the flowing gas is dependent upon pressure-driven, gravity-driven, and capillary-driven crossflows as well as diffusion and dispersion. The focus of this study is on the influence that wettability has on bypassing and mass transfer. Experimental results reveal comparatively less bypassing occurs in a strongly oil-wet sandstone than in a water-wet sandstone for gravity-dominated, secondary gas floods. Mass transfer under oil-wet conditions is enhanced, as a result of oil-wetting film connectivity, over that of water-wet conditions, where water shielding is significant. Introduction As gas flooding becomes a more viable means of enhanced oil recovery, the ability to quantify and simulate bypassing and mass transfer becomes increasingly important. Bypassing in gas injection processes may occur as a result of gravity override, viscous fingering, or heterogeneities in the reservoir, such as low permeability layers or a fracture-matrix network. Mass-transfer mechanisms, such as pressure-driven, gravity-driven, capillary-driven, and diffusion/dispersion crossflows are studied on the laboratory scale before being scaled up for incorporation into reservoir simulations. The laboratory studies reveal influences that govern the extent that each mechanism contributes to overall mass transfer. The enrichment of the injected gas has been discovered, through simulation and experiment, to play a key role in overall gas flood performance.1–6 Pande2 proposed, using 1D numerical simulation, that secondary and tertiary hydrocarbon gas floods, at or below minimum miscibility pressure or enrichment (MMP or MME), may perform as well as enriched gas floods. Shyeh-Yung1 demonstrated that tertiary gasflood recoveries below MMP do not decrease as severely as predicted by slim-tube tests for CO2 and Shyeh-Yung and Stadler5 and Grigg et al.7 showed that gasflood Sorm increases almost linearly as hydrocarbon gas enrichment decreases. The injection methodology has been shown to affect ultimate oil recovery.7,8 The experiments of Jackson et al.7 demonstrated that the optimum miscible WAG ratio in a water-wet bead pack under tertiary conditions was 0:1 (continuous gas injection) and 1:1 for a miscible flood in an oil-wet bead pack. Laboratory studies have also revealed the influence of mass-transfer zone orientation and water saturation on gasflood oil recovery.9–11 Burger et al.9,10 have found that mass transfer increases with solvent enrichment and that horizontal mass transfer provides the most efficient oil recovery as a result of gravity-driven crossflow. The inverted, or positive gravity orientation, exhibits countercurrent gravity-driven crossflow that inhibits mass transfer somewhat. The vertical, or negative gravity orientation, yielded the lowest recovery, as diffusion was the only significant mass-transfer mechanism for their particular fluid system. Wylie and Mohanty11 have investigated the effect of water saturation on bypassing and mass transfer, concluding that mass transfer is decreased in the presence of water, but that capillary forces become more dominant as enrichment decreases. Less bypassing, due to gravity override, was observed in horizontal gasflood experiments in the presence of water; however, it was conjectured that bypassing was still present as a result of fluid redistribution and water shielding. With the exception of Jackson et al.7 these studies were performed under strongly water-wet or at restored mixed-wet conditions. The extent that media wettability influences gasflood bypassing and the subsequent mass transfer is largely unexplored. Recent research has examined wettability alteration and its influence on waterflood oil recoveries.12,13 Buckley et al.12 concluded that high pH, low ionic strength, monovalent salt solutions typically induce more water-wet conditions on silica surfaces or cores, aged with asphaltic crude oils, while lower pH solutions led to less water wettability. Their results showed optimum waterflood oil recoveries from Clashach cores under mixed-wet conditions with a slightly positive Amott index. Tang and Morrow13 investigated the influences that temperature, salinity, and oil composition have on wettability and waterflood oil recovery from cores aged in crude oil. They discovered wettability to shift toward more water-wet conditions and waterflood oil recovery to increase with a decrease in the salinity of the connate or invading brine. Waterflood oil recoveries also increased as the displacement temperature increased. Basu and Sharma14 provided evidence suggesting that mixed wettability results from the capillarity-induced, destabilization of brine films on the rock surface.


2009 ◽  
Vol 12 (02) ◽  
pp. 200-210 ◽  
Author(s):  
Benjamin Ramirez ◽  
Hossein Kazemi ◽  
Mohammed Al-kobaisi ◽  
Erdal Ozkan ◽  
Safian Atan

Summary Accurate calculation of multiphase-fluid transfer between the fracture and matrix in naturally fractured reservoirs is a crucial issue. In this paper, we will present the viability of the use of simple transfer functions to account accurately for fluid exchange resulting from capillary, gravity, and diffusion mass transfer for immiscible flow between fracture and matrix in dual-porosity numerical models. The transfer functions are designed for sugar-cube or match-stick idealizations of matrix blocks. The study relies on numerical experiments involving fine-grid simulation of oil recovery from a typical matrix block by water or gas in an adjacent fracture. The fine-grid results for water/oil and gas/oil systems were compared with results obtained with transfer functions. In both water and gas injection, the simulations emphasize the interaction of capillary and gravity forces to produce oil, depending on the wettability of the matrix. In gas injection, the thermodynamic phase equilibrium, aided by gravity/capillary interaction and, to a lesser extent, by molecular diffusion, is a major contributor to interphase mass transfer. For miscible flow, the fracture/matrix mass transfer is less complicated because there are no capillary forces associated with solvent and oil; nevertheless, gravity contrast between solvent in the fracture and oil in the matrix creates convective mass transfer and drainage of oil. Using the transfer functions presented in this paper, fracture- and matrix-flow calculations can be decoupled and solved sequentially--reducing the complexity of the computation. Furthermore, the transfer-function equations can be used independently to calculate oil recovery from a matrix block.


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