Effect of Lateral Diffusivity on Miscible Displacement In Horizontal Reservoirs

1962 ◽  
Vol 2 (04) ◽  
pp. 317-326 ◽  
Author(s):  
C. Van Der Poel
Keyword(s):  
Oil Recovery ◽  
Glass Powder ◽  
Molecular Diffusion ◽  
Viscosity Ratio ◽  
Ammonium Thiocyanate ◽  
Miscible Displacement ◽  
Favorable Effect ◽  
Mixing Zone ◽  
Interfacial Boundary ◽  
Small Models

Abstract When oil is displaced from a horizontal formation by another fluid of lower density, the latter tends to override the former in the shape of a tongue owing to gravity segregation. This gravity tongue has an adverse influence on the oil recovery. If the fluids are miscible, diffusion (mixing) takes place at the interfacial boundary of the gravity tongue. This mixing should have a favorable effect on oil recovery. The report describes a laboratory study of the magnitude of the mixing zone under various conditions, so as to assess the effect of diffusion on oil recovery both in laboratory experiments and under actual field conditions. The technique used enables visual observation and measurement of the size of the mixing zone in transparent glass-powder packs. The results show that in experiments in small models and cores the width of the mixing zone may well be of the same order of magnitude as the height of the model. In such cases oil recovery is favorably affected by mixing. It can further be concluded that, under conditions prevailing in the field, mixing of the injected fluid with reservoir oil is equal to that caused by molecular diffusion alone, eddy-mixing not taking place to any appreciable extent. A simple calculation, then, shows that molecular diffusion is too small for a beneficial effect to be expected from the injection of miscible fluids in horizontal or nearly horizontal reservoirs unless pay zones are thin. Introduction This paper gives results of experiments made on the mixing which occurs when a miscible displacement is carried out in a horizontal reservoir. This mixing takes place at the interfacial boundary of the gravity tongue formed when the lighter injected fluid overrides the oil present in the reservoir. The object of the experiments was to simulate the field case where, for example, propane with a viscosity of 0.075 cp under reservoir conditions displaces an oil of viscosity 0.6 cp. In the experiments the lighter fluid had a viscosity of about 1 cp and the heavier one a viscosity of about 8 cp, so as to obtain the same viscosity ratio. In order to enable the results to be compared with those published in the literature, a set of experiments with viscosity ratio equal to one was also performed. EXPERIMENTAL TECHNIQUE The technique developed for the purpose enables the width of the mixing zone to be studied as a function of time and place. A glass-powder pack is saturated with a water-glycerine mixture of suitable viscosity, which represents the reservoir fluid. The pack is then rendered transparent by dissolving sufficient ammonium thiocyanate in the mixture to obtain a solution with a refractive index matching that of the glass powder. Alkaline water to which phenolphthalein has been added is used as the lighter and less-viscous displacing fluid. In those places where mixing or diffusion of the two liquids occurs, the slightly acidic ammonium-thiocyanate solution neutralizes the alkali in the water, and the glass pack shows up white against the red-colored invading water. If a black cloth is hung over the back of the apparatus, the transparent part of the glass pack appears black. In this way the position of the two phases and the transition zone between them is clearly visible, as shown in Fig. 1 (where the red-colored invading water is the grey-shaded zone lying uppermost).In all experiments the amount of alkali in the water was chosen such that the upper contour corresponded to a concentration of 5 per cent of the dense liquid. The lower contour is determined by the size of the glass grains and the thickness of the pack and, consequently, varies from experiment to experiment. SPEJ P. 317^

Design of Laboratory Models for Study of Miscible Displacement

1963 ◽  
Vol 3 (01) ◽  
pp. 28-40 ◽  
Author(s):  
Anthony L. Pozzi ◽  
Robert J. Blackwell
Keyword(s):  
Oil Recovery ◽  
Molecular Diffusion ◽  
Dispersion Coefficient ◽  
Miscible Displacement ◽  
Laboratory Model ◽  
Transverse Mixing ◽  
Model Studies ◽  
Geometric Similarity ◽  
Transverse Dispersion ◽  
Laboratory Models

Abstract Scaled laboratory-model studies provide a powerful method for evaluation of a proposed oil-recovery process. In recent years, models have been used extensively to evaluate processes in which solvents displace oil, both for general cases and for specific reservoir conditions. Since the performance of a miscible flood in a horizontal reservoir can be significantly affected by transverse mixing between solvent and oil, this displacement mechanism must be accurately simulated in the scaled model studies. Unfortunately, precise scaling of transverse dispersion coupled with the requirement of geometric similarity requires impractically large laboratory models and long times for experiments.If scaling requirements for miscible displacements could be relaxed while accurate simulation of essential displacement mechanisms is maintained, the utility of model studies would be greatly enhanced. The purpose of the work reported herein was to evaluate the relative importance of various mechanisms affecting miscible displacement and to ascertain whether the essential features of the displacement process can be simulated even though some scaling groups are not satisfied. These studies were performed with completely miscible systems in linear, horizontal models packed with unconsolidated media.From the experimental results, a set of relaxed scaling criteria was formulated which allows the requirements of geometric similarity and equality of the ratio of viscous to gravity forces to be omitted for specified conditions. The relaxed criteria are valid whether transverse mixing is by molecular diffusion or by convective dispersion.Correlations which permit prediction of vertical sweep efficiencies in linear, horizontal reservoirs were developed from the experimental data when transverse mixing is by molecular diffusion, These same correlations may be used when transverse mixing is by convective dispersion if an empirically defined, effective, transverse dispersion coefficient is used in the description of the mixing process. The effective transverse dispersion coefficient correlation essentially duplicates the dispersion coefficient correlation for equal-viscosity, equal-density fluid systems. Experimental values for the effective transverse dispersion coefficient can be measured readily. Introduction One of the most effective methods for evaluation of miscible-displacement oil-recovery processes is that of displacements in laboratory models scaled to simulate reservoir conditions. For these laboratory studies to be meaningful, however, the essential displacement mechanisms affecting reservoir performance must be accurately simulated.Since the performance of a miscible flood in horizontal reservoirs, or in dipping reservoirs at high rates, can be significantly affected by transverse mixing of solvent and oil, this mechanism must be considered in the design of laboratory experiments. Unfortunately, precise scaling of transverse dispersion coupled with the requirement of geometric similarity requires impracticality large laboratory models and long experiment times. This difficulty seriously limits the utility of laboratory model studies.Craig, et al, demonstrated that geometric similarity is not required when mixing is unimportant. Their experimental data indicate, for the cases studied, that the displacement is sufficiently characterized by scaling the ratio of viscous-to-gravitational forces. This work suggests that relaxation of the requirement of geometric similarity and, possibly, other criteria might also be permissible when mixing is important, provided suitable groups describing the mixing process are scaled.The purpose of the work reported here was to evaluate the relative importance of various mechanisms affecting miscible displacement and to ascertain whether the essential features of the displacement process can be simulated even though some scaling groups are not satisfied. SPEJ P. 28^

Sweep Efficiency by Miscible Displacement in a Five-Spot

1966 ◽  
Vol 6 (01) ◽  
pp. 73-80 ◽  
Author(s):  
J.L. Mahaffey ◽  
W.M. Rutherford ◽  
C.S. Matthews
Keyword(s):  
Oil Recovery ◽  
Parallel Plate ◽  
Molecular Diffusion ◽  
Miscible Displacement ◽  
Sweep Efficiency ◽  
Miscible Displacements ◽  
Model Studies ◽  
Convective Mixing ◽  
Plate Spacing ◽  
Diffusion Effects

Abstract This paper gives results of an experimental study of the sweep efficiency of a miscible displacement in a five-spot. The study was carried out in a parallel-plate glass model in which effects of diffusion were scaled at or near the molecular diffusion level. The experiments show that very early breakthrough (25 to 35 per cent of pore volume (PV) injected) may be expected in miscible floods because of the unfavorable viscosity ratio. However after 1 PV of displacing fluid is injected, the sweep rises to a reasonable value (50 to 60 per cent). Photographs show that small slugs of less than 10 per cent of PV tend to dissipate before breakthrough. A minimum slug size of 15 per cent of PV would appear to be necessary even in a relatively homogeneous formation. Presence of a slug whose viscosity is intermediate between that of oil and gas increases the sweep efficiency of the oil-gas system. In a typical system the sweep at breakthrough rose from 26 to 37 per cent of PV for a 25 per cent slug. The increase in sweep brought about by use of a large slug could well pay for the extra deferment cost of the additional slug material. Introduction Most miscible displacement processes involve the displacement of oil with fluids of much lower viscosity and density. The displacement process at these adverse viscosity and density ratios is dominated by instability phenomena, i.e., viscous fingers and gravity tongues. These phenomena have highly adverse effects on oil recovery. Although a number of laboratory studies have been made to determine the effect of adverse viscosity ratios on five-spot sweep patters,1,2 the scaling of diffusion effects is uncertain. In the series of scaled model studies reported herein, an attempt was made to scale diffusion. Model studies of miscible displacements in which molecular diffusion predominates are permitted by controlling the parallel plate spacing which reduces convective mixing to arbitrarily small levels. To decide how this scaling relates to any particular field displacement necessitates an estimation of diffusion effects for the natural rock being considered and conditions under which displacement will be conducted. The approach normally taken is to extrapolate data obtained from stable miscible displacements performed in the laboratory, such as those presented by Brigham et al.3 The validity with which such an extrapolation can be applied to an unstable flow system has yet to be established. If this approach is accepted, a family of oil recovery curves can be generated for a single viscosity ratio based on Brigham's observation that the magnitude of the dispersion coefficient is dependent, among other things, upon specific rock properties. Objective of our test was to define the lower limit of this range by presenting the case where dispersion effects were reduced to the molecular diffusion level in both the transverse and longitudinal directions. The scaling of diffusion effects can be handled in two-dimensional systems by the usse of narrow-gap, parallel-plate models. In parallel-plate models the Taylor diffusion coefficient for convective mixing in the direction of flow at low flow rates is given by (following Taylor4):Equation 1 where h is the plate spacing and D is the molecular diffusion coefficient. Clearly, convective mixing can be reduced to arbitrarily small levels by manipulating the gap spacing h. This was the method used in these studies.

Simulation of Miscible Displacement in Full-Diameter Carbonate Cores

1982 ◽  
Vol 22 (05) ◽  
pp. 647-657 ◽  
Author(s):  
J.P. Batycky ◽  
B.B. Maini ◽  
D.B. Fisher
Keyword(s):  
Oil Recovery ◽  
Water Saturation ◽  
Accurate Determination ◽  
Miscible Displacement ◽  
Carbonate Reservoir ◽  
Core Material ◽  
Immiscible Fluid ◽  
Displacement Efficiency ◽  
Carbonate Cores ◽  
Capacitance Model

Abstract Miscible gas displacement data obtained from full-diameter carbonate reservoir cores have been fitted to a modified miscible flow dispersion-capacitance model. Starting with earlier approaches, we have synthesized an algorithm that provides rapid and accurate determination of the three parameters included in the model: the dispersion coefficient, the flowing fraction of displaceable volume, and the rate constant for mass transfer between flowing and stagnant volumes. Quality of fit is verified with a finite-difference simulation. The dependencies of the three parameters have been evaluated as functions of the displacement velocity and of the water saturation within four carbonate cores composed of various amounts of matrix, vug, and fracture porosity. Numerical simulation of a composite core made by stacking three of the individual cores has been compared with the experimental data. For comparison, an analysis of Berea sandstone gas displacement also has been provided. Although the sandstone displays a minor dependence of gas recovery on water saturation, we found that the carbonate cores are strongly affected by water content. Such behavior would not be measurable if small carbonate samples that can reflect only matrix properties were used. This study therefore represents a significant assessment of the dispersion-capacitance model for carbonate cores and its ability to reflect changes in pore interconnectivity that accompany water saturation alteration. Introduction Miscible displacement processes are used widely in various aspects of oil recovery. A solvent slug injected into a reservoir can be used to displace miscibly either oil or gas. The necessary slug size is determined by the rate at which deterioration can occur as the slug is Another commonly used miscible process involves addition of a small slug within the injected fluids or gases to determine the nature and extent of inter well communication. The quantity of tracer material used is dictated by analytical detection capabilities and by an understanding of the miscible displacement properties of the reservoir. We can develop such understanding by performing one-dimensional (1D) step-change miscible displacement experiments within the laboratory with selected reservoir core material. The effluent profiles derived from the experiments then are fitted to a suitable mathematical model to express the behavior of each rock type through the use of a relatively small number of parameters. This paper illustrates the efficient application of the three-parameter, dispersion-capacitance model. Its application previously has been limited to use with small homogeneous plugs normally composed of intergranular and intencrystalline porosity, and its suitability for use with cores displaying macroscopic heterogeneity has been questioned. Consequently, in addition to illustrating its use with a homogeneous sandstone, we fit data derived from previously reported full-diameter carbonate cores. As noted earlier, these cores were heterogeneous, and each of them displayed different dual or multiple types of porosity characteristic of vugular and fractured carbonate rocks. Dispersion-Capacitance Model The displacement efficiency of one fluid by a second immiscible fluid within a porous medium depends on the complexity of rock and fluid properties. SPEJ P. 647^

scholarly journals A Numerical Method for Computing Recovery of Oil By Hot Water Injection in a Radial System

1965 ◽  
Vol 5 (02) ◽  
pp. 131-140 ◽  
Author(s):  
K.P. Fournier
Keyword(s):  
Thermal Expansion ◽  
Oil Recovery ◽  
Viscosity Ratio ◽  
Water Injection ◽  
Injection Rate ◽  
Heat Losses ◽  
Hot Water ◽  
Radial System ◽  
System Equation ◽  
Finite Difference Equations

Abstract This report describes work on the problem of predicting oil recovery from a reservoir into which water is injected at a temperature higher than the reservoir temperature, taking into account effects of viscosity-ratio reduction, heat loss and thermal expansion. It includes the derivation of the equations involved, the finite difference equations used to solve the partial differential equation which models the system, and the results obtained using the IBM 1620 and 7090–1401 computers. Figures and tables show present results of this study of recovery as a function of reservoir thickness and injection rate. For a possible reservoir hot water flood in which 1,000 BWPD at 250F are injected, an additional 5 per cent recovery of oil in place in a swept 1,000-ft-radius reservoir is predicted after injection of one pore volume of water. INTRODUCTION The problem of predicting oil recovery from the injection of hot water has been discussed by several researchers.1–6,19 In no case has the problem of predicting heat losses been rigorously incorporated into the recovery and displacement calculation problem. Willman et al. describe an approximate method of such treatment.1 The calculation of heat losses in a reservoir and the corresponding temperature distribution while injecting a hot fluid has been attempted by several authors.7,8 In this report a method is presented to numerically predict the oil displacement by hot water in a radial system, taking into account the heat losses to adjacent strata, changes in viscosity ratio with temperature and the thermal-expansion effect for both oil and water. DERIVATION OF BASIC EQUATIONS We start with the familiar Buckley-Leverett9 equation for a radial system:*Equation 1 This can be written in the formEquation 2 This is sometimes referred to as the Lagrangian form of the displacement equation.

Prediction of the Phase Behavior Generated by the Enriched-Gas-Drive Process

1965 ◽  
Vol 5 (02) ◽  
pp. 160-166 ◽  
Author(s):  
A.M. Rowe ◽  
I.H. Silberberg
Keyword(s):  
Computer Program ◽  
Phase Behavior ◽  
Oil Recovery ◽  
Miscible Displacement ◽  
Phase Changes ◽  
Experimental Results ◽  
High Concentration ◽  
Gas Drive ◽  
Non Equilibrium ◽  
Vapor Liquid

Abstract A computer program was written to predict the phase behavior generated by the enriched-gas-drive process. This program is based, in part, on a new concept of convergence pressure, which is then used to select vapor-liquid equilibrium ratios (K-factors) for performing a series of flash calculations. The results of these calculations are the equilibrium vapor and liquid phase compositions which define the phase envelopes. The program was used to predict phase envelopes for 11 different hydrocarbon systems on which published experimental data were available. The predicted and experimental results compare favorably. Introduction The reservoir engineer is frequently faced with the problem of predicting what will happen if gas is injected into a reservoir. One aspect of this general problem is predicting the phase changes that will occur when a non-equilibrium gas displaces a reservoir fluid. In particular, a "dry" gas, upon displacing a volatile oil will pick up intermediate components from the oil. On the other hand, a "wet" gas, containing a high concentration of intermediates, will lose some of these components to a relatively low-gravity, non-equilibrium crude. It is this latter process, occurring in the enriched-gas displacement, which is treated in this paper. In the past, these phase changes have been determined experimentally and the results incorporated into various modifications of the Buckley-Leverett analysis. Such experimental work is time consuming, and the results are sensitive to numerous experimental errors. With the wide availability of high-speed digital computing equipment and numerous correlations pertaining to the vapor-liquid equilibria of hydrocarbon systems, it is now practical to calculate such phase behavior. This paper describes a computer program for performing these calculations. THE ENRICHED GAS DISPLACEMENT PROCESS Experimental results have shown that oil recovery can be significantly increased by enriching the displacing gas with intermediate hydrocarbon components. The essential features of the phase behavior generated by this enriched-gas-drive process are commonly illustrated with ternary diagrams such as Fig. 1. In this figure, Gas D, which contains a high concentration of intermediate hydrocarbons with respect to the undersaturated Crude A, is injected into the reservoir. When D contacts A, gas goes into solution until the oil becomes saturated (Point. B). Further contacting of Gas D and saturated Oil B results in a Mixture C which separates into Vapor Y(c) and Liquid X(c). Liquid X(c) is contacted by additional Gas D, resulting in Mixture E which separates into Vapor Y(e) and Liquid X(e). Repeated contacts of the liquid by the injected gas will eventually result in Liquid X(d) of maximum enrichment existing in equilibrium with Gas Y(d). The equilibrium tie-line X(d) Y(d), when extended, passes through the Point D representing the enriched injection gas. For systems of more than three components, the predicted equilibrium states are dependent upon not only reservoir temperature and pressure, but also the compositions of the crude oil and injected gas. If the gas is sufficiently enriched, a miscible displacement is generated. Line is tangent to the phase envelope at the critical point (Point Z) and represents the limiting slope of the tie-lines as the critical state is approached. Point I therefore represents the minimum enrichment of injection gas required to generate a miscible displacement. Point G represents the minimum enrichment required for initial miscibility of the injection gas with Crude A.Attra has presented a method to be used for prediction of oil recovery by the enriched gas displacement process. To develop the phase behavior data needed, he designed the experimental procedure described in the following quotation from his paper SPEJ P. 160ˆ

Effects of Rate, Temperature, and Solvent Type on Vapor/Oil Gravity Drainage (VOGD) in Fractured Reservoirs

SPE Journal ◽  
2019 ◽  
Vol 24 (03) ◽  
pp. 973-987 ◽  
Author(s):  
Neha Anand ◽  
Brandon Tang ◽  
Bradley (Duong) Nguyen ◽  
Chao-yu Sie ◽  
Marco Verlaan ◽  
...  
Keyword(s):  
Oil Recovery ◽  
Molecular Diffusion ◽  
Operating Temperature ◽  
Fractured Reservoirs ◽  
Viscosity Reduction ◽  
Gravity Drainage ◽  
Asphaltene Precipitation ◽  
Solvent Vapor ◽  
Solvent Type ◽  
High Fluid

Summary Application of thermal and solvent enhanced-oil-recovery (EOR) technologies for viscous heavy-oil recovery in naturally fractured reservoirs is generally challenging because of low permeability, unfavorable wettability and mobility, and considerable heat losses. Vapor/oil gravity drainage (VOGD) is a modified solvent-only injection technology, targeted at improving viscous oil recovery in fractured reservoirs. It uses high fluid conductivity in vertical fractures to rapidly establish a large solvent/oil contact area and eliminates the need for massive energy and water inputs, compared with thermal processes, by operating at significantly lower temperatures with no water requirement. An investigation of the effects of solvent-injection rate, temperature, and solvent type [n-butane and dichloromethane (DCM)] on the recovery profile was performed on a single-fracture core model. This work combines the knowledge obtained from experimental investigation and analytical modeling using the Butler correlation (Das and Butler 1999) with validated fluid-property models to understand the relative importance of various recovery mechanisms behind VOGD—namely, molecular diffusion, asphaltene precipitation and deposition, capillarity, and viscosity reduction. Experimental and analytical model studies indicated that molecular diffusion, convective dispersion, viscosity reduction by means of solvent dissolution, and gravity drainage are dominant phenomena in the recovery process. Material-balance analysis indicated limited asphaltene precipitation. High fluid transmissibility in the fracture along with gravity drainage led to early solvent breakthroughs and oil recoveries as high as 75% of original oil in place (OOIP). Injecting butane at a higher rate and operating temperature enhanced the solvent-vapor rate inside the core, leading to the highest ultimate recovery. Increasing the operating temperature alone did not improve ultimate recovery because of decreased solvent solubility in the oil. Although with DCM, lower asphaltene precipitation should maximize the oil-recovery rate, its higher solvent (vapor)/oil interfacial tension (IFT) resulted in lower ultimate recovery than butane. Ideal density and nonideal double-log viscosity-mixing rules along with molecular diffusivity as a power function of oil viscosity were used to obtain an accurate physical description of the fluids for modeling solvent/oil behavior. With critical phenomena such as capillarity and asphaltene precipitation missing, the Butler analytical model underpredicts recovery rates by as much as 70%.

The Effect of Phase Equilibria on the CO2 Displacement Mechanism

1979 ◽  
Vol 19 (04) ◽  
pp. 242-252 ◽  
Author(s):  
R.S. Metcalfe ◽  
Lyman Yarborough
Keyword(s):  
Carbon Dioxide ◽  
Phase Equilibria ◽  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Miscible Displacement ◽  
Co2 Flooding ◽  
Recovery Method ◽  
Two Fluids ◽  
Reservoir Conditions

Abstract Carbon dioxide flooding under miscible conditions is being developed as a major process for enhanced oil recovery. This paper presents results of research studies to increase our understanding of the multiple-contact miscible displacement mechanism for CO2 flooding. Carbon dioxide displacements of three synthetic oils of increasing complexity (increasing number of hydrocarbon components) are described. The paper concentrates on results of laboratory flow studies, but uses results of phase-equilibria and numerical studies to support the conclusions.Results from studies with synthetic oils show that at least two multiple-contact miscible mechanisms, vaporization and condensation, can be identified and that the phase-equilibria data can be used as a basis for describing the mechanism. The phase-equilibria change with varying reservoir conditions, and the flow studies show that the miscible mechanism depends on the phase-equilibria behavior. Qualitative predictions with mathematical models support our conclusions.Phase-equilibria data with naturally occurring oils suggest the two mechanisms (vaporization and condensation) are relevant to CO2 displacements at reservoir conditions and are a basis for specifying the controlling mechanisms. Introduction Miscible-displacement processes, which rely on multiple contacts of injected gas and reservoir oil to develop an in-situ solvent, generally have been recognized by the petroleum industry as an important enhanced oil-recovery method. More recently, CO2 flooding has advanced to the position (in the U.S.) of being the most economically attractive of the multiple-contact miscibility (MCM) processes. Several projects have been or are currently being conducted either to study or use CO2 as an enhanced oil-recovery method. It has been demonstrated convincingly by Holm and others that CO2 can recover oil from laboratory systems and therefore from the swept zone of petroleum reservoirs using miscible displacement. However, several contradictions seem to exist in published results.. These authors attempt to establish the mechanism(s) through which CO2 and oil form a miscible solvent in situ. (The solvent thus produced is capable of performing as though the two fluids were miscible when performing as though the two fluids were miscible when injected.) In addition, little experimental work has been published to provide support for the mechanisms of multiple-contact miscibility, as originally discussed by Hutchinson and Braun.One can reasonably assume that the miscible CO2 process will be related directly to phase equilibria process will be related directly to phase equilibria because it involves intimate contact of gases and liquids. However, no data have been published to indicate that the mechanism for miscibility development may differ for varying phase-equilibria conditions.This paper presents the results of both flow and phase-equilibria studies performed to determine the phase-equilibria studies performed to determine the mechanism(s) of CO2 multiple-contact miscibility. These flow studies used CO2 to displace three multicomponent hydrocarbon mixtures under first-contact miscible, multiple-contact miscible, and immiscible conditions. Results are presented to support the vaporization mechanism as described by Hutchinson and Braun, and also to show that more than one mechanism is possible with CO2 displacements. The reason for the latter is found in the results of phase-equilibria studies. SPEJ P. 242

Carbon Dioxide Displacement of a West Texas Reservoir Oil

1982 ◽  
Vol 22 (06) ◽  
pp. 805-815 ◽  
Author(s):  
William F. Yellig
Keyword(s):  
Mass Transfer ◽  
Phase Equilibria ◽  
Oil Recovery ◽  
Miscible Displacement ◽  
Pilot Test ◽  
Co2 Flooding ◽  
Process Data ◽  
Analytical Technique ◽  
West Texas ◽  
Pilot Tests

Yellig, William F., SPE, Amoco Production Co. Abstract This paper presents results of an extensive study to understand CO2 displacement of Levelland (TX) reservoir oil. The work was conducted to support Levelland CO2 pilots currently in progress. Experimental displacement tests were conducted at various pressures, core lengths, and CO2 frontal advance rates. The experimental system included a novel analytical technique to obtain effluent compositional profiles within the oil-moving zone at test conditions. The results of this study show that at pressures greater than the CO2 minimum miscibility pressure (MMP), a multicontact miscible displacement mechanism predominates. Miscibility is developed in situ by vaporization or extraction-type mass transfer. The laboratory lengths required for CO2 to develop miscibility and exhibit miscible displacement efficiency were found dependent on the phase equilibria of the CO2/Levelland oil system. Displacements requiring the greatest length to develop miscibility were at pressures where single-contact mixtures of CO2 and Levelland oil form two liquid phases. A companion paper demonstrates the use of the analytical technique developed in this study to obtain process data from a CO2 field pilot test. In addition, the mechanistic information obtained from this study is used to interpret the process data from the pilot test. The results have application to other reservoir oils whose phase equilibria with CO2 are similar to the CO2/ Levelland oil system. Introduction Miscible CO2 flooding is developing rapidly as a commercial enhanced oil-recovery process. The successful design and interpretation of CO2 pilot tests and fieldwide floods are dependent on a good knowledge of the reservoir and the CO2 displacement process. The overall CO2 displacement process is shown schematically in Fig. 1. The main focus of this study concerned the oil moving zone (OMZ) and particularly the mechanisms by which this zone formed and by which CO2 displaced Levelland oil. Levelland oil was chosen because it is typical of many west Texas reservoir oils being considered for CO2 flooding. In addition, the CO2 pilot tests currently conducted in the Levelland field provide a direct application of this research. Several authors have discussed the displacement of reservoir oil by CO2. These discussions have centered around three primary displacement mechanisms: immiscible, multicontact or developed miscible, and contact miscible. In addition, two basic types of mass transfer have been postulated as responsible for the development of miscibility in a multicontact process: transfer of hydrocarbons from the in-place oil to the displacing CO2 (i.e., vaporization or extraction) and transfer of CO2 to the in-place oil (i.e., condensation). Vaporization and extraction are the same basic mass-transfer process. Vaporization refers to mass transfer from a liquid oil phase to a CO2-rich vapor phase and extraction refers to mass transfer from a liquid oil phase to a CO2-rich liquid phase. The distinction between vaporization and extraction is somewhat arbitrary in describing the CO2 process since it reflects the types of phases present only on first contact. One purpose of this paper is to present results of a comprehensive study to determine the mechanism by which CO2 displaces Levelland oil at reservoir conditions. SPEJ P. 805^

Interfacial Effects in Immiscible Liquid-Liquid Displacement in Porous Media

1966 ◽  
Vol 6 (03) ◽  
pp. 247-253 ◽  
Author(s):  
Necmettin Mungan
Keyword(s):  
Porous Media ◽  
Interfacial Tension ◽  
Oil Recovery ◽  
Viscosity Ratio ◽  
Active Material ◽  
Immiscible Liquid ◽  
Low Surface Energy ◽  
Surface Active ◽  
Surface Active Material ◽  
Liquid Displacement

Abstract A study was made of the effects of wettability and interfacial tension the immiscible displacement of a liquid by another liquid for porous media. The influence of viscosity ratio was also investigated. Porous media used were polytetrafluoroethylene (TFE) cores prepared by compressing TFE powder under different pressures. It is shown that displacement of a wetting by a nonwetting liquid is always less efficient than the displacement of a nonwetting by a wetting fluid, all other things being equal. In the former case, the recovery efficiency can be increased substantially by either reducing the interfacial tension or increasing the viscosity of the displacing fluid. A qualitative discussion is given on the implications of this work to the recovery of crude oil by waterflooding. Introduction The high cost of oil exploration and new recovery schemes makes it imperative that waterflooding be conducted under conditions favoring most efficient oil recovery. To improve oil recovery by waterflooding, it is essential that the role played by interfacial forces in the entrapment of residual oil be studied and understood. Interfacial phenomena in natural rock, connate water and crude oil systems are very complicated because of the complexity of the natural liquids found in petroleum reservoirs, because of our inability to adequately describe the geometrical structure of the porous media and because of a lack of understanding of physical and chemical interactions between the liquids and surface of the pores. The problem becomes further complicated when one tries to elucidate the role of interfacial phenomena in fluid flow. Numerous studies of the displacement of oil by water under different interfacial tension or wettability conditions have been made. These studies have been performed in silica, alundum or sandstone systems using water and paraffin oil and also some surface active material to control the interfacial tension or and the contact angle. Unfortunately, the high energies of various interfaces involved favor adsorption and orientation of the surface active material at the intrafaces. Also the surface active material concentration at the interfaces exceeds that in the bulk of the liquid phases. Such surface excess may cause the surfactant distribution, the contact angle and the interfacial tension to differ from their measured static equilibrium values and makes interpretation of the displacement experiments difficult. Furthermore, as changes in also lead to changes in cos, the role played individually by one of these parameters in the displacement becomes obscured by the effect of the other. To circumvent these difficulties, a low surface energy solid and true solutions or pure liquids should be used. Use of a low surface energy solid minimizes adsorption and orientation effects at the solid-liquid interfaces. By controlling and cos through use of selected pairs of pure liquids or true solutions rather than by surfactants, the adsorption effects at liquid-liquid interfaces are eliminated. In the present study TFE cores were used as me porous media. Liquids used were water sucrose solutions, paraffin oils and benzyl, n-butyl and isobutyl alcohols. The interfacial tension was varied from 40 to 1.1 dynes/cm by suitably choosing the liquid pair. A surface above material was added to the water-oil system only in the case where interfacial tension of 0.5 dynes/ cm was desired. No precise changes of cos were attempted. However, either the displaced or the displacing liquid could be made the one which preferentially wets the TFE surface. Using sucrose solutions and blends of paraffin oils proved to be a convenient way of changing the viscosity ratio between the displaced and displacing liquids. The present investigation examines the effect of interfacial tension, wettability and viscosity ratio on the immiscible liquid-liquid displacement from porous media. SPEJ P. 217ˆ

Using vorticity to quantify the relative importance of heterogeneity, viscosity ratio, gravity and diffusion on oil recovery

2012 ◽  
Vol 16 (2) ◽  
pp. 409-422 ◽  
Author(s):  
Bilal Rashid ◽  
Astor-Lonice Bal ◽  
Glyn J. J. Williams ◽  
Ann H. Muggeridge
Keyword(s):  
Oil Recovery ◽  
Viscosity Ratio ◽  
Relative Importance ◽  
And Diffusion
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