Kinetics of CaCO3 Scale Formation. The Influence of Temperature, Supersaturation and Ionic Composition

Author(s):  
Terje Østvold ◽  
Preben Randhol
2013 ◽  
Vol 634-638 ◽  
pp. 541-545 ◽  
Author(s):  
Jun Seong Park ◽  
Dae Hee Yun ◽  
Tae Won Ko ◽  
Yong Sung Park ◽  
Je Wan Woo

The kinetics of the Diels-Alder reaction of cyclopentadiene with bis(2-ethylhexyl) maleate has been studied at temperatures between 25 and 100 °C and at atmospheric pressure. The influence of temperature on the kinetic constants was determined by fitting the results to the Arrhenius equation. As a result, fitting line similar with the linear curve of the Arrhenius equation at 25, 30 and 40 °C. However, the fitting curve, at 60, 80 and 100 °C, tended towards the outside of the curve in the form of Arrhenius equation. The ratio of endo/exo was a slight change from increase of the reaction temperature.


2014 ◽  
Vol 955-959 ◽  
pp. 2306-2309
Author(s):  
Shu Bin Zhao ◽  
Pan Zhang ◽  
Xiao Tong Cai ◽  
Dong Fu

The absorption rates of CO2 in diethanolamine (DEA) promoted N-methyldiethanolamine (MDEA) aqueous solution were measured at normal pressure with temperatures ranging from 303.15-323.15K. The influence of temperature and the mass fraction of DEA on the absorption rate of CO2 was illustrated.


1998 ◽  
Vol 54 (3-4) ◽  
pp. 131-145 ◽  
Author(s):  
Fenwei Su ◽  
K Hanumantha Rao ◽  
K.S.E Forssberg ◽  
P.O Samskog

2015 ◽  
Vol 228 ◽  
pp. 237-241
Author(s):  
Magdalena Popczyk ◽  
B. Łosiewicz

The Ni+MoS2composite coatings were prepared by electrodeposition under galvanostatic conditions from the Ni-plating bath containing suspended MoS2powder (100 mesh). Investigations of hydrogen evolution reaction (HER) were carried out using steady-state polarization measurements and electrochemical impedance spectroscopy (EIS) in 5 M KOH solution on the coatings obtained at 30, 40, and 50°C. It was found that the kinetics of the HER on the Ni+MoS2coatings decreases with the increase in the electrodeposition temperature of the coatings. This effect is attributed to decreasing content of MoS2(from 26.4 to 18.0 wt.%) embedded into the Ni matrix as composite crystalline component having the electrocatalytic properties towards the HER and/or surface development of the coatings. The higher amount of MoS2was embedded, the more porous electrodes containing pear-shape pores on the surface were produced what was detected by EIS.


2018 ◽  
Vol 509 ◽  
pp. 488-495 ◽  
Author(s):  
Yulia Arinicheva ◽  
Clemence Gausse ◽  
Stefan Neumeier ◽  
Felix Brandt ◽  
Konstantin Rozov ◽  
...  

2012 ◽  
Vol 31 (1) ◽  
Author(s):  
Michal Besterci ◽  
Marián Varchola ◽  
Ladislav Kováč ◽  
Oksana Velgosová

AbstractThe influence of temperature at constant strain rate has been evaluated with respect to superplastic behavior of dispersion strengthened Al-Al


2008 ◽  
Author(s):  
Tore Larsen ◽  
Maria Lioliou ◽  
Terje Ostvold ◽  
Leif Olav Josang ◽  
Preben Randhol

1947 ◽  
Vol 30 (5) ◽  
pp. 379-387 ◽  
Author(s):  
Eric Ponder

In systems containing human red cells and sodium taurocholate as a lysin, or distearyl lecithin as a sphering agent, the prolytic loss of K at 25°C. is accompanied by a gain of Na by the cell, the gain being somewhat greater than the K loss. A small volume increase accompanies the exchange. The kinetics of the K loss and the Na gain are similar to those already described; i.e., the changes are rapid at first, and slow down so that after 12 to 20 hours it appears that a new steady state is being approached. Similar, but smaller, losses of K and gains of Na occur when the cells stand in isotonic NaCl at 25°C. without the addition of a lysin or sphering agent. On these and other experimental grounds, it is impossible to retain the idea that the mammalian red cell in general is impermeable to cations. The cells nevertheless seem to be in a steady state with respect to their environment, their ionic composition changing as the composition of the environment is changed. The possible processes by means of which one steady state can be exchanged for another—changes in the permeability of a surface membrane, changes in the velocity of an active ion transfer process dependent on red cell metabolism, and changes in the activity of the ions in the red cell interior as a result of changes in an orderly internal structure—are discussed.


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