Calcite Scale Mitigation in a Very Low Watercut, Low Salinity, HPHT Environment: Lessons Learned in Surveillance, Mitigation and Scale Inhibitor Performance Monitoring for an Onshore Field

2021 ◽  
Author(s):  
Jonathan J. Wylde ◽  
Alexander R. Thornton ◽  
Mark Gough ◽  
Rifky Akbar ◽  
William A. Bruckmann

Abstract A prolific Southeast Asia onshore oilfield has enjoyed scale free production for many years before recently experiencing a series of unexpected and harsh calcite scaling events. Well watercuts were barely measurable, yet mineral scale deposits accumulated quickly across topside wellhead chokes and within downstream flowlines. This paper describes the scale management experience, and the specific challenges presented by this extraordinarily low well water cut, low pH, calcium carbonate scaling environment. To the knowledge of the authors, no previous literature works have been published regarding such an unusual and aggressive mineral scale control scenario. A detailed analysis of the scaling experience is provided, including plant layout, scaling locations, scale surveillance and monitoring programs, laboratory testing, product selection and implementation, and scale inhibitor efficacy surveillance and monitoring programs. The surveillance and application techniques themselves are notable, and feature important lessons learned for addressing similar very low water cut and moderate pH calcium carbonate scaling scenarios. For example, under ultra-low watercut high temperature well production conditions, it was found that a heavily diluted scale inhibitor was necessary to achieve optimum scale control, and a detailed laboratory and field implementation process is described that led to this key learning lesson. The sudden and immediate nature of the occurrence demanded a fast-track laboratory testing approach to rapidly identify a suitable scale inhibitor for the high temperature topside calcium carbonate scaling scenario. The streamlined selection program is detailed, however what could not be readily tested for via conventional laboratory testing was the effect of <1% water cut, and how the product would perform in that environment. A risk-managed field surveillance program was initiated to determine field efficiency of the identified polymeric scale inhibitor and involved field-trialing on a single well using a temporary restriction orifice plate (ROP) to modify the residence time of the injected chemical. The technique proved very successful and identifed that product dispersibility was important, and that dilution of the active scale inhibitor had a positive effect on dispersibility for optimum inhibitor action. The lessons learned were rolled out to all at-risk field producers with positive results. The ongoing success of this program continues and will be detailed in the manuscript and presentation. This paper demonstrates a unique situation of calcium carbonate scale formation and control that utilized a previously unreported and analytical surveillance approach. The cumulative performance derived by improving not only chemical selection, but the way the wells were managed via surveillance and chemical management decision making processes is compelling and of value to other production chemists working in the scaling arena.

RSC Advances ◽  
2016 ◽  
Vol 6 (46) ◽  
pp. 39883-39895 ◽  
Author(s):  
Ping Zhang ◽  
Dong Shen ◽  
Amy T. Kan ◽  
Mason B. Tomson

Developed calcium-phosphonate scale inhibitor reverse micelle nanomaterial for oilfield mineral scale control in low water cut or water sensitive wells.


2019 ◽  
Author(s):  
Haiping Lu ◽  
Bethanni Mccabe ◽  
Johnathon Brooks ◽  
Stephen Heath ◽  
Shane Stevens

2014 ◽  
Author(s):  
J. K. Daniels ◽  
I.. Littlehales ◽  
L.. Lau ◽  
S.. Linares-Samaniego

Abstract HPHT (high pressure, high temperature) conditions create challenges and push the limits of existing technology (i.e., scale prediction modeling, testing methodology and instrumentation) and commercial scale inhibitor chemistry. Scale prediction modeling often fails at HPHT conditions and laboratory testing under appropriate field conditions have to be compromised due to instrument limitations. This paper details work done under high temperature (204°C) and elevated pressure (3,000 psi) conditions in in order to obtain effective scale control. More specifically, this paper will discuss selection methods for continuous and squeeze scale inhibitor application via dynamic performance testing and coreflood studies for scale control in this deep-water oil production field. The technical challenges encountered such as matching the scale type predicted in the prediction software to the scale observed during dynamic tube blocking will be outlined. Thermal ageing procedures/performance testing for continual injection chemicals and performance testing of coreflood effluent from HT coreflood studies will be outlined.


CORROSION ◽  
1961 ◽  
Vol 17 (5) ◽  
pp. 232t-236t ◽  
Author(s):  
L. W. JONES

Abstract The expense attributable to scaling in oil producing operations totals many millions of dollars annually. Causes of precipitation and deposition are fairly well understood but better methods of control are needed. In order to evaluate chemical scale inhibitor components, a laboratory testing device was designed. Performance of sequestrants, surface active agents, colloids, and mixed compounds in the laboratory tester are discussed. Polyphosphates and sodium carboxymethyl cellulose proved effective for calcium carbonate scale and calcium sulfate scale, respectively. Results of tests made over a period of several years led to the development of an inhibitor composition that is capable of inhibiting both carbonate and sulfate scales. The inhibitor is now in field use. 5.8.2, 3.2.3, 8.4.3


RSC Advances ◽  
2016 ◽  
Vol 6 (49) ◽  
pp. 43016-43027 ◽  
Author(s):  
Ping Zhang ◽  
Gedeng Ruan ◽  
Amy T. Kan ◽  
Mason B. Tomson

This study synthesized phosphonate–polymer nanoparticle capsules using SiO2 nanoparticles as the building blocks and polymer aggregates as the template for the purpose of oilfield mineral scale control.


RSC Advances ◽  
2016 ◽  
Vol 6 (64) ◽  
pp. 59195-59205 ◽  
Author(s):  
Ping Zhang ◽  
Dong Shen ◽  
Amy T. Kan ◽  
Mason B. Tomson

Evaluation of the transport and return behavior of phosphino-polycarboxylic acid modified scale inhibitor nanomaterial for oilfield mineral scale control.


Desalination ◽  
2020 ◽  
Vol 491 ◽  
pp. 114548
Author(s):  
Stéphanie C. de Morais ◽  
Djalan F. de Lima ◽  
Thuany M. Ferreira ◽  
Josiel B. Domingos ◽  
Miguel Angelo F. de Souza ◽  
...  

RSC Advances ◽  
2016 ◽  
Vol 6 (7) ◽  
pp. 5259-5269 ◽  
Author(s):  
Ping Zhang ◽  
Amy T. Kan ◽  
Mason B. Tomson

Prepared crystalline Si–Ca–DTPMP scale inhibitor nanomaterials with enhanced transportability and extended squeeze lifetime potentially for oilfield mineral scale control.


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