Using XRF Elemental Data and XRD Direct Measured Mineralogy for an Accurate Wellbore Placement and Geosteering through Carbonates Reservoirs* Drilled Within 04 ½" Slim Hole: A Case Study from a Jurassic Middle Marrat Carbonates Reservoir-Kuwait

2021 ◽  
Author(s):  
Rasha Al-Muraikhi ◽  
Nami Mohammad Al-Mutairi ◽  
Karim Ousdidene ◽  
Caroline Magnier ◽  
Sachin Sharma ◽  
...  

ABSTRACT As the pursuit of oil and gas in Middle East Jurassic carbonates reservoirs grows, it is increasingly evident that horizontal wellbore placement, or targeting, plays a first-order role in the production capability of a well. Indeed, the percentage of a wellbore "in target" is a common metric used when evaluating the causes for good or poor production from any particular well. The most common process used for geosteering a horizontal wellbore into a chosen target is the correlation of logging-while-drilling (LWD) total gamma-ray (GR) to a vertical pilot-hole GR log or offset wells GR logs. However, limitations inherent to this procedure can reduce the ability to effectively use LWD GR data due to 4 ½" slim hole diameter and mud telemetry issues, the non-descript signal from LWD tools due to high pressure and high temperature and the possibility of lost signal from LWD tools. In addition, the thickness of MRW-F11 targeted reservoir is limited to plus or minus 22 ft and low GR contrast from bed to bed might lead to loss of directional control in the target MRW-F11. To accurately geosteer a well, Geochemical analyses of drilled cuttings are proposed to assist well placement. The analyses performed were elemental data derived from energy-dispersive X-ray fluorescence (ED-XRF) and mineralogical quantitative content acquired from the direct measurement from energy-dispersive X-ray Diffraction (ED-XRD). The Elemental and mineralogy data were acquired from drilling cuttings taken at ten feet intervals, from two offsets wells. The mineral and elemental data were used to build a chemo-stratigraphic profile and zonation of the sedimentary section. Chemo-stratigraphic zones are defined as having multiple elements and keys ratios (where possible) which illustrate distinct changes in chemical and mineralogical composition profiles from one zone to another. These zones were correlated over reasonable distances (at a minimum the length of the horizontal wellbore) and can be readily identifiable in cuttings. Using these criteria chemo-stratigraphic zonation's have been constructed in the Middle Marrat formation going from MRW-F1 toward MRW-F11 layer. Well site ED-XRF and ED-XRD data were used in conjunction with LWD Gamma Ray to geosteer at approximately 22 feet thin zone which resides at the base of an approximately 100 ft thick reservoir carbonate section of the main MRW-F11 reservoir. The LWD GR Signal was 45 ft behind the bit while all XRF and XRD data were at plus or minus 5 feet while sliding at plus or minus 10 ft in rotary mode and with a controlled slow rate of penetration (ROP) of 10 ft/hr. Geochemical rock analyses (GEAR) using XRF & XRD chemical analyses was the unique reference for approximately 500 ft interval to geosteer the well when LWD lost the signal, wiper trip was cancelled which considerably reduced drilling costs. Well site XRF and XRD data was successfully applied to geosteer the well, determine the position of the wellbore in zones of non-descript LWD GR signature, and determine the lateral extent of the reservoir interval.

2017 ◽  
Vol 50 (2) ◽  
pp. 616
Author(s):  
C. Athanassoulis ◽  
S. Zaimis ◽  
A. Chatziapostolou ◽  
S. Agalaniotou

The current study presents the preliminary results of the mineralogical and geochemical characterization of the Sagiada mud (Prefecture of Thesprotia), which is considered as one of the most representative therapeutic mud occurrences in Greece. This work is part of a bigger project, conducted by IGME (Athens, Greece), for the characterization of the Greek therapeutic mud deposits. The mineralogical composition was determined using X-Ray Diffraction (XRD), Differential Thermal Analysis (DTA), optical microscopy and Scanning Electron Microscopy (SEM). The main mineral phases of the Sagiada mud are quartz, feldspars, clay minerals such as illite, kaolinite, chlorite and vermiculite, and calcite accompanied by minor phases such as halite and pyrite. Traces of muscovite and gypsum were also identified. Geochemical analyses were performed using X-Ray Fluorescence (XRF) and Inductively Coupled Plasma-Mass Spectrometry (ICP-MS) for the determination of major and trace element content, respectively. Compared to Spanish peloids and European floodplain sediments, the Sagiada mud reveals an analogue chemical composition.


1978 ◽  
Vol 22 ◽  
pp. 337-342
Author(s):  
Colin G. Sanderson

Least squares computer programs have been used for the resolution of complex gamma-ray spectra obtained from NaI(Tl) detectors for many years. With the addition of computer codes, which account for the differences “between gamma-ray and x-ray fluorescence spectra, these same programs can be used to quantify energy dispersive x-ray fluorescence data.


2022 ◽  
Author(s):  
Matthias Sinnesael ◽  
Alfredo Loi ◽  
Marie-Pierre Dabard ◽  
Thijs R. A. Vandenbroucke ◽  
Philippe Claeys

Abstract. To expand traditional cyclostratigraphic numerical methods beyond their common technical limitations and apply them to truly deep-time archives we need to reflect on the development of new approaches to sedimentary archives that traditionally are not targeted for cyclostratigraphic analysis, but that frequently occur in the impoverished deep-time record. Siliciclastic storm-dominated shelf environments are a good example of such records. Our case study focusses on the Middle to Upper Ordovician siliciclastic successions of the Armorican Massif (western France), which are well-studied in terms of sedimentology and sequence stratigraphy. In addition, these sections are protected geological heritage due to the extraordinary quality of the outcrops. We therefore tested the performance of non-destructive high-resolution (cm-scale) portable X-ray fluorescence and natural gamma-ray analyses on outcrop to obtain major and trace element compositions. Despite the challenging outcrop conditions in the tidal beach zone, our geochemical analyses provide useful information regarding general lithology and several specific sedimentary features such as the detection of paleoplacers, or the discrimination between different types of diagenetic concretions such as nodules. Secondly, these new high-resolution data are used to experiment the application of commonly used numerical cyclostratigraphic techniques on this siliciclastic storm-dominated shelf environment, a non-traditional sedimentological setting for cyclostratigraphic analysis. In the lithological relatively homogenous parts of the section spectral power analyses and bandpass filtering hint towards a potential astronomical imprint of some sedimentary cycles, but this needs further confirmation in the absence of more robust independent age constraints.


Author(s):  
Nicole Gäumann

SNF-Project (1.722-0.83): Naturwissenschaftliche und typologische Untersuchungen an Rollsiegeln. When?         1983-1986 Who?           Dr. Julia Asher-Greve and Prof. Dr. Willem Stern, University of Basel Material?     1017 cylinder seals from Mesopotamia and neighbouring regions covering all periods from Uruk to Achaemenid period. What? XRD (X-ray diffraction) -> mineralogical composition EDXRF (energy dispersive X-ray fluorescence) -> chemical composition Iconographical typology Project couldn’t be brought to an end, data not interpreted   PhD-Project based on the corpus and analyses of the project Asher-Greve When?         2017-2020 (?) Who?           Nicole Gäumann Material?     Same What? Interpretation of XRD- and EDXRF from previous project Further analyses on existing powder samples (?) Typology Bringing together the results of the material analyses and the archaeological data, the material ought to be interpreted in terms of connections between material, colour, dating, provenance, theme, owner…  


2017 ◽  
Vol 32 (2) ◽  
pp. 133-139
Author(s):  
Einar Nygård ◽  
Nail Malakhov ◽  
Peter Weilhammer ◽  
Ole Dorholt ◽  
Ole M. Røhne ◽  
...  

A new methodology for very high-speed, energy-dispersive detection of X-ray fluorescence is being developed. The underlying reasoning behind it, as well as early results from the evaluation of the first prototype, is presented.


Author(s):  
J.M. Titchmarsh

The advances in recent years in the microanalytical capabilities of conventional TEM's fitted with probe forming lenses allow much more detailed investigations to be made of the microstructures of complex alloys, such as ferritic steels, than have been possible previously. In particular, the identification of individual precipitate particles with dimensions of a few tens of nanometers in alloys containing high densities of several chemically and crystallographically different precipitate types is feasible. The aim of the investigation described in this paper was to establish a method which allowed individual particle identification to be made in a few seconds so that large numbers of particles could be examined in a few hours.A Philips EM400 microscope, fitted with the scanning transmission (STEM) objective lens pole-pieces and an EDAX energy dispersive X-ray analyser, was used at 120 kV with a thermal W hairpin filament. The precipitates examined were extracted using a standard C replica technique from specimens of a 2¼Cr-lMo ferritic steel in a quenched and tempered condition.


Author(s):  
J. Bentley ◽  
E. A. Kenik

Instruments combining a 100 kV transmission electron microscope (TEM) with scanning transmission (STEM), secondary electron (SEM) and x-ray energy dispersive spectrometer (EDS) attachments to give analytical capabilities are becoming increasingly available and useful. Some typical applications in the field of materials science which make use of the small probe size and thin specimen geometry are the chemical analysis of small precipitates contained within a thin foil and the measurement of chemical concentration profiles near microstructural features such as grain boundaries, point defect clusters, dislocations, or precipitates. Quantitative x-ray analysis of bulk samples using EDS on a conventional SEM is reasonably well established, but much less work has been performed on thin metal foils using the higher accelerating voltages available in TEM based instruments.


Author(s):  
Allen Angel ◽  
Kathryn A. Jakes

Fabrics recovered from archaeological sites often are so badly degraded that fiber identification based on physical morphology is difficult. Although diagenetic changes may be viewed as destructive to factors necessary for the discernment of fiber information, changes occurring during any stage of a fiber's lifetime leave a record within the fiber's chemical and physical structure. These alterations may offer valuable clues to understanding the conditions of the fiber's growth, fiber preparation and fabric processing technology and conditions of burial or long term storage (1).Energy dispersive spectrometry has been reported to be suitable for determination of mordant treatment on historic fibers (2,3) and has been used to characterize metal wrapping of combination yarns (4,5). In this study, a technique is developed which provides fractured cross sections of fibers for x-ray analysis and elemental mapping. In addition, backscattered electron imaging (BSI) and energy dispersive x-ray microanalysis (EDS) are utilized to correlate elements to their distribution in fibers.


Author(s):  
Marc H. Peeters ◽  
Max T. Otten

Over the past decades, the combination of energy-dispersive analysis of X-rays and scanning electron microscopy has proved to be a powerful tool for fast and reliable elemental characterization of a large variety of specimens. The technique has evolved rapidly from a purely qualitative characterization method to a reliable quantitative way of analysis. In the last 5 years, an increasing need for automation is observed, whereby energy-dispersive analysers control the beam and stage movement of the scanning electron microscope in order to collect digital X-ray images and perform unattended point analysis over multiple locations.The Philips High-speed Analysis of X-rays system (PHAX-Scan) makes use of the high performance dual-processor structure of the EDAX PV9900 analyser and the databus structure of the Philips series 500 scanning electron microscope to provide a highly automated, user-friendly and extremely fast microanalysis system. The software that runs on the hardware described above was specifically designed to provide the ultimate attainable speed on the system.


Author(s):  
Michael E. Rock ◽  
Vern Kennedy ◽  
Bhaskar Deodhar ◽  
Thomas G. Stoebe

Cellophane is a composite polymer material, made up of regenerated cellulose (usually derived from wood pulp) which has been chemically transformed into "viscose", then formed into a (1 mil thickness) transparent sheet through an extrusion process. Although primarily produced for the food industry, cellophane's use as a separator material in the silver-zinc secondary battery system has proved to be another important market. We examined 14 samples from five producers of cellophane, which are being evaluated as the separator material for a silver/zinc alkaline battery system in an autonomous underwater target vehicle. Our intent was to identify structural and/or chemical differences between samples which could be related to the functional differences seen in the lifetimes of these various battery separators. The unused cellophane samples were examined by transmission electron microscopy (TEM) and energy dispersive X-ray spectroscopy (EDS). Cellophane samples were cross sectioned (125-150 nm) using a diamond knife on a RMC MT-6000 ultramicrotome. Sections were examined in a Philips 430-T TEM at 200 kV. Analysis included morphological characterization, and EDS (for chemical composition). EDS was performed using an EDAX windowless detector.


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