DDTW-A Method for Gas Reservoir Evaluation Using Dual Wait-Time NMR and Density Log Data

2001 ◽  
Vol 4 (04) ◽  
pp. 289-296
Author(s):  
Holger F. Thern ◽  
Songhua Chen

Summary Accurate estimates of porosity, fluid saturations, and in-situ gas properties are critical for the evaluation of a gas reservoir. By combining data from a dual wait-time (DTW) nuclear magnetic resonance (NMR) log and a density log, these properties can be determined more reliably than by either of the data alone. The density and NMR dual wait-time (DDTW) technique, introduced in this paper, is applicable to reservoirs where the pore-filling fluid consists of a liquid phase and a gas phase. The low proton density of the gas phase causes a reduction in the NMR signal strength resulting in underestimation of the apparent porosity. The polarization for different wait-times depends on the spin-lattice relaxation time of each fluid and may cause additional NMR porosity underestimation. The density log, on the other hand, delivers a porosity that is overestimated because of the presence of a gas phase. These data, together with known correlations for gas properties, yield a robust approach for the gas-zone porosity, f, and the flushed zone gas saturation, Sg, xo. DDTW also derives gas properties including the in-situ gas density, ?g, as well as the two NMR-related properties, hydrogen index, IH, g, and spin-lattice relaxation time, T1g. Two field examples illustrate the method, and an error propagation study shows the reliability of the technique. Introduction NMR well logging yields information about fluid and rock properties. Depending on the goal of the investigation, various NMR measurement procedures are employed. Differences in the acquisition pulse sequence - including the wait-time (tw) between the echo-train measurements - characterize these procedures. Common evaluation techniques estimate different petrophysical properties, such as incremental and total porosities or movable (fm, NMR) and irreducible (fir, NMR) fluid fractions. More sophisticated methods separate the response of multiple fluids for hydrocarbon typing and saturation estimation. DTW NMR Log. Water as the wetting phase is dominated by surface relaxation and usually has a shorter T1 than hydrocarbons. DTW NMR uses the T1 contrast between aqueous fluid and hydrocarbon phases to achieve partial or full polarization for different fluid phases. The DTW log acquires two echo trains with a long (tw, L) and a short (tw, S) wait-time in a single pass; tw, L is chosen to fully polarize both water and hydrocarbon, and tw, S is sufficiently long to fully polarize the water fraction, while the hydrocarbon fraction is only partially polarized, causing porosity underestimation. An interpretation technique for DTW NMR data - used mainly qualitatively - is the differential spectrum method (DSM).1 A successful quantitative evaluation technique is the time domain analysis (TDA).2 Both techniques require the calculation of either differential echo signals or differential T2 spectra, where the spectra are derived from echo-train data by inversion. The differential signals are significantly weaker than the original signal, and the noise level increases because the incoherent noise of the echo trains is added. Differential data, therefore, are unfavorable in terms of their signal-to-noise ratio (SNR). SNR often limits the applicability of evaluation techniques that are based solely on NMR data. Particularly when coupled with low hydrocarbon saturation and the low proton density of a gas phase, poor SNR is the limiting factor in estimating accurate reservoir properties. Density Log. The density log provides a bulk density, ?b, of the investigated formation. Additional information about the density of the rock matrix and formation fluids determines the density porosity fr. An established method to evaluate gas-bearing formations combines the apparent porosities provided by the density and the neutron logging tools. For many data sets, however, this method yields only semiquantitative results because of the strong influence of rock mineralogy on the neutron measurement. Theory The porosity of clean formations bearing only liquid-phase components can be accurately quantified by either the NMR or the density logging tool. However, the tool's responses are significantly altered by the presence of a gas phase, causing the estimated porosities to deviate from the formation porosity. Three main effects cause the deviation.Low IH, g decreases the NMR porosity.Partial polarization Pg<1 decreases the NMR-derived porosity, if the wait-time between the NMR measurements is insufficiently long.Low ?g increases the density porosity. The characterization of a hydrocarbon gas by three key properties, ?g, IH, g, and T1g, effectively quantifies these effects. DTW NMR Log. In a two-phase system with one gas and one liquid phase, the total NMR porosity ft, NMR is expressed byEquation 1 where the first term on the right side describes the contribution of the gas phase and the second term describes the contribution of the liquid phase. The polarization P (with P?[0,1]) quantifies the reduction of the NMR signal caused by underpolarization. The termsEquation 2Equation 3 describe the polarization of the liquid and gas phases, respectively. Some approximations can be made for common reservoir conditions.IH, l is close to 1 for an aqueous-phase liquid and most oleic-phase liquids. In the presence of a light liquid hydrocarbon, its value can be slightly smaller (IH, l =0.8-1).If tw 3T1, the polarization is nearly unity. Typical tw values range from 1 to several seconds, whereas typical T1 values for formation water range from a few milliseconds to a few seconds. However, in a porous medium saturated with two fluid phases, the wetting phase (i.e., water) saturates smaller pores, and the maximum T1 of the aqueous-phase liquid usually reduces to values less than several hundreds of milliseconds.3 Thus, Pl is unity for aqueous-phase liquids in a two-phase system, when data are acquired with typical wait-time parameters in an MRIL®* DTW acquisition (i.e., tw, S,˜1–2 seconds and tw, L,˜6–10 seconds).

Author(s):  
Vladimir A. Nikiforov ◽  
Elena I. Laguseva ◽  
Evgeny A. Pankratov ◽  
Ilya S. Zhokhov

The brief characteristics of the reaction system of pilot production of fatty-aromatic polyamides based on aliphatic diamines (acylated monomers) and dicarboxylic acid dichloroanhydrides (acylating monomers) by the method of gas-liquid polycondensation in a highly turbulized foamy hydrodynamic mode are described. Technological scheme and rational instrumentation of the technology of polyterephthalamides, the reactor unit (reactor-fibridator), which includes a two-stage reaction chamber and a gas phase generating chamber coaxially located under it, chemistry and operating principle of the facility are shown. The method combines the chemical processes of polyamidation with the physical processes of the reaction molding of polyamide fibrids or gas-structural elements used in the technology of gas-filled plastics. The reaction system of the method includes three structural units: a liquid phase (aqueous alkaline solution of aliphatic, cycloaliphatic and fatty-aromatic diamines), a gas phase (superheated vapours of aromatic and aliphatic dicarboxylic acid dichloroanhydrides, dispersed in a dynamic airflow or inert gas) and an interface (gas-liquid interface). Gas-liquid polyamidation is accompanied by phase formation: the reaction system during the process becomes three-phase system – the swollen polymer forms a solid mobile phase (target product), which acts as a foamy mode stabilizer, which allows technological process to proceed at optimal linear gas phase rates of 30–35 m/s (unlike classical two-phase foamy mode – 4 m/s). A polyamidation mechanism at the liquid-gas interface is proposed, which includes two versions of the process (adsorption and condensation) depending on the ratio of the temperature characteristics of the acylated monomer and the liquid phase carrying the acylating monomer. Analysis of the proposed versions of the mechanism allows you to make an engineering decision on the expediency of organizing a cycle in the liquid phase. Possible criteria for predicting the versions of the mechanism and examples of reaction systems with condensation and absorption versions of polyamidation are given.


2017 ◽  
Vol 14 (06) ◽  
pp. 1750063 ◽  
Author(s):  
A. M. Hegab ◽  
S. A. Gutub ◽  
A. Balabel

This paper presents the development of an accurate and robust numerical modeling of instability of an interface separating two-phase system, such as liquid–gas and/or solid–gas systems. The instability of the interface can be refereed to the buoyancy and capillary effects in liquid–gas system. The governing unsteady Navier–Stokes along with the stress balance and kinematic conditions at the interface are solved separately in each fluid using the finite-volume approach for the liquid–gas system and the Hamilton–Jacobi equation for the solid–gas phase. The developed numerical model represents the surface and the body forces as boundary value conditions on the interface. The adapted approaches enable accurate modeling of fluid flows driven by either body or surface forces. The moving interface is tracked and captured using the level set function that initially defined for both fluids in the computational domain. To asses the developed numerical model and its versatility, a selection of different unsteady test cases including oscillation of a capillary wave, sloshing in a rectangular tank, the broken-dam problem involving different density fluids, simulation of air/water flow, and finally the moving interface between the solid and gas phases of solid rocket propellant combustion were examined. The latter case model allowed for the complete coupling between the gas-phase physics, the condensed-phase physics, and the unsteady nonuniform regression of either liquid or the propellant solid surfaces. The propagation of the unsteady nonplanar regression surface is described, using the Essentially-Non-Oscillatory (ENO) scheme with the aid of the level set strategy. The computational results demonstrate a remarkable capability of the developed numerical model to predict the dynamical characteristics of the liquid–gas and solid–gas flows, which is of great importance in many civilian and military industrial and engineering applications.


Author(s):  
Zhichao Guo ◽  
Zhaoci Li

Abstract In 2018, China’s natural gas import reached 90.39 million tons, and the liquefied natural gas (LNG) import was 53.78 million tons, accounting for 59.5% of total natural gas imports. With the construction of LNG terminals, more studies on the leakage of LNG storage and transportation facilities have emerged to prevent catastrophic consequences such as explosions and frostbite. However, most of previous researches focused on gas pipeline leakage after LNG gasification, and few of those have been done on LNG liquid pipeline leakage. In this paper, Fluent software is used to numerically simulate the process of LNG liquid pipeline leakage. After the occurrence of LNG leakage, it will suffer the process of endothermic, evaporation, and diffusion, which is considered as a two-phase diffusion process. The Euler-Lagrangian method is introduced to simulate the diffusion process of gas phase and liquid phase separately. In the simulation, the liquid phase is regarded as discrete droplets for discrete processing. The movement trajectory, heat transfer process and evaporation process of each droplet are tracked respectively. Different from the liquid phase, the gas phase is regarded as a continuous phase and the Navier-Stokes equations are adopted for calculation. Thereafter, coupling calculations of two phase are performed to determine the concentration field and temperature field of the LNG liquid pipeline leakage. As a supplement to this research, the influence of wind speed on LNG leakage and diffusion process is analysed in detail. Finally, the numerical simulation method is applied to a coastal LNG terminal in northern China to determine the distribution of natural gas concentration and temperature, as well as delimit the combustion range. The results can provide scientific reference for the delimitation of risky zones and the formulation of emergency response strategy.


2007 ◽  
Vol 7 (21) ◽  
pp. 5555-5567 ◽  
Author(s):  
L. Smoydzin ◽  
R. von Glasow

Abstract. Organic material from the ocean's surface can be incorporated into sea salt aerosol particles often producing a surface film on the aerosol. Such an organic coating can reduce the mass transfer between the gas phase and the aerosol phase influencing sea salt chemistry in the marine atmosphere. To investigate these effects and their importance for the marine boundary layer (MBL) we used the one-dimensional numerical model MISTRA. We considered the uncertainties regarding the magnitude of uptake reduction, the concentrations of organic compounds in sea salt aerosols and the oxidation rate of the organics to analyse the possible influence of organic surfactants on gas and liquid phase chemistry with a special focus on halogen chemistry. By assuming destruction rates for the organic coating based on laboratory measurements we get a rapid destruction of the organic monolayer within the first meters of the MBL. Larger organic initial concentrations lead to a longer lifetime of the coating but lead also to an unrealistically strong decrease of O3 concentrations as the organic film is destroyed by reaction with O3. The lifetime of the film is increased by assuming smaller reactive uptake coefficients for O3 or by assuming that a part of the organic surfactants react with OH. With regard to tropospheric chemistry we found that gas phase concentrations for chlorine and bromine species decreased due to the decreased mass transfer between gas phase and aerosol phase. Aqueous phase chlorine concentrations also decreased but aqueous phase bromine concentrations increased. Differences for gas phase concentrations are in general smaller than for liquid phase concentrations. The effect on gas phase NO2 or NO is very small (reduction less than 5%) whereas liquid phase NO2 concentrations increased in some cases by nearly 100%. We list suggestions for further laboratory studies which are needed for improved model studies.


1998 ◽  
Vol 42 (4) ◽  
pp. 471-478 ◽  
Author(s):  
Agnès Choplin ◽  
Silvia Dos Santos ◽  
Françoise Quignard ◽  
Silvana Sigismondi ◽  
Denis Sinou

1985 ◽  
Vol 146 (1) ◽  
pp. 31-35 ◽  
Author(s):  
J. A. O. Besson ◽  
F. M. Corrigan ◽  
E. Iljon Foreman ◽  
L. M. Eastwood ◽  
F. W. Smith ◽  
...  

SummaryProton NMR imaging of the brain is rapidly becoming established as a useful investigative tool in medicine. This paper examines the usefulness of the NMR parameters—spin-lattice relaxation time (T1) and proton density (PD)—in differentiating groups of patients with senile dementia of Alzheimer type (SDAT) and multi-infarct dementia (MID) from each other, and from elderly controls. T1 values increase with severity of dementia. NMR parameters may also be of use in localising regions of brain damage.


Author(s):  
Sergey A. Zanochuev ◽  
Alexander B. Shabarov

Within the objectives of predicting the composition and properties of the produced fluid during the development of oil and gas condensate fields, this article proposes an experimental method for predicting the composition and properties of the produced fluid. In addition, the authors show its practical use in a situation where the liquid phase (precipitated condensate or oil) is filtered together with the gas phase. Based on the proposed approach, experimental data were obtained on changes in the current gas saturation of the formation, as well as on changes in the composition and properties of the produced fluid during field development for depletion. The studies make use of the real reservoir fluid samples and the data from the results of stream experiments, in order to determine the relative phase permeabilities.


2005 ◽  
Vol 71 (11) ◽  
pp. 6606-6612 ◽  
Author(s):  
Grit Neumann ◽  
Nadja Kabelitz ◽  
Andreas Zehnsdorf ◽  
Anja Miltner ◽  
Holger Lippold ◽  
...  

ABSTRACT The strain Pseudomonas putida DOT-T1E was tested for its ability to tolerate second phases of different alkanols for their use as solvents in two-liquid-phase biotransformations. Although 1-decanol showed an about 10-fold higher toxicity to the cells than 1-octanol, the cells were able to adapt completely to 1-decanol only and could not be adapted in order to grow stably in the presence of a second phase of 1-octanol. The main explanation for this observation can be seen in the higher water and membrane solubility of 1-octanol. The hydrophobicity (log P) of a substance correlates with a certain partitioning of that compound into the membrane. Combining the log P value with the water solubility, the maximum membrane concentration of a compound can be calculated. With this simple calculation, it is possible to predict the property of an organic chemical for its potential applicability as a solvent for two-liquid-phase biotransformations with solvent-tolerant P. putida strains. Only compounds that show a maximum membrane concentration of less than 400 mM, such as 1-decanol, seem to be tolerated by these bacterial strains when applied in supersaturating concentrations to the medium. Taking into consideration that a solvent for a two-liquid-phase system should possess partitioning properties for potential substrates and products of a fine chemical synthesis, it can be seen that 1-decanol is a suitable solvent for such biotransformation processes. This was also demonstrated in shake cultures, where increasing amounts of a second phase of 1-decanol led to bacteria tolerating higher concentrations of the model substrate 3-nitrotoluene. Transferring this example to a 5-liter-scale bioreactor with 10% (vol/vol) 1-decanol, the amount of 3-nitrotoluene tolerated by the cells is up to 200-fold higher than in pure aqueous medium. The system demonstrates the usefulness of two-phase biotransformations utilizing solvent-tolerant bacteria.


2005 ◽  
Vol 44 (10) ◽  
pp. 1054-1062 ◽  
Author(s):  
Yong-Jun Cho ◽  
Hee-Chul Yang ◽  
Hee-Chul Eun ◽  
Jae-Hyung Yoo ◽  
Joon-Hyung Kim

2005 ◽  
Vol 77 (9) ◽  
pp. 1575-1581 ◽  
Author(s):  
Valeria Conte ◽  
Barbara Floris ◽  
Pierluca Galloni ◽  
Adriano Silvagni

Oxybromination reaction of styrene was performed in a two-phase system of water/ionic liquids (ILs). The aim of the work was to make the mild and efficient two-phase system previously developed for the vanadium(V)-catalyzed oxybromination of alkenes, inspired by the activity of haloperoxidase enzymes, even more interesting from a sustainable point of view. As in that case, a brominating intermediate was formed from the metal catalyst, H2O2, and bromide ion in the acid aqueous phase, but chlorinated solvents were replaced with ILs.[bmim+][PF6-], [bm2im+][PF6-], [bmim+][BF4-], [bmim+][CF3SO3-], and [bmim+][(CF3SO2)2N-] were tested. We report on interesting results in terms of reaction rates and selectivities.


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