Sulphate Removal for Barium Sulphate Scale Mitigation a Deepwater Subsea Production System

Author(s):  
I.R. Collins ◽  
R. Stalker ◽  
G.M. Graham
2021 ◽  
pp. 109072
Author(s):  
Yi Wang ◽  
Qi Wang ◽  
Aixia Zhang ◽  
Weiwei Qiu ◽  
Menglan Duan ◽  
...  

2021 ◽  
Author(s):  
Joseph Rizzo Cascio ◽  
Antonio Da Silva ◽  
Martino Ghetti ◽  
Martino Corti ◽  
Marco Montini

Abstract Objectives/Scope The benefits of real-time estimation of the cool down time of Subsea Production System (SPS) to prevent formation of hydrates are shown on a real oil and gas facility. The innovative tool developed is based on an integrated approach, which embeds a proxy model of SPS and hydrate curves, exploiting real-time field data from the Eni Digital Oil Field (eDOF, an OSIsoft PI based application developed and managed by Eni) to continuously estimate the cool down time before hydrates are formed during the shutdown. Methods, Procedures, Process The Asset value optimization and the Asset integrity of hydrocarbon production systems are complex and multi-disciplinary tasks in the oil and gas industry, due to the high number of variables and their synergy. An accurate physical model of SPS is built and, then, used to develop a proxy model, which integrates hydrate curves at different MeOH concentration, being able to estimate in real time the cool down time of SPS during the shutdown exploiting data from subsea transmitters made available by eDOF in order to prevent formation of hydrates. The tool is also integrated with a user-friendly interface, making all relevant information readily available to the operators on field. Results, Observations, Conclusions The integrated approach provides a continues estimation of cool down time based on real time field data (eDOF) in order to prevent formation of hydrates and activate preservation actions. An accurate physical model of SPS is built on a real business case using Olga software and cool down curves simulated considering different operating shutdown scenarios. Hydrate curves of the considered production fluid are also simulated at different MeOH concentration using PVTsim NOVA software. Off-line simulated curves are then implemented as numerical tables combined with eDOF data by an Eni developed fast executing proxy model to produce estimated cool down time before hydrates are formed. A graphic representation of SPS behavior and its cool down time estimation during shutdown are displayed and ready to use by the operators on field in support of the operations, saving cost and time. Novel/Additive Information The benefits of real time estimation of the cool down time of SPS to prevent hydrates formation are shown in terms of saving of time and cost during the shutdown operations on a real case application. This integrated approach allows to rely on a continue, automatic and acceptably accurate estimate of the available time before hydrates are formed in SPS, including the possibility to be further developed for cases where subsea transmitters are not available or extended to other flow assurance issues.


Author(s):  
Magdalena Balintova ◽  
Stefan Demcak ◽  
Adriana Estokova ◽  
Marian Holub ◽  
Petra Pavlikova

Industrial wastewaters, particularly those associated with mining and mineral processing, can contain high con-centrations of sulphate. There are various methods of sulphate removal e.g. reverse osmosis, ion exchange, precipitation by lime, cements, and salts of barium and the biological removal process. The soluble salts of barium are most commonly used for precipitation of sulphate from aquatic acidic solutions to the insoluble product barium sulphate BaSO4. Benefits of precip-itation are high sulphate removal efficiency but limitations are toxicity of barium compounds and high economical costs. For this reason the recycling of BaSO4 to barium sulphide BaS (the precipitating reagent) is very important. The paper deals with study of BaSO4 reduction by activated carbon to BaS by thermal analysis and infrared spectrometry. DCS analysis indicated that conversion of BaSO4 to BaS in the range of temperature 800–1,000 °C was performed. Thermal analysis and infrared spectra of the products confirmed the change in its composition, but process of reduction by carbon was incomplete and in sample was still present a part of BaSO4. Presence of BaS was confirmed by colorimetric method.


2011 ◽  
Vol 148-149 ◽  
pp. 1000-1006 ◽  
Author(s):  
Chang Yong Wang ◽  
Hong Huan Zhang ◽  
Meng Lan Duan

That the oil and gas exploration and development is extending into deep water proceeds the rapidly shift to subsea production system. However, complex subsea equipment and frequency offshore accidents aroused the concern on the risk assessment of subsea system. The paper illustrates the hazard aspects which should be focused on in the subsea equipment compared with the surface equipment. The hazards identification and risk analysis on subsea X-tree system is carried out. A general risk-prevent process of subsea X-tree system is illustrated, so does the reliability analysis process. Besides, some commendations on subsea detection and maintenance are presented in the paper.


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