Thermal Behavior of Unconsolidated Oil Sands

1974 ◽  
Vol 14 (05) ◽  
pp. 513-521 ◽  
Author(s):  
W.H. Somerton ◽  
J.A. Keese ◽  
S.L. Chu

ABSTRACT Thermal conductivities of unconsolidated oil sands have been measured and the results correlated with physical properties of the sand-fluid system. Saturation of the wetting fluid has a dominant effect on thermal conductivity values. Water-saturated sands were found to have thermal conductivities six to eight times greater than values for the same sand packs air saturated. For correlation purposes, the porosity of a sand pack is an adequate indicator of matrix structure. Other quantities needed to develop a satisfictory equation for predicting thermal conductivity are the conductivities of the wetting fluid and of the rock solids. The effects of changes in temperature on the thermal conductivity of unconsolidated oil sands are relatively small and can be evaluated with a simple linear equation. The effects of changes in pressure on the thermal conductivity of liquid-saturated unconsolidated sands are also small and for practical purposes can be ignored. Results of the present work are believed to have direct application to calculations relating to thermal processes in underground reservoirs. Core-analysis and well-log data can be used to evaluate the thermal properties of unconsolidated oil sands required for such calculations. INTRODUCTION The most successful thermal recovery operations are those that have been applied to relatively shallow producing formations consisting mostly of unconsolidated sands. Necessary in designing such projects is a knowledge of the thermal properties and behavior of the sand-fluid system under reservoir conditions of saturation, pressure, and temperature. A great deal of literature has been published on the thermal properties of granular materials, and several models and correlations for predicting thermal properties have been proposed.1–5 Unfortunately, most test data have been obtained for systems or conditions much different from those found in petroleum reservoirs. Most models or prediction equations do not cover ranges of variables of importance to subsurface applications and, in addition, often require knowledge of system parameters that normally are not readily available from common sources such as core analyses and well logs. The purpose of this work was to establish relationships between laboratory measurements of thermal properties and other more easily measurable properties of unconsolidated sands. Simple systems consisting of uniform-grain-size quartz sands saturated with single fluids were first studied. The work then progressed to more complex systems, including actual oilfield cores containing substantial portions of their original fluids. RELATIONSHIP OF THERMAL CONDUCTIVITY TO OTHER PHYSICAL PROPERTIES The thermal conductivity of fluid-saturated, unconsolidated sand is strongly dependent upon the saturation and thermal conductivity of the wetting phase fluid. Air- or gas-saturated sands characteristically have low thermal conductivities. This is because the contact areas between grains, through which heat must flow, are small. Introduction of a wetting-phase liquid greatly increases the thermal conductivity by increasing the effective grain contact area and thus enlarging the effective area through which heat can flow. Present experimental results show that the thermal conductivity of brine-saturated unconsolidated sands increases sixfold to eightfold over that of the same sand packs air saturated. This effect is considerably less pronounced in consolidated sandstones; Anand's data6 show a twofold to threefold increase between brine-saturated and air-saturated sand packs.

2019 ◽  
Vol 2 (22) ◽  
pp. 151-167 ◽  
Author(s):  
Izabela Staniszewska ◽  
Szymon Staszyński ◽  
Magdalena Zielińska

The aim of study was to determine the influence of sonication and freezing on the kinetic of the microwave-vacuum drying, energy consumption and physical properties of whole cranberries as well as evaluate the applicability of sonication instead of freezing in order to change their physical properties and the drying kinetic of whole cranberries. Microwave-vacuum drying of whole cranberries with/without initial treatments took from 12 ± 1 to 14.5 ± 0.5 minutes. All of treatments did not significantly shorten the drying time of cranberries. However, they increased SMER values even by 31%. Despite of cryogenic freezing, all of treatments significantly increased the values of Dew. Sonication combined with drying allowed to obtain dried berries characterized by the lowest cohesiveness (0.19±0.02), springiness (0.62±0.02) and chewiness (3.4±0.8 N), while cryogenic freezing combined with drying allowed to obtain dried fruits characterized by highest springiness (0.75±0.03) and low chewiness (3.3±0.5 N). The highest lightness (32.2±0.7), redness (32.6±0.8), and yellowness (11.1±0.7) were found for fruits subjected to initial convective freezing before drying. The efficiency of sonication in color change was comparable to cryogenic freezing and much lower than convective freezing. All of initial treatments increased such thermal properties of dried cranberries as thermal conductivity and thermal diffusivity.


Author(s):  
Mazhar Hussain ◽  
Daniel Levacher ◽  
Nathalie Leblanc ◽  
Hafida Zmamou ◽  
Irini Djeran Maigre ◽  
...  

Crude bricks are composite materials manufactured with sediments and natural fibers. Natural fibers are waste materials and used in construction materials for reinforcement. Their reuse in manufacturing reinforced crude bricks is eco-friendly and improves mechanical and thermal characteristics of crude bricks. Factors such as type of fibers, percentage of fibers, length of fibers and distribution of fibers inside the bricks have significant effect on mechanical, physical and thermal properties of biobased composite materials. It can be observed by tests such as indirect tensile strength, compressive strength for mechanical characteristics, density, shrinkage, color for physical properties, thermal conductivity and resistivity for thermal properties, and inundation test for durability of crude bricks. In this study, mechanical and physical characteristics of crude bricks reinforced with palm oil fibers are investigated and effect of change in percentage and length of fibers is observed. Crude bricks of size 4*4*16 cm3 are manufactured with dredged sediments from Usumacinta River, Mexico and reinforced with palm oil fibers at laboratory scale. For this purpose, sediments and palm oil fibers characteristics were studied. Length of fibers used is 2cm and 3cm. Bricks manufacturing steps such as sediments fibers mixing, moulding, compaction and drying are elaborated. Dynamic compaction is opted for compaction of crude bricks due to energy control. Indirect tensile strength and compressive strength tests are conducted to identify the mechanical characteristics of crude bricks. Physical properties of bricks are studied through density and shrinkage. Durability of crude bricks is observed with inundation test. Thermal properties are studied with thermal conductivity and resistivity test. Distribution and orientation of fibers and fibers counting are done to observe the homogeneity of fibers inside the crude bricks. Finally, comparison between the mechanical characteristics of crude bricks manufactured with 2cm and 3cm length with control specimen was made.


2015 ◽  
Vol 1727 ◽  
Author(s):  
M. Rifu ◽  
K. Shintani

ABSTRACTThe thermal conductivities of pillared-graphene nanostructures (PGNSs) are obtained using nonequilibrium molecular-dynamics simulation. It is revealed their thermal conductivities are much smaller than the thermal conductivities of carbon nanotubes (CNTs). This fact is explained by examining the density of states (DOS) of the local phonons of PGNSs. It is also found the thermal conductivity of a PGNS linearly decreases with the increase of the inter-pillar distance.


2014 ◽  
Vol 783-786 ◽  
pp. 437-442 ◽  
Author(s):  
Gun Young Oh ◽  
Dae Guen Kim ◽  
Young Gyu Yoo ◽  
Young Ok Yoon ◽  
Shae K. Kim ◽  
...  

The thermal conductivities of binary Mg-CaO and Mg-Zn, and ternary Mg-Zn-CaO alloys have been investigated by evaluating the effect of CaO on pure Mg and Mg-Zn alloys, with an emphasis to develop a new Mg alloy by compromising thermal conductivity, process-ability and mechanical property. The Mg alloys specimens were prepared by casting into a steel mold and then by machining. The thermal conductivities of the alloys were determined by evaluating the thermal properties of specific heat and diffusivity, from room temperature to 200 °C. OM, SEM, and EDS were used to analyze the microstructures and phases. The fluidity was also investigated by using a spiral fluidity mold for improved process-ability during actual die casting.


Author(s):  
Dan Parkes ◽  
Jon Busby ◽  
Simon J. Kemp ◽  
Estelle Petitclerc ◽  
Ian Mounteney

The Mercia Mudstone Group (MMG) crops out extensively across England and Wales and its thermal properties are required for the design of infrastructure such as ground source heating and cooling schemes and electrical cable conduits. Data from the literature and new data from a borehole core have been compiled to generate an updated range of thermal conductivities related to rock type and the lithostratigraphy. These indicate a total range in saturated vertical thermal conductivity of 1.67–3.24 W m−1 K−1, comprising 1.67–2.81 W m−1 K−1 for mudstones, 2.12–2.41 W m−1 K−1 for siltstones and 2.3–3.24 W m−1 K−1 for sandstones. These data are all from measurements on samples and there will be uncertainty when considering the thermal properties of the rock mass owing to micro- and macrostructural features. Geometric mean modelling of thermal conductivity based on mineralogy has overestimated the thermal conductivity. Correction factors for the modelled thermal conductivities have been calculated to allow a first estimate of MMG thermal conductivities when only mineralogical data are available. Measured thermal diffusivities from the borehole core were in the range of 0.63–3.07 × 10−6 m2 s−1 and are the first measured thermal diffusivities to be reported for the MMG.


Proceedings ◽  
2018 ◽  
Vol 2 (22) ◽  
pp. 1391
Author(s):  
Zamira Sattinova ◽  
Gaukhar Ramazanova ◽  
Bakhytzan Assilbekov ◽  
Elmira Mussenova

Obtaining of ceramic fabrications by hot molding from dispersion materials with anomalous physical properties, such as BeO is particularly complicated. In this case, the difficulties of obtaining of quality products were caused firstly by thermal properties of beryllium oxide, in particular, its unique thermal conductivity. Results of experiments and calculations of the mathematical model of the motion and heat exchange of the slurry mass in the annular cavity are presented. The results of experiments and calculations show the process of molding of the slurry in the annular cavity.


1973 ◽  
Vol 13 (05) ◽  
pp. 267-273 ◽  
Author(s):  
J. Anand ◽  
W.H. Somerton ◽  
E. Gomaa

Abstract Measuring the thermal properties of rocks and rock-fluid systems is difficult and time consuming and the results from such measurements are of limited value unless complete descriptions of the rock and fluids are given. A need exists for a method of predicting thermal behavior from other more easily measurable properties. Presented here are correlations developed for predicting the thermal conductivity of consolidated sandstones from a knowledge of density, porosity, permeability, and formation resistivity factor. Values for all these properties are available from well logs or core properties are available from well logs or core analysis data. Also obtained were correlations for estimating the thermal conductivity of liquid-saturated sandstones from a knowledge of the conductivities of dry sandstone. The thermal conductivity of most rocks decreases with increasing temperature and a method of estimating this effect is presented. The effect of pressure on conductivities is generally small, but may be predicted from a knowledge of the bulk predicted from a knowledge of the bulk compressibility of the rock. Introduction Although thermal recovery processes have been applied in the petroleum industry for many years, there is still a lack of basic thermal data with which predict the performance of these processes. Much of the thermal conductivity work reported in the literature lacks a complete description of the physical properties of the rocks used, and in physical properties of the rocks used, and in addition, most of the thermal conductivity measurements have been made at room temperature and at atmospheric pressure. The work reported in this paper deals with the thermal conductivity of typical porous rocks at simulated subsurface conditions of temperature, pressure, and saturation. Because thermal conductivity is difficult to measure, emphasis has been placed here on methods of predicting thermal conductivity from other more easily measured properties as well as on methods of predicting the effects of temperature, pressure, and liquid saturation on thermal properties. pressure, and liquid saturation on thermal properties. RELATIONSHIP OF THERMAL CONDUCTIVITY TO OTHER PHYSICAL PROPERTIES The thermal conductivities of dry rocks have been shown to be functions of density, porosity, grain size and shape, cementation, and mineral composition. The first two properties are easy to measure and precise values may, be assigned for correlation purposes. Grain size and shape and cementation are difficult to quantify. There are, however, other related properties that can be used to characterize these properties for use in correlations. Permeability and formation resistivity factors are probably most closely related to these properties and are readily measurable as unique properties and are readily measurable as unique values. Precise mineral composition values are generally not available, and even A they were, it would be difficult to introduce them into correlations. The high thermal conductivity of quartz seems to have a predominating influence, and thus for most sandstones containing quartz in moderate amounts, the effects of other minerals can be ignored. Many efforts have been made to relate thermal conductivity to the physical properties of porous rocks. These efforts have been reviewed in rather complete detail by Scorer and Anand. Unfortunately, most of the correlations developed require a knowledge of the thermal conductivity of the rock matrix or the dry rock at some known porosity. Although some simple correlations have porosity. Although some simple correlations have been obtained, these are for specific systems and are not applicable generally. Probably the most useful work in this area is that reported by Zierfuss and Van der Vliet. Basing their analysis on 36 sandstones having a wide range in measured properties, they obtained a correlation between properties, they obtained a correlation between effective porosity and the product of thermal conductivity and formation resistivity factor. A fourth-order polynomial fit of thermal conductivity and fractional porosity was obtained by regression analysis. Their data also seemed to indicate that thermal conducting increases with permeability, this being attributed to conduction with permeability. SPEJ P. 267


Author(s):  
Xuehu Ma ◽  
Fengmin Su ◽  
Zhong Lan ◽  
Jiabin Chen

In this paper, carbon nanotubes—ammonia nanofluids (the binary nanofluids) have been prepared by two steps method. And the thermal conductivity, surface tension and kinetic viscosity of the binary nanofluid have been measured. The effects of the mass fraction of carbon nanotubes, the concentration of ammonia and temperature on the thermal physical properties of the binary nanofluid have been systematically studied. On the base, the effective thermal conductivities of the binary nanofluids have been calculated using the models in the literatures, and have been compared with the experimental values.


2017 ◽  
Vol 13 (2) ◽  
Author(s):  
Amel S. Merzah

Abstract  Locally natural occurring Iraqi rocks of Bauxite and Porcelanite (after pre calcinations at 1000oC for 1hr) were used, with the addition of different proportions of MgO and Al2O3, to prepare refractory materials. The effects of these additives on the physical and thermal properties of the prepared refractories were investigated. Many batches of Bauxite/MgO, Bauxite/Al2O3, Bauxite/MgO/Al2O3, and   Porcelanite/ MgO/Al2O3 were prepared. The mixture is milled and classified into different size fractions; fine (less than 45μm) 40%, middle (45-75μm) 40%, and coarse (75-106μm) 20% .                          X-ray diffraction technique was used to identify the structure of Bauxite and Porcelanite rocks. The samples were formed by semi dry pressing with the addition of few drops of water as a binder. These samples were sintered at 1100oC for 2hrs. Physical properties (linear shrinkage, density and porosity), and the thermal properties (thermal conductivity, diffusivity and specific heat) were measured for all the prepared samples.          The results show the increasing of density is susceptible to the thermal properties, and also the addition of Al2O3 and MgO to the natural rocks have a limited effect, and the values of the parameters above  for the natural rocks, were in the levels to be used as a refractory material for lining a metal fusion furnaces and other applications. Keywords: Bauxite, Refractory brick, Porcelanite Stone, Physical properties, Thermal properties.


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