Lessons from Trinidad's CO2 Immiscible Pilot Projects

2005 ◽  
Vol 8 (05) ◽  
pp. 397-403 ◽  
Author(s):  
Lorna J. Mohammed-Singh ◽  
Ashok K. Singhal
Keyword(s):  
Natural Gas ◽  
Oil Recovery ◽  
Water Injection ◽  
Lessons Learned ◽  
Co2 Injection ◽  
Efficient Production ◽  
Co2 Flooding ◽  
Injection Wells ◽  
Forest Reserve ◽  
Stable Mode

Summary Four immiscible carbon dioxide (CO2) pilot floods were implemented in the Petroleum Co. of Trinidad and Tobago's (Petrotrin's) reservoirs at its Forest Reserve and Oropouche fields, Trinidad, over the period 1973 to 1990. The projects were conducted in a gravity-stable mode after primary, secondary, and tertiary production (after natural-gas and water injection). CO2 was injected into thick sands of variable continuity containing medium-gravity crude (17 to29°API). Production increases were observed in all projects. It is postulated that injected CO2 swelled the oil, reduced viscosity and helped form oil banks that could move more easily under gravity. Oil-production rates and recovery improved as a consequence. In some of the projects, these beneficial effects continued for several years, even after discontinuation of CO2 injection(supply interruptions), with recovery aided by water influx. Interruptions in CO2 supply did not appear to harm incremental oil recovery materially. Channeling was observed at high injection rates and was promoted in reservoirs with low transmissibility. Oil recovery improved as more offtake (production) wells were added downstream of the injection wells. This phenomenon reinforced the importance of optimizing volumetric sweep and of capture during CO2 flooding by judiciously selecting injection and offtake locations. Incremental recovery ranges between2 and 8% of the original oil in place (OOIP), with predicted ultimate recoveries of 4 to 9% of OOIP. Cumulative CO2 use improved with efficient production practices and ranges from 3 to 11 Mcf/bbl to date. Introduction The Forest Reserve and Oropouche fields are located in the southwest peninsula of the island of Trinidad, as shown in Fig. 1. In 1973, CO2 injection was initiated into a former natural-gas-injection project in Forest Reserve when there was a shortage of natural gas. Three immiscible pilot floods and one cyclic-injection project were later implemented between 1974 and 1986. Another immiscible pilot flood was implemented in 1990 in the Oropouche field. These projects were implemented in a "poor boy" mode using existing wells and equipment. CO2 is piped 25 miles from an ammonia plant, compressed, and injected into target reservoirs. This paper documents Petrotrin's 30 years of experience1 with CO2 immiscible injection into these projects and presents a comparative analysis of the performance of the four enhanced-oil-recovery (EOR) projects with some immiscible CO2-flood projects from the literature. Results and lessons learned will be used to guide the extension of CO2 injection to other similar reservoirs in the company's operations and to improve the management of existing projects.

The Experimental Study on the Flooding Regularities of Various CO2 Flooding Modes Implemented on Ultralow Permeability Cores

2018 ◽  
Vol 140 (7) ◽  
Author(s):  
Aifen Li ◽  
Xiaoxia Ren ◽  
Shuaishi Fu ◽  
Jiao Lv ◽  
Xuguang Li ◽  
...  
Keyword(s):  
Crude Oil ◽  
Oil Recovery ◽  
Water Injection ◽  
Water Flooding ◽  
Co2 Injection ◽  
Rapid Decline ◽  
Co2 Flooding ◽  
Gas Oil ◽  
Water Cut ◽  
Ultralow Permeability

The application of water flooding is not successful for the development of low permeability reservoirs due to the fine pore sizes and the difficulty of water injection operation. CO2 can dissolve readily in crude oil and highly improve the mobility of crude oil, which makes CO2 flooding an effective way to the development of the ultralow-permeability reservoirs. The regularities of various CO2 displacement methods were studied via experiments implemented on cores from Chang 8 Formation of Honghe Oilfield. The results show that CO2 miscible displacement has the minimum displacement differential pressure and the maximum oil recovery; CO2-alternating-water miscible flooding has lower oil recovery, higher drive pressure, and relatively lower gas-oil ratio; water flooding has the minimum oil recovery and the maximum driving pressure. A large amount of oil still can be produced under a high gas-oil ratio condition through CO2 displacement method. This fact proves that the increase of gas-oil ratio is caused by the production of dissolved CO2 in oil rather than the free gas breakthrough. At the initial stage of CO2 injection, CO2 does not improve the oil recovery immediately. As the injection continues, the oil recovery can be improved rapidly. This phenomenon suggests that when CO2 displacement is performed at high water cut period, the water cut does not decrease immediately and will remain high for a period of time, then a rapid decline of water cut and increase of oil production can be observed.

Lessons Learned From Applications of a New Organic-Oil-Recovery Method That Activates Resident Microbes

2012 ◽  
Vol 15 (06) ◽  
pp. 688-694 ◽  
Author(s):  
R.L.. L. Zahner ◽  
S.J.. J. Tapper ◽  
B.W.G.. W.G. Marcotte ◽  
B.R.. R. Govreau
Keyword(s):  
Oil Recovery ◽  
Microbial Growth ◽  
Water Injection ◽  
The United States ◽  
Lessons Learned ◽  
Injection Wells ◽  
Recovery Method ◽  
Scientific Analysis ◽  
Wide Range

Summary Using a breakthrough process, which does not require microbes to be injected, more than 100 microbial enhanced-oil-recovery (MEOR) treatments were conducted from 2007 to the end of 2010 in oil-producing and water-injection wells in the United States and Canada. On average, these treatments increased oil production by 122%, with an 89% success rate. This paper reviews the MEOR process, reviews the results of the first 100+ treatments, and shares what has been learned from this work. Observations and conclusions include the following: Screening reservoirs is critical to success. Identifying reservoirs where appropriate microbes are present and oil is movable is the key. MEOR can be applied to a wide range of oil gravities. MEOR has been applied successfully to reservoirs with oil gravity as high as 41° API and as low as 16° API. When microbial growth is appropriately controlled, reservoir plugging or formation damage is no longer a risk. Microbes reside in extreme conditions and can be manipulated to perform valuable in-situ "work." MEOR has been applied successfully at reservoir temperatures as high as 200°F and salinities as high as 140,000 ppm total dissolved solids (TDS). MEOR can be applied successfully in dual-porosity reservoirs. A side benefit of applying MEOR is that it can reduce reservoir souring. An oil response is not always observed when treating producing wells. MEOR can be applied to many more reservoirs than thought originallys with little downside risk. This review of more than 100 MEOR well treatments expands the types of reservoirs in which MEOR can be applied successfully. Low-risk and economically attractive treatments can be accomplished when appropriate scientific analysis and laboratory screening are performed before treatments.

The New Generation of Outflow Control Devices Autonomously Controlling the Conformance of Water Injection Well- A Case Study with ADNOC Onshore

2021 ◽  
Author(s):  
Sultan Ibrahim Al Shemaili ◽  
Ahmed Mohamed Fawzy ◽  
Elamari Assreti ◽  
Mohamed El Maghraby ◽  
Mojtaba Moradi ◽  
...  
Keyword(s):  
Oil Recovery ◽  
Dynamic Properties ◽  
Short Circuit ◽  
Water Injection ◽  
Performance Outcomes ◽  
Injection Well ◽  
Well Performance ◽  
Injection Wells ◽  
Horizontal Section ◽  
Control Devices

Abstract Several techniques have been applied to improve the water conformance of injection wells to eventually improve field oil recovery. Standalone Passive flow control devices or these devices combined with Sliding sleeves have been successful to improve the conformance in the wells, however, they may fail to provide the required performance in the reservoirs with complex/dynamic properties including propagating/dilating fractures or faults and may also require intervention. This is mainly because the continuously increasing contrast in the injectivity of a section with the feature compared to the rest of the well causes diverting a great portion of the injected fluid into the thief zone which ultimately creates short-circuit to the nearby producer wells. The new autonomous injection device overcomes this issue by selectively choking the injection of fluid into the growing fractures crossing the well. Once a predefined upper flowrate limit is reached at the zone, the valves autonomously close. Well A has been injecting water into reservoir B for several years. It has been recognised from the surveys that the well passes through two major faults and the other two features/fractures with huge uncertainty around their properties. The use of the autonomous valve was considered the best solution to control the water conformance in this well. The device initially operates as a normal passive outflow control valve, and if the injected flowrate flowing through the valve exceeds a designed limit, the device will automatically shut off. This provides the advantage of controlling the faults and fractures in case they were highly conductive as compared to other sections of the well and also once these zones are closed, the device enables the fluid to be distributed to other sections of the well, thereby improving the overall injection conformance. A comprehensive study was performed to change the existing dual completion to a single completion and determine the optimum completion design for delivering the targeted rate for the well while taking into account the huge uncertainty around the faults and features properties. The retrofitted completion including 9 joints with Autonomous valves and 5 joints with Bypass ICD valves were installed in the horizontal section of the well in six compartments separated with five swell packers. The completion was installed in mid-2020 and the well has been on the injection since September 2020. The well performance outcomes show that new completion has successfully delivered the target rate. Also, the data from a PLT survey performed in Feb 2021 shows that the valves have successfully minimised the outflow toward the faults and fractures. This allows achieving the optimised well performance autonomously as the impacts of thief zones on the injected fluid conformance is mitigated and a balanced-prescribed injection distribution is maintained. This paper presents the results from one of the early installations of the valves in a water injection well in the Middle East for ADNOC onshore. The paper discusses the applied completion design workflow as well as some field performance and PLT data.

scholarly journals Investigation of Oil Recovery in Fractured Carbonate Rock by

2016 ◽  
Vol 6 (1) ◽  
pp. 14
Author(s):  
H. Karimaie ◽  
O. Torsæter
Keyword(s):  
Oil Recovery ◽  
Gas Injection ◽  
Water Injection ◽  
Co2 Injection ◽  
Recovery Method ◽  
Asmari Limestone ◽  
Fractured Carbonate ◽  
Efficient Recovery ◽  
Live Oil ◽  
Non Equilibrium

The purpose of the three experiments described in this paper is to investigate the efficiency of secondary andtertiary gas injection in fractured carbonate reservoirs, focusing on the effect of equilibrium gas,re-pressurization and non-equilibrium gas. A weakly water-wet sample from Asmari limestone which is the mainoil producing formation in Iran, was placed vertically in a specially designed core holder surrounded withfracture. The unique feature of the apparatus used in the experiment, is the capability of initializing the samplewith live oil to obtain a homogeneous saturation and create the fracture around it by using a special alloy whichis easily meltable. After initializing the sample, the alloy can be drained from the bottom of the modified coreholder and create the fracture which is filled with live oil and surrounded the sample. Pressure and temperaturewere selected in the experiments to give proper interfacial tensions which have been measured experimentally.Series of secondary and tertiary gas injection were carried out using equilibrium and non-equilibrium gas.Experiments have been performed at different pressures and effect of reduction of interfacial tension werechecked by re-pressurization process. The experiments showed little oil recovery due to water injection whilesignificant amount of oil has been produced due to equilibrium gas injection and re-pressurization. Results alsoreveal that CO2 injection is a very efficient recovery method while injection of C1 can also improve the oilrecovery.

scholarly journals Polymer gels for controlling water thief zones in injection wells

2012 ◽  
Vol 5 (1) ◽  
pp. 37-44 ◽  
Author(s):  
Gustavo-Adolfo Maya-Toro ◽  
Rubén-Hernán Castro-García ◽  
Zarith del Pilar Pachón-Contreras. ◽  
Jose-Francisco Zapata-Arango
Keyword(s):  
Oil Recovery ◽  
Water Injection ◽  
Injection Wells ◽  
Recovery Processes ◽  
Injection Water ◽  
Secondary Oil Recovery ◽  
High Concentrations ◽  
Low Efficiency ◽  
Hydrolyzed Polyacrylamide ◽  
Positive Results

Oil recovery by water injection is the most extended technology in the world for additional recovery, however, formation heterogeneity can turn it into highly inefficient and expensive by channeling injected water. This work presents a chemical option that allows controlling the channeling of important amounts of injection water in specific layers, or portions of layers, which is the main explanation for low efficiency in many secondary oil recovery processes. The core of the stages presented here is using partially hydrolyzed polyacrylamide (HPAM) cross linked with a metallic ion (Cr+3), which, at high concentrations in the injection water (5000 – 20000 ppm), generates a rigid gel in the reservoir that forces the injected water to enter into the formation through upswept zones. The use of the stages presented here is a process that involves from experimental evaluation for the specific reservoir to the field monitoring, and going through a strict control during the well intervention, being this last step an innovation for this kind of treatments. This paper presents field cases that show positive results, besides the details of design, application and monitoring.

Advances in Midland Basin Expand Boundaries of CO2 EOR in Marginal Pay Areas

2021 ◽  
Vol 73 (06) ◽  
pp. 65-66
Author(s):  
Judy Feder
Keyword(s):  
Oil Recovery ◽  
Large Scale ◽  
Co2 Injection ◽  
Co2 Flooding ◽  
Improved Oil Recovery ◽  
Midland Basin ◽  
The North ◽  
Production Wells ◽  
Original Oil In Place ◽  
Carbon Dioxide Co2

This article, written by JPT Technology Editor Judy Feder, contains highlights of paper SPE 200460, “A Case Study of SACROC CO2 Flooding in Marginal Pay Regions: Improving Asset Performance,” by John Kalteyer, SPE, Kinder Morgan, prepared for the 2020 SPE Improved Oil Recovery Conference, originally scheduled to be held in Tulsa, 18–22 April. The paper has not been peer reviewed. As one of the first fields in the world to use carbon dioxide (CO2) in enhanced oil recovery (EOR), the Scurry Area Canyon Reef Operators Committee (SACROC) unit of the Kelly-Snyder field in the Midland Basin of Texas provides a unique opportunity to study, learn from, and improve upon the development of CO2 flood technology. The complete paper reviews the history of EOR at SACROC, discusses changes in theory over time, and provides a look at the field’s future. Field Overview and Development History The first six pages of the paper discuss the field’s location, geology, and development before June 2000, when Kinder Morgan acquired the SACROC unit and took over as operator. Between initial gas injection in 1972 and 2000, approximately 1 TCF of CO2 had been injected into the Canyon Reef reservoir. Since 2000, cumulative CO2 injection has sur-passed 7 TCF and yielded cumulative EOR of over 180 million bbl. The reservoir is a primarily limestone reef complex containing an estimated original oil in place (OOIP) of just under 3 billion bbl. The reservoir ranges from 200 ft gross thickness in the south to 900 ft in the north, where the limestone matrix averages 8% porosity and 20-md permeability. The Canyon Reef structure is divided into four major intervals, of which the Upper Canyon zone provides the highest-quality pay. The field was discovered in 1948 at a pressure of 3,122 psi. By late 1950, 1,600 production wells had been drilled and the reservoir pressure plummeted, settling as low as 1,700 psi. Waterflooding begun in 1954 enabled the field to continue producing for nearly 20 years, at which time the operators deter-mined that another recovery mechanism would be needed to maximize recovery and reach additional areas of the field. The complete paper discusses various CO2 injection programs that were developed and applied—including a true tertiary response from a miscible CO2 flood in 1981—along with their outcomes. Acquisition and CO2-Injection Redevelopment In June 2000 Kinder Morgan acquired the SACROC Unit and took over as operator. Approximately 6.7 billion bbl of water and 1.3 TCF of CO2 had been injected across the unit to that date, but the daily oil rate of 8,700 B/D was approaching the field’s economic limit. An estimated 40% of the OOIP had been produced through the combination of recovery methods that each previous operator had used. Expanding on the conclusions of its immediate predecessor, the operator initiated large-scale CO2-flood redevelopment in a selection of project areas. These redevelopments were based on several key distinctions differentiating them from previous injection operations.

Ten years of time-lapse seismic on Atlantis Field

2021 ◽  
Vol 40 (7) ◽  
pp. 494-501
Author(s):  
Jean-Paul van Gestel
Keyword(s):  
Waveform Inversion ◽  
Water Injection ◽  
Main Tool ◽  
Time Lapse ◽  
Velocity Model ◽  
Lessons Learned ◽  
Ocean Bottom ◽  
Injection Wells ◽  
History Match ◽  
Business Decisions

In 2019, the fourth ocean-bottom-node survey was acquired over Atlantis Field. This survey was quickly processed to provide useful time-lapse (4D) observations two months after the end of the acquisition. The time-lapse observations were immediately valuable in placing wells, refining final drilling target locations, updating well prioritization, and sequencing production and water-injection wells. These data are indispensable pieces of information that bring geophysicists and reservoir engineers together and focus the conversation on key remaining uncertainties such as fault transmissibilities and drainage areas. Time-lapse observations can confirm the key conceptional models already in place but are even more valuable when they highlight alternative models that have not yet been considered. The lessons learned from the acquisition, processing, analysis, interpretation, and integration of the data are shared. Some of these lessons are reiterations of previous work, but several new lessons originated from the latest 2019 acquisition. This was the first survey in which independent simultaneous sources were successfully deployed to collect a time-lapse survey. This resulted in a much faster and less expensive acquisition. In addition, full-waveform inversion was used as the main tool to update the velocity model, enabling a much faster turnaround in processing. The fast turnaround enabled incorporation of the latest acquisition to better constrain the velocity model update. The updated velocity model was used for the final time-lapse migration. In the integration part, the 4D-assisted history-match workflow was engaged to update the reservoir model history match. All of the upgrades led to an overall faster, less expensive, and better way to incorporate the acquired data in the final business decisions.

scholarly journals Investigation of Properties Alternation during Super-Critical CO2 Injection in Shale

2019 ◽  
Vol 9 (8) ◽  
pp. 1686 ◽  
Author(s):  
Sai Wang ◽  
Kouqi Liu ◽  
Juan Han ◽  
Kegang Ling ◽  
Hongsheng Wang ◽  
...  
Keyword(s):  
Oil Recovery ◽  
Supercritical Co2 ◽  
Indentation Test ◽  
Nitrogen Adsorption ◽  
Xrd Analysis ◽  
Bet Surface Area ◽  
Co2 Injection ◽  
Co2 Flooding ◽  
Recovery Method ◽  
Injection Process

The low recovery of oil from tight liquid-rich formations is still a major challenge for a tight reservoir. Thus, supercritical CO2 flooding was proposed as an immense potential recovery method for production improvement. While up to date, there have been few studies to account for the formation properties’ variation during the CO2 Enhanced Oil Recovery (EOR) process, especially investigation at the micro-scale. This work conducted a series of measurements to evaluate the rock mechanical change, mineral alteration and the pore structure properties’ variation through the supercritical CO2 (Sc-CO2) injection process. Corresponding to the time variation (0 days, 10 days, 20 days, 30 days and 40 days), the rock mechanical properties were analyzed properly through the nano-indentation test, and the mineralogical alterations were quantified through X-ray diffraction (XRD). In addition, pore structures of the samples were measured through the low-temperature N2 adsorption tests. The results showed that, after Sc-CO2 injection, Young’s modulus of the samples decreases. The nitrogen adsorption results demonstrated that, after the CO2 injection, the mesopore volume of the sample would change as well as the specific Brunauer–Emmett–Teller (BET) surface area which could be aroused from the chemical reactions between the CO2 and some authigenic minerals. XRD analysis results also indicated that mesopore were altered due to the chemical reaction between the injected Sc-CO2 and the minerals.

scholarly journals Experimental Study on Reducing CO2–Oil Minimum Miscibility Pressure with Hydrocarbon Agents

Energies ◽  
2019 ◽  
Vol 12 (10) ◽  
pp. 1975 ◽  
Author(s):  
Junrong Liu ◽  
Lu Sun ◽  
Zunzhao Li ◽  
Xingru Wu
Keyword(s):  
Crude Oil ◽  
Petroleum Ether ◽  
Oil Recovery ◽  
Mass Concentration ◽  
Co2 Flooding ◽  
Oil Viscosity ◽  
Injection Wells ◽  
Boiling Range ◽  
Minimum Miscibility Pressure ◽  
Soluble Surfactants

CO2 flooding is an important method for improving oil recovery for reservoirs with low permeability. Even though CO2 could be miscible with oil in regions nearby injection wells, the miscibility could be lost in deep reservoirs because of low pressure and the dispersion effect. Reducing the CO2–oil miscibility pressure can enlarge the miscible zone, particularly when the reservoir pressure is less than the needed minimum miscible pressure (MMP). Furthermore, adding intermediate hydrocarbons in the CO2–oil system can also lower the interfacial tension (IFT). In this study, we used dead crude oil from the H Block in the X oilfield to study the IFT and the MMP changes with different hydrocarbon agents. The hydrocarbon agents, including alkanes, alcohols, oil-soluble surfactants, and petroleum ethers, were mixed with the crude oil samples from the H Block, and their performances on reducing CO2–oil IFT and CO2–oil MMP were determined. Experimental results show that the CO2–oil MMP could be reduced by 6.19 MPa or 12.17% with petroleum ether in the boiling range of 30–60 °C. The effects of mass concentration of hydrocarbon agents on CO2–oil IFT and crude oil viscosity indicate that the petroleum ether in the boiling range of 30–60 °C with a mass concentration of 0.5% would be the best hydrocarbon agent for implementing CO2 miscible flooding in the H Block.

scholarly journals Experimental Investigation on the Effects of CO2 Displacement Methods on Petrophysical Property Changes of Ultra-Low Permeability Sandstone Reservoirs Near Injection Wells

Energies ◽  
2019 ◽  
Vol 12 (2) ◽  
pp. 327 ◽  
Author(s):  
Qian Wang ◽  
Shenglai Yang ◽  
Haishui Han ◽  
Lu Wang ◽  
Kun Qian ◽  
...  
Keyword(s):  
Physical Properties ◽  
Pore Size ◽  
Mineral Dissolution ◽  
Co2 Injection ◽  
Low Permeability ◽  
Co2 Flooding ◽  
Formation Water ◽  
Injection Wells ◽  
Rock Interaction ◽  
Sandstone Reservoirs

The petrophysical properties of ultra-low permeability sandstone reservoirs near the injection wells change significantly after CO2 injection for enhanced oil recovery (EOR) and CO2 storage, and different CO2 displacement methods have different effects on these changes. In order to provide the basis for selecting a reasonable displacement method to reduce the damage to these high water cut reservoirs near the injection wells during CO2 injection, CO2-formation water alternate (CO2-WAG) flooding and CO2 flooding experiments were carried out on the fully saturated formation water cores of reservoirs with similar physical properties at in-situ reservoir conditions (78 °, 18 MPa), the similarities and differences of the changes in physical properties of the cores before and after flooding were compared and analyzed. The measurement results of the permeability, porosity, nuclear magnetic resonance (NMR) transversal relaxation time (T2) spectrum and scanning electron microscopy (SEM) of the cores show that the decrease of core permeability after CO2 flooding is smaller than that after CO2-WAG flooding, with almost unchanged porosity in both cores. The proportion of large pores decreases while the proportion of medium pores increases, the proportion of small pores remains almost unchanged, the distribution of pore size of the cores concentrates in the middle. The changes in range and amplitude of the pore size distribution in the core after CO2 flooding are less than those after CO2-WAG flooding. After flooding experiments, clay mineral, clastic fines and salt crystals adhere to some large pores or accumulate at throats, blocking the pores. The changes in core physical properties are the results of mineral dissolution and fines migration, and the differences in these changes under the two displacement methods are caused by the differences in three aspects: the degree of CO2-brine-rock interaction, the radius range of pores where fine migration occurs, the power of fine migration.

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