Asphaltene Precipitation and Alteration of Wetting: Can Wettability Change during Oil Production?

Author(s):  
Rashid S.H. Al-Maamari ◽  
Jill S. Buckley
2020 ◽  
pp. 120-127
Author(s):  
E. N. Skvortsova ◽  
O. P. Deryugina

The article discusses the results of a study on the selection of wax inhibitors that can be used at the Kondinskoye oil field during transportation and dehydration of the emulsion.Asphaltene precipitation is one of the most serious issues in oil production. The experiment was conducted in order to select the most effective wax inhibitors. We have carried out laboratory tests to choose the most effective wax inhibitor in the conditions of oil production, collection, preparation and external transport systems at the Kondinskoye oil field. Based on the data obtained, wax inhibitor-2, wax inhibitor-4, and wax inhibitor-6 have shown the best results in ensuring the efficiency of inhibition, which should be at least 70 %, and, therefore, they can be allowed to pilot tests. The recommended initial dosage of inhibitors according to the results obtained during pilot tests should be at least 500 g/t of oil.


2013 ◽  
Vol 52 (17) ◽  
pp. 6009-6031 ◽  
Author(s):  
Sohrab Zendehboudi ◽  
Mohammad Ali Ahmadi ◽  
Omidreza Mohammadzadeh ◽  
Alireza Bahadori ◽  
Ioannis Chatzis

2020 ◽  
Vol 39 (1) ◽  
pp. 22-28 ◽  
Author(s):  
Qian Wang ◽  
Piroska Lorinczi ◽  
Paul W. J. Glover

The blockage and alteration of wettability in reservoirs caused by asphaltene deposits are problems that contribute to poor oil recovery performance during carbon dioxide (CO2) injection. Oil production and reservoir damage are both controlled by macroscopic interlayer heterogeneity and microscopic pore-throat structure and may be optimized by the choice of flooding method. In this work, the residual oil distribution and the permeability decline caused by organic and inorganic precipitation after miscible CO2 flooding and water-alternating-CO2 (CO2-WAG) flooding have been studied by carrying out core-flooding experiments on a model heterogeneous three-layer reservoir. For CO2, flooding experimental results indicate that the low-permeability layers retain a large oil production potential even in the late stages of production, while the permeability decline due to formation damage is larger in the high-permeability layer. We found that CO2-WAG can reduce the influence of heterogeneity on the oil production, but it results in more serious reservoir damage, with permeability decline caused by CO2–brine–rock interactions becoming significant. In addition, miscible CO2 flooding has been carried out for rocks with similar permeabilities but different wettabilities and different pore-throat microstructures in order to study the effects of wettability and pore-throat microstructure on formation damage. Reservoir rocks with smaller pore-throat sizes and more heterogeneous pore-throat microstructures were found to be more sensitive to asphaltene precipitation, with corresponding lower oil recovery and greater decreases in permeability. However, it was found that the degree of water wetness for cores with larger, more connected pore-throat microstructures became weaker due to asphaltene precipitation to pore surfaces. Decreasing the degree of water wetness was found to be exacerbated by increases in the sweep volume of injected CO2 that arise from cores with larger and better connected pore throats. Erosion of water wetness is a disadvantage for enhanced oil recovery operations as asphaltene precipitation prevention and control measures become more necessary.


Author(s):  
Abdulaziz S. Al-Qasim ◽  
Mohammed Alasker

Serious operational problems caused by asphaltene deposition during oil production have driven the ongoing effort to understand this phenomenon. Many studies have focused on related asphaltene precipitation flocculation and deposition in oil reservoirs and flow assurance in the wellbores. Experimental techniques and theoretical models have been developed trying to understand and predict asphaltene behavior. Nevertheless, some ambiguities still remain with regard to the characterization of asphaltene in crude oil and its stability during the primary, secondary, and tertiary recovery stages within the near-wellbore regions. The paper will review asphaltene in crude oil systems: asphaltene properties and their impact on oil production, including the effects of pressure, temperature, and composition. Asphaltene content is an important factor in determining the properties of a crude oil. Three main methods are used to measure the asphaltene content in laboratory: the first method called SARA, which separates dead oil into saturates, aromatics, resins, and asphaltenes depending on their solubility and polarity. The second is aliphatic hydrocarbon titration using dead oil; in this method the asphaltene precipitation point is detected by the asphaltene precipitation detection unit (APDU). The third method is the depressurization of a live oil bottomhole sample, this method depends on monitoring the flocculation point due to light transmittance caused by the infrared laser [3]. Solubility and density parameters trends are proportional to the pressure depletion until the pressure reaches the bubble point. Below the bubble point pressure (Pb), the solubility and density are inversely proportional to the pressure. The solubility increases linearly with temperature until the reservoir temperature, after that, it decreases linearly as the temperature increases. These advanced measurements facilitate an understanding of petroleum heavy constituents. Anew research field called “Petroleomics” has started receiving more attention; it is based on integrating the different knowledge of chemical composition of petroleum to develop correlation studies and improve the prediction of asphaltene phase behavior.


2003 ◽  
pp. 136-146
Author(s):  
K. Liuhto

Statistical data on reserves, production and exports of Russian oil are provided in the article. The author pays special attention to the expansion of opportunities of sea oil transportation by construction of new oil terminals in the North-West of the country and first of all the largest terminal in Murmansk. In his opinion, one of the main problems in this sphere is prevention of ecological accidents in the process of oil transportation through the Baltic sea ports.


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