A New Class of 125 ksi SMYS Sour Service Drillpipe Offers Improved Capabilities for Drilling in Sour Gas Environments

2016 ◽  
Author(s):  
Lucien Hehn ◽  
Amie Uttecht ◽  
Michael Jellison ◽  
Leianne Sanclemente ◽  
Mike Delahoussaye
Keyword(s):  
Author(s):  
Ray Goodfellow ◽  
Rory Belanger

Chevron Canada Resources recently completed a hot tap on the Simonette high-pressure sour gas transmission line near Grande Prairie, Alberta. The hot tap was required to bring on new production into the Simonette pipeline without shutting in existing production. The hot tap was completed under full line pressure and gas/condenstate flow during the winter with temperatures averaging −20°C. The design pressure of the 12 “ Gr. 359 Cat II pipeline is 9930 kPa and the line operates at 8200 kPa. The gas in the main transmission line is approximately 2% H2S and 4% CO2. The gas being brought on through the 4″ hot tap tie-in was 21% H2S and 5% CO2. At the tie-in point the transmission line temperature was 3°C. Safely welding on the pipeline under these conditions was a considerable technical challenge. In welding sour service lines it is critical that the final weld hardness be below Vickers 248 micro hardness. This can be very difficult to achieve when welding on a line transporting a quenching medium of gas and condensate. In addition, hydrogen charging of the steel from operation in sour service can lead to hydrogen embrittlement during welding. Ludwig & Associates developed the hot tap weld procedure and extensively tested the procedure to ensure that suitable weld microhardness was achievable under pipeline operating conditions. As part of the procedure development the welder who would perform the hot tap was tested repeatedly until he could confidently and successfully complete the weld. During fieldwork, the welding was rigorously monitored to ensure procedural compliance thereby minimizing the possibility of elevated hardness zones within the completed weldment. This paper will detail with the technical development of the hot tap welding procedure and the successful field implementation.


Author(s):  
Mamdouh M. Salama ◽  
Hernan Rincon ◽  
Stuart Wilson

The recent premature failure of TMCP steel pipes handling sour gas was attributed to the presence of local hard spots. This raised concern regarding the suitability of the Thermo-Mechanically Controlled Process (TMCP) steel for sour service. The paper discusses the impact of hard spots on pipeline fracture resistance in sour service, proposes a basis for steel specification to avoid the formation of hard spots and presents a recommended qualification program to ensure the integrity of the steel pipelines despite the presence of hard spots.


Author(s):  
Frances M. Ross ◽  
Peter C. Searson

Porous semiconductors represent a relatively new class of materials formed by the selective etching of a single or polycrystalline substrate. Although porous silicon has received considerable attention due to its novel optical properties1, porous layers can be formed in other semiconductors such as GaAs and GaP. These materials are characterised by very high surface area and by electrical, optical and chemical properties that may differ considerably from bulk. The properties depend on the pore morphology, which can be controlled by adjusting the processing conditions and the dopant concentration. A number of novel structures can be fabricated using selective etching. For example, self-supporting membranes can be made by growing pores through a wafer, films with modulated pore structure can be fabricated by varying the applied potential during growth, composite structures can be prepared by depositing a second phase into the pores and silicon-on-insulator structures can be formed by oxidising a buried porous layer. In all these applications the ability to grow nanostructures controllably is critical.


Author(s):  
G. C. Ruben ◽  
K. Iqbal ◽  
I. Grundke-Iqbal ◽  
H. Wisniewski ◽  
T. L. Ciardelli ◽  
...  

In neurons, the microtubule associated protein, tau, is found in the axons. Tau stabilizes the microtubules required for neurotransmitter transport to the axonal terminal. Since tau has been found in both Alzheimer neurofibrillary tangles (NFT) and in paired helical filaments (PHF), the study of tau's normal structure had to preceed TEM studies of NFT and PHF. The structure of tau was first studied by ultracentrifugation. This work suggested that it was a rod shaped molecule with an axial ratio of 20:1. More recently, paraciystals of phosphorylated and nonphosphoiylated tau have been reported. Phosphorylated tau was 90-95 nm in length and 3-6 nm in diameter where as nonphosphorylated tau was 69-75 nm in length. A shorter length of 30 nm was reported for undamaged tau indicating that it is an extremely flexible molecule. Tau was also studied in relation to microtubules, and its length was found to be 56.1±14.1 nm.


Author(s):  
T. F. Kelly ◽  
P. J. Lee ◽  
E. E. Hellstrom ◽  
D. C. Larbalestier

Recently there has been much excitement over a new class of high Tc (>30 K) ceramic superconductors of the form A1-xBxCuO4-x, where A is a rare earth and B is from Group II. Unfortunately these materials have only been able to support small transport current densities 1-10 A/cm2. It is very desirable to increase these values by 2 to 3 orders of magnitude for useful high field applications. The reason for these small transport currents is as yet unknown. Evidence has, however, been presented for superconducting clusters on a 50-100 nm scale and on a 1-3 μm scale. We therefore planned a detailed TEM and STEM microanalysis study in order to see whether any evidence for the clusters could be seen.A La1.8Sr0.2Cu04 pellet was cut into 1 mm thick slices from which 3 mm discs were cut. The discs were subsequently mechanically ground to 100 μm total thickness and dimpled to 20 μm thickness at the center.


Author(s):  
J. Fink

Conducting polymers comprises a new class of materials achieving electrical conductivities which rival those of the best metals. The parent compounds (conjugated polymers) are quasi-one-dimensional semiconductors. These polymers can be doped by electron acceptors or electron donors. The prototype of these materials is polyacetylene (PA). There are various other conjugated polymers such as polyparaphenylene, polyphenylenevinylene, polypoyrrole or polythiophene. The doped systems, i.e. the conducting polymers, have intersting potential technological applications such as replacement of conventional metals in electronic shielding and antistatic equipment, rechargable batteries, and flexible light emitting diodes.Although these systems have been investigated almost 20 years, the electronic structure of the doped metallic systems is not clear and even the reason for the gap in undoped semiconducting systems is under discussion.


2020 ◽  
Vol 7 (3) ◽  
pp. 786-794 ◽  
Author(s):  
Jingqi Han ◽  
Kin-Man Tang ◽  
Shun-Cheung Cheng ◽  
Chi-On Ng ◽  
Yuen-Kiu Chun ◽  
...  

A new class of luminescent cyclometalated Ir(iii) complexes with readily tunable mechanochromic properties derived from the mechanically induced trans-to-cis isomerization have been developed.


2020 ◽  
Vol 11 (24) ◽  
pp. 3940-3950 ◽  
Author(s):  
Patrick Verkoyen ◽  
Holger Frey

Amino-functional polyethers have emerged as a new class of “smart”, i.e. pH- and thermoresponsive materials. This review article summarizes the synthesis and applications of these materials, obtained from ring-opening of suitable epoxide monomers.


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