Understanding the Co-deposition of Calcium Sulphate and Barium Sulphate and Developing Environmental Acceptable Scale Inhibitors Applied in HTHP Wells

Author(s):  
Xuan Liu ◽  
Tao Chen ◽  
Ping Chen ◽  
Harry Montgomerie ◽  
Thomas Hille Hagen ◽  
...  
Author(s):  
Dominica Una ◽  
Dulu Appah ◽  
Amieibibama Joseph ◽  
Onyewuchi Akaranta

With growing awareness of the environmental impact of some conventional production chemicals and concerns about the depletion of non-renewable natural resources, increased efforts are being made to use renewable and non-toxic materials in the oilfield. In this study, a potential green scale inhibitor was developed from the skin of red onions and evaluated for calcium sulphate, calcium carbonate and barium scale inhibition. Based on the different extraction processes utilized, two products were obtained and characterized using FTIR and SEM and evaluated using a static jar test procedure. The FTIR results confirmed the bands that make up the major constituents (quercetin) and other important compounds, which supports the present study. Laboratory evaluation show that ROSE can efficiently inhibit calcium sulphate scale and barium sulphate scales with a good inhibition rate of greater than 75% at an optimum dosage. Effect of temperature and dosage on inhibition performance revealed that ROSE is stable at higher temperatures and can effectively inhibit calcium and barium sulphate scales at nearly the same rate without degradation but requires additional dosage to produce same result for calcium carbonate scale. Also, the effect of time reveals that scale inhibitor performs a continuous CaSO4 and CaCO3 inhibition. Not only does ROSE perform excellently in the laboratory condition as a green scale inhibitor, but it also show a relatively close performance rate when compared to an existing commercial inhibitor which indicate that ROSE has a high potential for use in the oil industry.


2021 ◽  
Vol 887 ◽  
pp. 60-64
Author(s):  
Alexey Stolbovsky ◽  
Vita Vyatchina

The possibility of using the compositions of BaSO4-KPO3-Na2B4O7 system as a glass-solder (frit) material was shown. A glass formation region has been established in BaSO4-KPO3-Na2B4O7 system which is located in the borate-phosphate part of the concentration triangle and occupies ~41% of the triangle area. The concentration dependences of linear thermal expansion coefficient (TCLE), the softening temperature and the glass transition temperature was determined and discussed. It is established that the glass formation region, the concentration dependences of TCLE and technological temperatures values are significantly closer to those for CaSO4-KPO3-Na2B4O7 system than for MgSO4-KPO3-Na2B4O7 system. That may point out at the similar effect barium sulphate and calcium sulphate doping in the sulphate-phosphate-borate systems.


1975 ◽  
Vol 33 (02) ◽  
pp. 256-270
Author(s):  
R. M Howell ◽  
S. L. M Deacon

SummaryElectron microscopy and particle electrophoresis were found to be complementary techniques with which to complete the physical data from an earlier study on barium sulphates used to adsorb clotting factors from serum. The differences revealed by scanning electron microscopy (S. E. M.) in the physical shape of low and high density grades of barium sulphate particles appear to be of greater significance than charge as expressed by electrophoretic mobility, in determining whether or not precursor or preformed factor Xa is eluted.This conclusion was based on the finding that at pH values close to 7, where the adsorption from serum occurs, all samples with the exception of natural barytes were uncharged. However as the high-density, or soil-grade, was found by S. E. M. to consist of large solid crystals it was suggested that this shape might induce activation of factor X as a result of partial denaturation and consequent unfolding of the adsorbed protein. In contrast, uptake of protein into the centre of the porous aggregates revealed by S. E. M. pictures of low-density or X-ray grade barium sulphate may afford protection against denaturation and exposure of the enzyme site.The porous nature of particles of low-density barium sulphate compared with the solid crystalline forms of other grades accounts not only for its lower bulk density but also for its greater surface/gram ratio which is reflected by an ability to adsorb more protein from serum.Neither technique produced evidence from any of the samples to indicate the presence of stabilising agents sometimes used to coat particles in barium meals.


1966 ◽  
Vol 16 (3) ◽  
pp. 78-80
Author(s):  
M. J. Ridge ◽  
H. Surkevicius

Author(s):  
Vitória Felicio Dornelas ◽  
Cristiano Severo AIolfi ◽  
Valéria Santos ◽  
Daniel Ribeiro ◽  
Fabio de Assis Ressel Pereira ◽  
...  
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