Salinity, Temperature, Oil Composition, and Oil Recovery by Waterflooding

1997 ◽  
Vol 12 (04) ◽  
pp. 269-276 ◽  
Author(s):  
G.Q. Tang ◽  
N.R. Morrow
Keyword(s):  
Energies ◽  
2020 ◽  
Vol 13 (23) ◽  
pp. 6456
Author(s):  
Ewa Knapik ◽  
Katarzyna Chruszcz-Lipska

Worldwide experiences related to geological CO2 storage show that the process of the injection of carbon dioxide into depleted oil reservoirs (CCS-EOR, Carbon Capture and Storage—Enhanced Oil Recovery) is highly profitable. The injection of CO2 will allow an increasing recovery factor (thus increasing CCS process profitability) and revitalize mature reservoirs, which may lead to oil spills due to pressure buildups. In Poland, such a solution has not yet been implemented in the industry. This work provides additional data for analysis of the possibility of the CCS-EOR method’s implementation for three potential clusters of Polish oil reservoirs located at a short distance one from another. The aim of the work was to examine the properties of reservoir fluids for these selected oil reservoirs in order to assure a better understanding of the physicochemical phenomena that accompany the gas injection process. The chemical composition of oils was determined by gas chromatography. All tested oils represent a medium black oil type with the density ranging from 795 to 843 g/L and the viscosity at 313 K, varying from 1.95 to 5.04 mm/s. The content of heavier components C25+ is up to 17 wt. %. CO2–oil MMP (Minimum Miscibility Pressure) was calculated in a CHEMCAD simulator using the Soave–Redlich–Kwong equation of state (SRK EoS). The oil composition was defined as a mixture of n-alkanes. Relatively low MMP values (ca. 8.3 MPa for all tested oils at 313 K) indicate a high potential of the EOR method, and make this geological CO2 storage form more attractive to the industry. For reservoir brines, the content of the main ions was experimentally measured and CO2 solubility under reservoir conditions was calculated. The reservoir brines showed a significant variation in properties with total dissolved solids contents varying from 17.5 to 378 g/L. CO2 solubility in brines depends on reservoir conditions and brine chemistry. The highest calculated CO2 solubility is 1.79 mol/kg, which suggest possible CO2 storage in aquifers.


2012 ◽  
Vol 594-597 ◽  
pp. 2451-2454
Author(s):  
Feng Lan Zhao ◽  
Ji Rui Hou ◽  
Shi Jun Huang

CO2is inclined to dissolve in crude oil in the reservoir condition and accordingly bring the changes in the crude oil composition, which will induce asphaltene deposition and following formation damage. In this paper, core flooding device is applied to study the effect of asphaltene deposition on flooding efficiency. From the flooding results, dissolution of CO2into oil leads to recovery increase because of crude oil viscosity reduction. But precipitated asphaltene particles may plug the pores and throats, which will make the flooding effects worse. Under the same experimental condition and with equivalent crude oil viscosity, the recovery of oil with higher proportion of precipitated asphaltene was relatively lower during the CO2flooding, so the asphltene precipitation would affect CO2displacement efficiSubscript textency and total oil recovery to some extent. Combination of static diffusion and dynamic oil flooding would provide basic parameters for further study of the CO2flooding mechanism and theoretical evidence for design of CO2flooding programs and forecasting of asphaltene deposition.


Author(s):  
Erhui Luo ◽  
Zifei Fan ◽  
Yongle Hu ◽  
Lun Zhao ◽  
Jianjun Wang

Produced gas containing the acid gas reinjection is one of the effective enhanced oil recovery methods, not only saving costs of disposing acid gases and zero discharge of greenhouse gases but also supporting reservoir pressure. The subsurface fluid from the Carboniferous carbonate reservoir in the southern margin of the Pre-Caspian basin in Central Asia has low density, low viscosity, high concentrations of H2S (15%) and CO2 (4%), high solution gas/oil ratio. The reservoir is lack of fresh water because of being far away onshore. Pilot test has already been implemented for the acid gas reinjection. Firstly, in our work a scheme of crude oil composition grouping with 15 compositions was presented on the basis of bottomhole sampling from DSTs of four wells. After matching PVT physical experiments including viscosity, density and gas/oil ratio and pressure–temperature (P–T) phase diagram by tuning critical properties of highly uncertain heavy components, the compositional model with phase behavior was built under meeting accuracy of phase fitting, which was used to evaluate mechanism of miscibility development in the acid gas injection process. Then using a cell-to-cell simulation method, vaporizing and/or condensing gas drive mechanisms were investigated for mixtures consisting of various proportions of CH4, CO2 and H2S in the gas injection process. Moreover, effects of gas compositions on miscible mechanisms have also been determined. With the aid of pressure-composition diagrams and pseudoternary diagrams generated from the Equation of State (EoS), pressures of First Contact Miscibility (FCM) and Multiple Contact Miscibility (MCM) for various gases mixing with the reservoir oil sample under reservoir temperature were calculated. Simulation results show that pressures of FCM are higher than those of MCM, and CO2 and H2S are able to reduce the miscible pressure. At the same time, H2S is stronger. As the CH4 content increases, both pressures of FCM and MCM are higher. But incremental values of MCM decrease. In addition, calculated envelopes of pseudoternary diagrams for mixtures of CH4, CO2 and H2S gases of varying composition with acid gas injection have features of bell shape, hourglass shape and triangle shape, which can be used to identify vaporizing and/or condensing gas drives. Finally, comparison of the real produced gas and the one deprived of its C3+ was performed to determine types of miscibility and calculate pressures of FCM and MCM. This study provides a theoretical guideline for selection of injection gas to improve miscibility and oil recovery.


2021 ◽  
pp. 1-18
Author(s):  
Takaaki Uetani ◽  
Hiromi Kaido ◽  
Hideharu Yonebayashi

Summary Low-salinity water (LSW) flooding is an attractive enhanced oil recovery (EOR) option, but its mechanism leading to EOR is poorly understood, especially in carbonate rock. In this paper, we investigate the main reason behind two tertiary LSW coreflood tests that failed to demonstrate promising EOR response in reservoir carbonate rock; additional oil recovery factors by the LSW injection were only +2% and +4% oil initially in place. We suspected either the oil composition (lack of acid content) or the recovery mode (tertiary mode) was inappropriate. Therefore, we repeated the experiments using an acid-enriched oil sample and injected LSW in the secondary mode. The result showed that the low-salinity effect was substantially enhanced; the additional oil recovery factor by the tertiary LSW injection jumped to +23%. Moreover, it was also found that the secondary LSW injection was more efficient than the tertiary LSW injection, especially in the acid-enriched oil reservoir. In summary, it was concluded that the total acid number (TAN) and the recovery mode appear to be the key successful factors for LSW in our carbonate system. To support the conclusion, we also performed contact angle measurement and spontaneous imbibition tests to investigate the influence of acid enrichment on wettability, and moreover, LSW injection on wettability alteration.


2020 ◽  
Vol 42 (5) ◽  
Author(s):  
Janice Ribeiro Lima ◽  
Arthur Claudio Rodrigues de Souza ◽  
Hilton César Rodrigues Magalhães ◽  
Cláudia Oliveira Pinto

Abstract The seed by-products of pequi pulp processing have a kernel in its core which is not used due to the difficulty of its extraction from the spinous endocarp. However, this kernel has high quality oil which can be used for human consumption. Thus, the kernel and the oil composition as well as the conditions to obtain the kernel oil by hydraulic pressing were evaluated in this study. The kernel showed high lipid content (55.76%), therefore being a good source for obtaining oil. The oil extraction by hydraulic pressing presented a higher yield at 5.5 tons to 6.0 tons of force and 9% to 10% moisture. Oil recovery was 75%. The pequi kernel oil showed low acid (0.17 mg KOH/g) and peroxide (1.22 mEq O2/kg) values. The kernel oil also presented high levels of oleic acid (42.47%). The results indicate that the kernel oil extraction is an alternative form for using seeds to increase the producer/processor income and to decrease residue volumes in the pequi processing industry.


2021 ◽  
Vol 43 (4) ◽  
pp. 467-475
Author(s):  
A. I. Shayakhmetov ◽  
V. L. Malyshev ◽  
E. F. Moiseeva ◽  
A. I. Ponomarev ◽  
Yu. V. Zeigman

The purpose of this work is to study the effect of carbon dioxide oil solubility on the aggregation of asphaltene associates and decrease of oil permeability of sandstones. Consideration is given to the interaction variants of oil and carbon dioxide in a free volume before being injected into a porous medium and immediately in the porous medium. The influence of oil composition on the aggregation of asphaltene associates is studied. The effect of the dissolved carbon dioxide on associate dispersion in oil is examined through oil filtering in sandstones. If asphaltene aggregation occurs in a porous medium it causes pore plugging leading to reduced permeability, complicates the development of carbon dioxide injection wells and, as a result, prevents from achieving the planned indicators of oil production and oil recovery. It is found that in the case when oil interacts with carbon dioxide in the free volume before being injected into a porous medium, the increase in the volume of filtered oil and the concentration of carbon dioxide dissolved in oil, and decrease in sandstone permeability reduce the relative mobility of oil with the dissolved carbon dioxide. The significant influence of sandstone permeability on the experimental results indicates that the sizes of asphaltene aggregates are comparable to the sizes of small pores. We have not observed complete attenuation of filtration after passing of oil with dissolved carbon dioxide through sandstones. Based on the analysis of changes in oil composition and properties carried out in the laboratory experiments on oil displacement by carbon dioxide rims, it has been determined that aggregation of asphaltene associates takes place under immediate contact of oil and carbon dioxide in a porous medium. The higher the asphaltene content in oil, the lower the formation permeability, whereas tight formations feature a more significant decrease in permeability.


2021 ◽  
Author(s):  
Mukhtar Elturki ◽  
Abdulmohsin Imqam

Abstract Minimum miscibility pressure (MMP) is a critical parameter when undergoing miscible gas injection operations for enhanced oil recovery (EOR). Miscibility has become a major term in designing the gas injection process. When the miscible gas contacts the reservoir oil, it causes changes in the basic oil properties, affecting reservoir oil composition and equilibrium conditions. Changes in conditions may also favor flocculation and deposition of organic solids, mainly asphaltene, which were previously in thermodynamic equilibrium. The main purpose of this study is to investigate how the most important parameters, such as oil temperature and oil viscosity, could affect the nitrogen (N2) MMP and the instability of asphaltene aggregation. Three sets of experiments were conducted: first, the determination of MMP was performed using a slim-tube packed with sand. The impact of crude oil viscosity using 32, 19, and 5.7 cp; and temperature using 32, 45, and 70 °C, were investigated. The results showed that the N2 MMP decreased when crude oil temperature increased. The temperature is inversely proportional to the N2 MMP due to the N2 remaining in a gaseous phase at the same conditions. In terms of viscosity, the MMP for N2 was found to decrease with the reduction in oil viscosity. Second, the effect of miscibility N2 injection pressure on asphaltene aggregation using 750 psi (below miscible pressure) and 1500 psi (at miscible pressure) was investigated using a specially designed filtration vessel. Various filter membrane pores sizes were placed inside the vessel to highlight the effect of asphaltene molecules on plugging the unconventional pore structure. The results demonstrated that increasing the pressure increased asphaltene weight percentage. The asphaltene weight percent was higher when using miscible injection pressure compared to immiscible injection pressure. Also, the asphaltene weight percentage increased when the pore size structure decreased. Finally, the visualization of asphaltene deposition over time was conducted, and the results showed that asphaltene particles started to precipitate after 2 hours. After 12 hours, the colloidal asphaltenes were fully precipitated.


Author(s):  
Yury Turov ◽  
Marina Guznyaeva

During the operation of multilayer oil fields, there is a likelihood of the occurrence of interstratal oil flows due to the occurrence of secondary technogenic channels of migration along vertical or lateral fill-spill chains. This is due to numerous perforations of fluid-tight and fluid-insulating layers, intensive oil withdrawal, the use of intensive oil recovery technologies (hydraulic fracturing, reservoir pressure maintenance systems and the other physicochemical effects in the reservoir). Thus, the original geological structure of the oil deposit may change during its operation. Besides, for some oil deposits in the later stages of their exploitation the oil inflows from deeper geological structures can be detected. In this paper the detection capability of oil deposit reformation and deep feeding on extracted oil composition is shown. The geochemical composition indices are calculated based on the GC/MS analysis of the isomeric composition of paraffins and some classes of aromatic hydrocarbons in oil samples recovered from different wells. The possibility of identifying the source of oil by their values is shown. When comparing the distributions of the values of geochemical indices in different samples of oil from one field, it was found that some of the wells extract oil from one horizon, while the composition of the extracted oil from other wells is of a mixed nature. The composition of oil from one well with a long service life is significantly differ from all others and cannot be explained as the result of mixing oil from two productive horizons. The composition of this oil is highly likely influenced by deep feeding or other technogenic factors.


Geofluids ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-17
Author(s):  
Guanqun Li ◽  
Yuliang Su ◽  
Yingchun Guo ◽  
Yongmao Hao ◽  
Lei Li

Shale reservoirs are characterized by low porosity and low permeability, and volume fracturing of horizontal wells is a key technology for the benefits development of shale oil resources. The results from laboratory and field tests show that the backflow rate of fracturing fluid is less than 50%, and the storage amount of fracturing fluid after large-scale hydraulic fracturing is positively correlated with the output of single well. The recovery of crude oil is greatly improved by means of shut-in and imbibition, therefore attracting increasing attention from researchers. In this review, we summarize the recent advances in the migration mechanisms and stimulation mechanisms of horizontal well high pressure forced soaking technology in the reservoirs. However, due to the diversity of shale mineral composition and the complexity of crude oil composition, the stimulation mechanism and effect of this technology are not clear in shale reservoir. Therefore, the mechanism of enhanced oil recovery by imbibition and the movable lower limit of imbibition cannot be characterized quantitatively. It is necessary to solve fragmentation research in the full-period fluid transport mechanisms in the follow-up research.


2002 ◽  
Vol 5 (03) ◽  
pp. 190-196 ◽  
Author(s):  
R.L. Kaufman ◽  
H. Dashti ◽  
C.S. Kabir ◽  
J.M. Pederson ◽  
M.S. Moon ◽  
...  

Summary This study reports reservoir geochemistry findings on the Greater Burgan field by a multidisciplinary, multiorganizational team. The major objectives were to determine if unique oil fingerprints could be identified for the major producing reservoirs and if oil fingerprinting could be used to identify wells with mixed production because of wellbore mechanical problems. Three potential reservoir geochemistry applications in the Burgan field are:evaluation of vertical and lateral hydrocarbon continuity,identification of production problems caused by leaky tubing strings or leaks behind casing, andallocation of production to individual zones in commingled wells. Results from this study show that while oils from the major reservoir units are different from each other, the differences are small. Furthermore, a number of wells were identified in which mixed oils were produced because of previous mechanical problems. Both transient pressure testing and distributed pressure measurements provided corroborative evidence of some of these findings. Other data show that Third Burgan oils are different in the Burgan and Magwa sectors, suggesting a lack of communication across the central graben fault complex. This finding supports the geologic model for the ongoing reservoir simulation studies. Success of the geochemistry project has spawned enlargement of the study in both size and scope. Introduction This paper describes the results from a joint project by Chevron- Texaco Overseas Petroleum, the Kuwait Oil Co. (KOC), and the Kuwait Inst. for Scientific Research (KISR). Approximately 50 oils were analyzed to assess the feasibility of applying reservoir geochemistry in the Burgan field. All analytical work was performed at KISR. In this study, we report on a subset of these oils that contain primarily single-zone production samples. Reservoir geochemistry involves the study of reservoir fluids (oil, gas, and water) to determine reservoir properties and to understand the filling history of the field. Many established methods for exploration geochemistry can be used for this purpose. Reservoir geochemistry differs from other reservoir characterization methods by dealing primarily with the detailed molecular properties of the fluids in the C1-C35+ region rather than the physical properties. Larter and Aplin1 offer a review of many of these methods. Geochemistry techniques have been used to help solve reservoir problems for many years. During this time, oil geochemistry has been applied to the following reservoir characterization and management problems:Evaluation of hydrocarbon continuity.Analysis of commingled oils for production allocation.Identification of wellbore mechanical problems.Evaluation of workovers.Production monitoring for enhanced oil recovery (EOR).Identification of reservoir fluid type from rock extracts.Characterization of reservoir bitumens and tar mats. Many different analytical techniques have been used in these reservoir geochemistry studies. One of the most widely used is gas chromatography (GC). When used for oil correlation, it is often referred to as oil fingerprinting. In most reservoirs, the oil composition represents a unique fingerprint of the oil that can be used for correlation purposes.2 This is an inexpensive method and can be very cost-effective when compared to many production-logging methods. Of course, we recommend verifying this technique with other methods before reducing these more costly measurements. A number of papers have documented the application of oil fingerprinting to Middle East oil fields.3–7 Based on these studies, we felt that there was a high probability of success in using reservoir geochemistry in Kuwait's Burgan field. Three applications were of specific importance. Reservoir Continuity. The Burgan field contains several major producing horizons: the Wara, Third Burgan (Upper, Middle, and Lower), and Fourth Burgan reservoirs. Each of these is further subdivided into several reservoir layers. Vertical compartmentalization of the field, both in geologic and production time frames, is possible. In addition, a number of faults have been mapped in the field, and these may act as lateral barriers to fluid flow. The most significant faulting occurs in the central graben fault complex that separates the Burgan and Magwa/Ahmadi sectors of the field. Oil fingerprinting, along with other oilfield data, will be used to evaluate vertical and lateral compartmentalization in the field. Tubing-String Leaks. In many older fields, the integrity of casing strings and cement bonding is often a problem. If multiple pay zones are present, oil may leak into or behind the casing string from zones other than the completion interval. Many wells in the Burgan field produce from two reservoirs. Some wells, for example, produce Wara oil up the annulus and Third Burgan oil up the tubing string. When fingerprints of the individual oil zones have been identified, wellhead samples of the two production streams can be analyzed to determine if a mechanical problem is present.2,8 Production Allocation. It has been shown that the relative proportions of individual oils in an oil mixture can be determined with GC.9,10 Using this method to analyze production streams provides a rapid means of production allocation and does not require that wells be taken off production. In the Burgan field, this method will be applied to evaluate the extent of oil mixing either in the wellbore, owing to mechanical problems, or in the reservoir because of crossflow from deeper, higher-pressure reservoirs. The Burgan Oil Field The Greater Burgan oil field lies within the Arabian basin in the state of Kuwait. General reviews of the geology and producing history of the field are described by Brennan11 and by Kirby et al.12 The field is subdivided into the Burgan, Magwa, and Ahmadi sectors, based on the presence of three structural domes. Fig. 1 shows that the northern Magwa and Ahmadi sectors are separated from the southern Burgan sector by a central graben fault complex.


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