Effects of Brine on Crude Oil Viscosity at Different Temperature and Brine Composition - Heavy Oil/Water Interaction

2013 ◽  
Author(s):  
Heron Gachuz-Muro ◽  
Mehran Sohrabi
Keyword(s):  
Crude Oil ◽  
Heavy Oil ◽  
Oil Viscosity ◽  
Water Interaction ◽  
Oil Water

Use CO2 Soluble Surfactant to Decrease the Minimum Miscibility Pressure of CO2 Flooding in Oil Reservoir

2011 ◽  
Vol 239-242 ◽  
pp. 2650-2654
Author(s):  
Fu Chen ◽  
Jie He ◽  
Ping Guo ◽  
Yuan Xu ◽  
Cheng Zhong
Keyword(s):  
Citric Acid ◽  
Crude Oil ◽  
Water System ◽  
Viscosity Reduction ◽  
Mass Ratio ◽  
Oil Viscosity ◽  
Minimum Miscibility Pressure ◽  
Oil Water ◽  
Carbon Dioxide Miscible Flooding ◽  
Soluble Surfactant

According to the mechanisms of carbon dioxide miscible flooding and previous researchers’ work on synthesis of CO2-soluble surfactant, Citric acid isoamyl ester was synthesized, and it’s oil solubility and the rate of viscosity reduction both in oil-water system and oil were evaluated. And then we found that this compound can solve in oil effectively; the optimum mass of Citric acid isoamyl ester introduced in oil-water system is 0.12g when the mass ratio of oil and water is 7:3 (crude oil 23.4g, formation water 10g) and the experimental temperature is 50°C , the rate of viscosity reduction is 47.2%; during the evaluation of the ability of Citric acid isoamyl ester to decrease oil viscosity, we found that the optimum dosage of this compound in 20g crude oil is 0.2g when the temperature is 40°C, and the rate of viscosity reduction is 7.37% at this point.

Indoor Study of Viscosity Reducer for Thickened Oil of Huancai

2012 ◽  
Vol 268-270 ◽  
pp. 547-550
Author(s):  
Qing Wang Liu ◽  
Xin Wang ◽  
Zhen Zhong Fan ◽  
Jiao Wang ◽  
Rui Gao ◽  
...  
Keyword(s):  
Interfacial Tension ◽  
Oil Recovery ◽  
Heavy Oil ◽  
High Viscosity ◽  
Oil Field ◽  
Viscosity Reduction ◽  
Oil Viscosity ◽  
Low Viscosity ◽  
Viscosity Reducer ◽  
Oil Water

Liaohe oil field block 58 for Huancai, the efficiency of production of thickened oil is low, and the efficiency of displacement is worse, likely to cause other issues. Researching and developing an type of Heavy Oil Viscosity Reducer for exploiting. The high viscosity of W/O emulsion changed into low viscosity O/W emulsion to facilitate recovery, enhanced oil recovery. Through the experiment determine the viscosity properties of Heavy Oil Viscosity Reducer. The oil/water interfacial tension is lower than 0.0031mN•m-1, salt-resisting is good. The efficiency of viscosity reduction is higher than 90%, and also good at 180°C.

Flow Patterns in Heavy Crude Oil-Water Flow

2001 ◽  
Author(s):  
Antonio C. Bannwart ◽  
Oscar M. H. Rodriguez ◽  
Carlos H. M. de Carvalho ◽  
Isabela S. Wang ◽  
Rosa M. O. Vara
Keyword(s):  
Crude Oil ◽  
Flow Pattern ◽  
Heavy Oil ◽  
Annular Flow ◽  
Effective Means ◽  
Practical Importance ◽  
Flow Patterns ◽  
Heavy Crude Oil ◽  
Oil Water ◽  
Heavy Crude

Abstract This paper is aimed to an experimental study on the flow patterns formed by heavy crude oil (488 mPa.s, 925.5 kg/m3 at 20 °C) and water inside vertical and horizontal 1 in. pipes. The interfacial tension was 29 dynes/cm. Effort is concentrated into flow pattern characterization, which was visually defined. The similarities with gas-liquid flow patterns are explored and the results are expressed in flow maps of the superficial velocities. In contrast with other studies, the annular flow pattern (‘core annular flow’) was observed in both horizontal and vertical test sections. In fact this flow pattern typically occurs in heavy oil-water flows at low water input fractions. Because of the practical importance of core flow in providing an effective means for heavy oil production and transportation, this paper discusses two criteria that favor its occurrence in pipes.

Flow Patterns in Heavy Crude Oil-Water Flow

2004 ◽  
Vol 126 (3) ◽  
pp. 184-189 ◽  
Author(s):  
Antonio C. Bannwart ◽  
Oscar M. H. Rodriguez ◽  
Carlos H. M. de Carvalho ◽  
Isabela S. Wang ◽  
Rosa M. O. Vara
Keyword(s):  
Crude Oil ◽  
Flow Pattern ◽  
Heavy Oil ◽  
Annular Flow ◽  
Effective Means ◽  
Practical Importance ◽  
Flow Patterns ◽  
Heavy Crude Oil ◽  
Oil Water ◽  
Heavy Crude

This paper is aimed to an experimental study on the flow patterns formed by heavy crude oil (initial viscosity and density 488 mPa s, 925.5kg/m3 at 20°C) and water inside vertical and horizontal 2.84-cm-i.d. pipes. The oil-water interfacial tension was 29 dyn/cm. Effort is concentrated into flow pattern characterization, which was visually defined. The similarities with gas-liquid flow patterns are explored and the results are expressed in flow maps. In contrast with other studies, the annular flow pattern (“core annular flow”) was observed in both horizontal and vertical test sections. These flow pattern tends to occur in heavy oil-water flows at low water input fractions. Because of the practical importance of core flow in providing an effective means for heavy oil production and transportation, this paper discusses criteria that favor its occurrence in pipes.

Water-Based Nanofluid-Alternating-CO2 Injection for Enhancing Heavy Oil Recovery: Underlying Mechanisms that Influence its Efficiency

2021 ◽  
Author(s):  
Changxiao Cao ◽  
Zhaojie Song ◽  
Shan Su ◽  
Zihan Tang ◽  
Zehui Xie ◽  
...  
Keyword(s):  
Crude Oil ◽  
Oil Recovery ◽  
Heavy Oil ◽  
Phase Inversion ◽  
Core Flooding ◽  
Heavy Component ◽  
Water Emulsion ◽  
Heavy Oil Reservoirs ◽  
Oil Water ◽  
Underlying Mechanisms

Abstract The efficiency of CO2 water-alternating-gas (WAG) flooding is highly limited in low-permeability heavy oil reservoirs due to the viscosifying action of W/O emulsification and high mobility contrast between oil and CO2. Here we propose a new enhanced oil recovery (EOR) process which involves water-based nanofluid-alternating-CO2 (NWAG) injection, and investigate the synergistic effect of nanofluid and CO2 for enhancing heavy oil recovery. Firstly, the oil-nanofluid and oil-water emulsions were prepared, and the bulk rheology and interfacial properties of emulsion fluid were tested. Then, core flooding tests were conducted to examine the NWAG flooding efficiency and its underlying mechanisms. The results showed that the bulk viscosity and viscoelasticity of oil-nanofluid emulsion reported much lower than those of oil-water emulsion, and nanofluid presented a positive contribution to the phase inversion from W/O to O/W emulsification. Compared with oil-water emulsion, the interfacial storage modulus of oil-nanofluid emulsion was obviously increased, which confirmed that more of crude oil heavy components with surface activity (e.g., resin and asphaltene) were adsorbed on interfacial film with the addition of silica nanoparticles (NPs). However, the interfacial viscosity of oil-nanofluid emulsion was much lower than that of oil-water emulsion, showing the irregularity of interfacial adsorption. This implied that the self-assembly structure of crude oil heavy component of the oil-water interface was destroyed due to the surface activity of silica NPs. During the core flooding experiments, NWAG injection could reduce the displacement pressure by 57.14% and increase oil recovery by 23.31% compared to WAG injection. By comparing produced-oil components after WAG and NWAG injection, we found that more of crude oil light components were extracted by CO2 during NWAG flooding, showing that the interaction between CO2 and crude oil was improved after oil-nanofluid emulsification. These findings clearly indicated two main EOR mechanisms of NWAG injection. One was the phase inversion during the nanofluid flooding process. The addition of silica NPs promoted phase-inversion emulsification and thus improved the displacement efficiency. The other was the enhanced interaction between CO2 and crude oil after oil-nanofluid emulsification. Because of the enhanced adsorption of crude oil heavy component on the oil-water interface, the proportion of light hydrocarbon increased in the bulk phase, and so the interaction between CO2 and oil phase was improved. This work could provide a new insight into the high-efficiency exploitation of low-permeability heavy oil reservoirs.

Particle-Transport Mechanism in Liquid/Liquid/Solid Multiphase Pipeline Flow of High-Viscosity Oil/Water/Sand

SPE Journal ◽  
2021 ◽  
pp. 1-16
Author(s):  
Archibong Archibong-Eso ◽  
Yahaya Baba ◽  
Aliyu Aliyu ◽  
Joseph Ribeiro ◽  
Fidelis Abam ◽  
...  
Keyword(s):  
Pressure Gradient ◽  
Heavy Oil ◽  
Test Section ◽  
Transport Mechanism ◽  
Plug Flow ◽  
Flow Patterns ◽  
Sand Transport ◽  
Oil Viscosity ◽  
Oil Water ◽  
Water Cut

Summary In this study, an investigation of sand transport in heavy-oil/water multiphase flow is performed. The study is conducted in three multiphase-flowpipeline-test facilities with internal diameters (IDs) of 1, 1, and 3 in. The pipeline orientations relative to the horizontal in the facilities are 0, +30, and 0°, respectively. Oil viscosity of 3.5 and 10.0 Pa·s with sand volume fractions from 0.010 to 0.100 vol% were used in the study. The effects of oil viscosity, upward inclination, sand volume fraction, pipe ID, and water cut on the sand-transport mechanism in pipelines are investigated. In the horizontal test section, flow patterns—namely, dispersed flow (DF), plug flow (PF), plug flow with moving sand bed (PFM), and plug flow with stationary sand bed (PFS)—were identified through flow visualization. In addition to the aforementioned, two flow patterns—stratified wavy flow with moving sand bed (SWM) and stratified wavy flow with dunes (SWD)—were observed in the inclined pipeline orientation. The pressure gradient measured decreased with a decrease in water cut until a minimum value was reached. Beyond the minimum pressure gradient, further reduction in water cut led to an increase in pressure gradient. The sand minimum transport condition (MTC) in the oil/water/sand test was largely the same for the 1-in. 30° upward inclined and the 1-in. horizontal test section. In contrast, that of the 3-in. horizontal test section was considerably higher. An improved MTC predictive correlation is proposed for multiphase heavy-oil/water/sand flow. The proposed correlation outperforms the existing models when tested on the heavy-oil/water/sand data set.

Effects of Steam on Heavy Oil Combustion

2009 ◽  
Vol 12 (04) ◽  
pp. 508-517 ◽  
Author(s):  
Alexandre Lapene ◽  
Louis Castanier ◽  
Gerald Debenest ◽  
Michel Yves Quintard ◽  
Arjan Matheus Kamp ◽  
...  
Keyword(s):  
Crude Oil ◽  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Heavy Oil ◽  
Combustion Front ◽  
Oil Viscosity ◽  
In Situ Combustion ◽  
Temperature Oxidation ◽  
Recovery Method

Summary In-Situ Combustion. In-situ combustion (ISC) is an enhanced oil-recovery method. Enhanced oil recovery is broadly described as a group of techniques used to extract crude oil from the subsurface by the injection of substances not originally present in the reservoir with or without the introduction of extraneous energy (Lake 1996). During ISC, a combustion front is propagated through the reservoir by injected air. The heat generated results in higher temperatures leading to a reduction in oil viscosity and an increase of oil mobility. There are two types of ISC processes, dry and wet combustion. In the dry-combustion process, a large part of the heat generated is left unused downstream of the combustion front in the burned-out region. During the wet-injection process, water is co-injected with the air to recover some of the heat remaining behind the combustion zone. ISC is a very complex process. From a physical point of view, it is a problem coupling transport in porous media, chemistry, and thermodynamics. It has been studied for several decades, and the technique has been applied in the field since the 1950s. The complexity was not well understood earlier by ISC operators. This resulted in a high rate of project failures in the 1960s, and contributed to the misconception that ISC is a problem-prone process with low probability of success. However, ISC is an attractive oil-recovery process and capable of recovering a high percentage of oil-in-place, if the process is designed correctly and implemented in the right type of reservoir (Sarathi 1999). This paper investigates the effect of water on the reaction kinetics of a heavy oil by way of ramped temperature oxidation under various conditions. Reactions. Earlier studies about reaction kinetic were conducted by Bousaid and Ramey (1968), Weijdema (1968), Dabbous and Fulton (1974), and Thomas et al. (1979). In these experiments, temperature of a sample of crude oil and solid matrix was increased over time or kept constant. The produced gas was analyzed to determine the concentrations of outlet gases, such as carbon dioxide, carbon monoxide, and oxygen. This kind of studies shows two types of oxidation reactions, the Low-Temperature Oxidation (LTO) and the High-Temperature Oxidation (HTO) (Burger and Sahuquet 1973; Fassihi et al. 1984a; Mamora et al. 1993). In 1984, Fassihi et al. (1984b) presented an analytical method to obtain kinetics parameters. His method requires several assumptions.

Loss Coefficient for Viscous Mixtures of Light and Heavy Crude Oil in Y-Junctions

2016 ◽  
Author(s):  
Andres Piñero ◽  
Elionora Caldera ◽  
Manuel Borregales ◽  
Miguel Asuaje
Keyword(s):  
Crude Oil ◽  
Viscous Fluids ◽  
Energy Losses ◽  
Heavy Crude Oil ◽  
Oil Viscosity ◽  
Cfd Simulations ◽  
Two Phase ◽  
Oil Water ◽  
Heavy Crude ◽  
Water Cut

One of the challenges of transporting highly viscous crude oil is to ensure that the flow of oil will be delivered. It is also necessary to keep the operational standards and conditions along sections of pipes and fittings. Today, with low oil prices, it is important to minimize energy losses through the pipelines and accessories. However, new designs are often based on correlations that have not been developed for heavy oil water mixtures and are not frequently reported in the literature. Moreover, conventional calculations do not take into account the presence of accessory lines, or simply consider by empirically adding an extra percentage of energy loss or according to the engineer design test. Even more, the current correlations that could estimate accessory loss do not work well for viscous fluids and are even less suitable for the case of two-phase mixtures. For example, Gardel correlation [1] was made for water flow through yee type accessories. Applying this correlation to viscous fluids result in high deviations, more than 500% compared to CFD simulations. The present work attempts to predict the fluid dynamics behavior and the energy losses of these viscous fluids and mixtures (oil - water) going through a Yee type confluence. All simulations were carried out using ANSY CFX® v14.5. Mesh number of elements was optimized using Pipe-It® (optimization software). A grid independence study was also carried out automatically in Pipe-It® to ensure the quality of results. Several conditions have been simulated: angle confluence of 45°–75°, diameter ratio 2–7, oil viscosity from 10 to 105 cP, and water cut of 0–1. As the main result, a correlation that predicts the behavior of viscous mixtures in their passage through yee type confluences was developed using a genetic algorithms technique [2]. This correlation takes into account: viscosity, fluid fractions, input speeds, confluence angle and other parameters that are not normally considered by other authors. Therefore, it may be used in mixtures of water with light and heavy crude oil. Finally, correlations with 10% deviation compared to CFD simulations were obtained.

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