Simultaneous Determination of Basic Geometrical Characteristics of Porous Media

1969 ◽  
Vol 9 (04) ◽  
pp. 413-416 ◽  
Author(s):  
Candelario Perez-Rosales

Abstract A statistical method for determining simultaneously some of the basic geometrical characteristics of porous media such as porosity, specific surface, porous media such as porosity, specific surface, mean pore with, mean grain thickness and absolute permeability is presented. The proposed method is permeability is presented. The proposed method is characterized by its simplicity and the minimum amount of laboratory equipment that it requires. The experimental procedure used to evaluate the various geometrical characteristics is based upon the surface analysis of a sample. in view of this fact the applicability of the method is limited to homogeneous and isotropic materials. Introduction The behavior of a fluid flowing through a porous medium depends, among other things, upon the internal geometry of the medium; hence the importance of developing efficient methods to determine the geometrical properties of porous materials. This paper describes a statistical method to determine simultaneously some of the basic geometrical properties of porous materials such as porosity, specific surface, mean pore width, mean grain thickness and absolute permeability. The mathematical formulation has been developed that the data required to calculate the various geometrical characteristics of a sample can be easily measured by analyzing a section of the sample with an evenly spaced grid. THEORY A simple way of obtaining information about the internal geometry of a porous material is to throw a point at random over a cross-section of a sample. point at random over a cross-section of a sample. Through this procedure the porosity can be determined. By considering that the material is homogeneous and isotropic, and that the point is dropped many times, the porosity is given by ...........(1) where N is the total number of times the point is thrown and n is the number of times the point falls within pore areas. Another simple manner of analyzing the structural characteristics of a porous material is to superimpose an arbitrarily long line on a cross-section so that its length is evenly distributed over the surface area. Through this procedure the porosity can also be determined. If L is the total length of the line, and l is the sum of the lengths of the line segments within void spaces, the porosity is given by .............(2) The advantage of this type of analysis is that geometrical characteristics other than porosity can be obtained. Thus, if c represents the number of intersections between the line and the perimeter of pores, it can be shown that the specific surface, pores, it can be shown that the specific surface, defined as the surface area of pores per unit bulk volume, is given by ............(3) To give a proper description of the internal geometry of a porous medium, it is necessary to define quantities that characterize the notions of pore size and grain size. Unfortunately, because of pore size and grain size. Unfortunately, because of the complexity of porous materials, it is difficult to give exact geometrical definitions of what is meant by the concepts of "pores" and "grains", especially when dealing with consolidated materials. Nevertheless, one often talks about the "size of pores" and the "size of grains" without defining accurately the terms. In possible solution to this problem follows. Assume that an arbitrarily long line is placed on a section of a sample so that the line is evenly distributed over the surface area (see Fig. 1). In a system like this, each line segment within a void space will be, by definition, the pore width in a given location and direction. SPEJ P. 413

2021 ◽  
Author(s):  
Imane Guetni ◽  
Claire Marlière ◽  
David Rousseau

Abstract Application of chemical enhanced oil recovery (C-EOR) processes to low-permeability sandstone reservoirs (in the 10-100 mD range) can be very challenging as strong retention and difficult in-depth propagation of polymer and surfactant can occur. Transport properties of C-EOR chemicals are particularly related to porous media mineralogy (clay content). The present experimental study aimed at identifying base mechanisms and providing general recommendations to design economically viable C-EOR injection strategies in low permeability clayey reservoirs. Polymer and surfactant injection corefloods were conducted using granular packs (quartz and clay mixtures) with similar petrophysical characteristics (permeability 70-130 mD) but having various mineralogical compositions (pure quartz sand, sand with 8 wt-% kaolinite and sand with 8 wt-% smectite). The granular packs were carefully characterized in terms of structure (SEM) and specific surface area (BET). The main observables from the coreflood tests were the resistance and residual resistance factors generated during the chemical injections, the irreversible polymer retention and the surfactant retention in various injection scenarios (polymer alone, surfactant alone, polymer and surfactant). A first, the impact of the clay contents on the retention of polymer and surfactant considered independently was examined. Coreflood results have shown that retention per unit mass of rock strongly increased in presence of both kaolinite and smectite, but not in the same way for both chemicals. For polymer, retention was about twice higher with kaolinite than with smectite, despite the fact that the measured specific surface area of the kaolinite was about 5 times less than that of the smectite. Conversely, for surfactant, retention was much higher with smectite than with kaolinite. Secondly, the impact of the presence of surfactant on the polymer in-depth propagation and retention was investigated in pure quartz and kaolinite-bearing porous media. In both mineralogies, the resistance factor quickly stabilized when polymer was injected alone whereas injection of larger solution volumes was required to reach stabilization when surfactant was present. In pure quartz, polymer retention was shown, surprisingly, to be one order of magnitude higher in presence of surfactant whereas with kaolinite, surfactant did not impact polymer retention. The results can be interpreted by considering adsorption-governed retention. The mechanistic pictures being that (a) large polymer macromolecules are not able to penetrate the porosity of smectite aggregates, whereas surfactant molecules can, and (b) that surfactant and polymer mixed adsorbed layers can be formed on surfaces with limited affinity for polymer. Overall, this study shows that C-EOR can be applied in low permeability reservoirs but that successful injection strategies will strongly depend on mineralogy.


2021 ◽  
Vol 186 ◽  
pp. 104261
Author(s):  
B. Sibiryakov ◽  
L.W.B. Leite ◽  
E. Sibiriakov

2014 ◽  
Vol 70 (a1) ◽  
pp. C1620-C1620
Author(s):  
Maciej Haranczyk ◽  
Richard Martin

We present a computational framework for the rapid identification and characterization of high surface area materials from within the vast chemical space of crystalline porous materials such as metal-organic frameworks (MOFs) or covalent organic frameworks (COFs). MOFs and COFs have been the subject of intense research interest due largely to their highly tunable structural properties and record-breaking internal surface areas; gravimetric surface area is one of the most addressed properties of porous materials, and has seen improvement by approximately a factor of twenty since the first reports. However, the design of MOFs with optimum chemical and geometrical properties remains a great challenge, due to the vast combinatorial space of building blocks and topologies in which they can be arranged. Efforts to identify high-performance materials have involved trial-and-error, observation-based design, computational enumeration and screening of large combinatorial libraries as well as optimization-based approaches. In our presentation, we will give an overview of techniques under development in our group, in particular, algorithms for 3D structure model assembly and material characterization. We will also present how these tools can be employed in both enumeration and optimization-based discovery of novel materials.


1996 ◽  
Vol 7 (2) ◽  
pp. 91-99 ◽  
Author(s):  
Sirikalaya Suvachittanont ◽  
Chikao Kanaoka ◽  
Akihiro Tsuchinari ◽  
Wiwut Tanthapanichakoon

Materials ◽  
2021 ◽  
Vol 14 (21) ◽  
pp. 6367
Author(s):  
Shu Xiong ◽  
Yan Zhao ◽  
Jiupeng Song

The surface roughness (Ra) and composite interfacial property of carbon fiber (CF) are considered to be mainly affected by the microstructure of the CF surface. However, quantitative characterization of the CF surface microstructure is always a difficulty. How the CF surface microstructure affects the interfacial property of CF composites is not entirely clear. A quantitative characterization technique based on images was established to calculate the cross-section perimeter and area of five types of CFs, as well as the number (N), width (W) and depth (D) of grooves on these CF surfaces. The CF composite interfacial shear strength (IFSS) was tested by the micro-droplet debonding test and modified by the realistic perimeter. The relationship between the groove structure parameter and the Ra, specific surface area and composite interfacial property was discussed in this article. The results indicated that the CF cross-section perimeter calculated by this technique showed strong consistency with the CF specific surface area and composite interfacial property. At last, the composite interface bonding mechanism based on defect capture was put forward. This mechanism can be a guiding principle for CF surface modification and help researchers better understand and establish interface bonding theories.


1971 ◽  
Vol 11 (04) ◽  
pp. 363-366
Author(s):  
Candelario Perez-Rosales ◽  
Juan J. Martinez

Abstract A statistical method, based upon the surface analysis of samples, is presented for determining simultaneously the following structural characteristics of granular porous media: porosity, mean pore width, mean grain thickness, specific surface, true sphericity of grains, number of grains per unit volume, and surface area of individual grains. per unit volume, and surface area of individual grains. Since a two-dimensional analysis is used as a means for obtaining information about three-dimensional systems, the applicability of the proposed method is restricted to homogeneous and isotropic media. Introduction The study of the geometrical properties of granular porous media is of importance in a variety of scientific and technological disciplines, such as fluid mechanics, soil mechanics, sedimentology, stratigraphy and petrophysics. The literature available in this field reveals that relatively little is known about the actual internal structure of granular media with a random distribution of irregular grains. When a quantitative description of the structural characteristics of these systems is required, it has become a practice to postulate idealized geometric models as representative of the real media. Thus, models consisting of packings of spheres and spheroids have been used for studying fluid flow and capillary behavior in granular media, such as soils and natural sands. Similar systems have been employed as models for filter cakes and beds of catalyst pellets. Likewise, cylindrical and parallel-plate pore models have been postulated for studying pore structure of real media. These simplified models, however, usually have the disadvantage of giving only approximate results; and sometimes large discrepancies between theory and observation are obtained. In view of the difficulty of giving a proper geometrical characterization of granular porous media by standard procedures, it is concluded that new methods of procedures, it is concluded that new methods of analysis leading to a better understanding of the anatomy of porous materials are needed. Accordingly, a method which allows a detailed structural description of granular porous media is presented in this paper. The guiding idea in the presented in this paper. The guiding idea in the development of the method has been the belief that a proper analysis of the surface of a homogeneous and isotropic porous material must provide all the basic information to characterize adequately the internal structure of the medium. The results obtained to date have shown that, if a cross-section of a granular porous sample is analyzed by means of a square grid, it is possible to determine in a simple and accurate way the following structural characteristics: porosity, mean pore width, mean grain thickness, specific surface, true sphericity of grains, number of grains per unit volume, and surface area of individual grains. To improve the consistency between the mathematical symbols and their meaning, the nomenclature employed in this paper is somewhat different from that used in the related previous papers. papers. IMPORTANT RELATIONSHIPS In addition to porosity, one of the most important geometrical characteristics of a porous sample is the specific surface. In the strict sense, there are two basic types of specific surface for a granular porous material: pore specific surface, Ssp, and porous material: pore specific surface, Ssp, and grain specific surface, Ssg. The former is defined as the surface area of the pore walls, Sp, per unit bulk volume, Vt, namely, and the latter is defined as the surface area of grains Sg also per unit bulk volume; that is If the contacts between grains were mathematical points, the two types of specific surface would have points, the two types of specific surface would have the same value. However, for a real granular medium, the contacts always have associated a given surface area, and hence these parameters are necessarily different. SPEJ P. 363


Author(s):  
Iman Mohammed ◽  
Ricardo Bernhardt ◽  
Markus Schubert ◽  
Uwe Hampel

Abstract Loofa sponge is a naturally-grown and decomposable material providing high specific surface area and high porosity for potential application as an environmentally-friendly catalyst carrier. In this work, cellular samples of various loofa types cut from different fiber network regions of the fruits were studied in detail using non-invasive imaging techniques. Digital microscopy was applied to characterize the cellular fiber network, which revealed a honeycomb structure in the core region and a sandwich structure in the wall region. Furthermore, reconstructed three-dimensional (3D) morphological images of the loofa samples obtained via micro-tomography (micro-CT) were utilized to extract the geometrical properties cell size, window diameter and strut thickness as well as porosity and volume-specific surface area. The reconstructed loofa samples revealed porosities of about 92% and specific surface areas up to 2057 m2/m3. In addition, the geometrical properties of manufactured solid foams (ceramic and polyurethane) were also determined via micro-CT and compared with loofa sponge. Finally, the different characteristic cell dimensions were employed to predict the porosity and specific surface area with available geometrical correlations. Deviations between correlation and measurement data (±16%) can be attributed to the peculiarity of the loofa cellular fiber network, which is somewhat different from the tetradecahedral-shaped geometry commonly used as the basis for most of the available correlations.


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