Experimental and Theoretical Studies of Flocculated Asphaltene Deposition From Oil in Porous Media

2010 ◽  
Author(s):  
Ali Rezaian ◽  
Amin Kordestany ◽  
Mohammad Jamialahmadi ◽  
Jamshid Moghadasi ◽  
Mohammad Yousefi Khoshdaregi ◽  
...  
Keyword(s):  
Porous Media ◽  
Theoretical Studies ◽  
Asphaltene Deposition ◽  
Experimental And Theoretical Studies

Features of wave propagation in the sand of different saturation

2011 ◽  
Vol 8 (1) ◽  
pp. 25-38
Author(s):  
A.T. Akhmetov ◽  
S.V. Lukin ◽  
D.M. Balapanov ◽  
S.F. Urmancheev ◽  
N.M. Gumerov ◽  
...  
Keyword(s):  
Mathematical Model ◽  
Porous Medium ◽  
Porous Media ◽  
Wave Propagation ◽  
Water Saturation ◽  
Weak Shock ◽  
Capillary Forces ◽  
Theoretical Studies ◽  
Longitudinal Waves ◽  
Experimental And Theoretical Studies

There are the results of experimental and theoretical studies on the propagation of weak shock waves in the wet sand at different water saturation. There are mathematical model and numerical analysis of propagation of pressure pulses in porous media, taking into account capillary forces. Non-monotonic dependence of the amplitude of the wave resulting in a wet porous medium vs. the degree of water saturation is installed. The evolution of the fast, slow and filtration waves depends on the saturation of the system with water is analyzed. The influence of capillary forces on the propagation of longitudinal waves is evaluated.

The Stabilizing Effect of Pre-Equilibria: A Trifluoromethyl Complex as CF2 Reservoir in Catalytic Olefin Difluorocarbenation

2020 ◽  
Author(s):  
Thomas Louis-Goff ◽  
Huu Vinh Trinh ◽  
Eileen Chen ◽  
Arnold L. Rheingold ◽  
Christian Ehm ◽  
...  
Keyword(s):  
High Selectivity ◽  
Side Reactions ◽  
Theoretical Studies ◽  
Attractive Feature ◽  
Catalyst Recovery ◽  
Wide Range ◽  
Stabilizing Effect ◽  
Experimental And Theoretical Studies

A new, efficient, catalytic difluorocarbenation of olefins to give 1,1-difluorocyclopropanes is presented. The catalyst, an organobismuth complex, uses TMSCF<sub>3</sub> as a stoichiometric difluorocarbene source. We demonstrate both the viability and robustness of this reaction over a wide range of alkenes and alkynes, including electron-poor alkenes, to generate the corresponding 1,1-difluorocyclopropanes and 1,1-difluorocyclopropenes. Ease of catalyst recovery from the reaction mixture is another attractive feature of this method. In depth experimental and theoretical studies showed that the key difluorocarbene-generating step proceeds through a bismuth non-redox synchronous mechanism generating a highly reactive free CF<sub>2</sub> in an endergonic pre-equilibrium. It is the reversibility when generating the difluorocarbene that accounts for the high selectivity, while minimizing CF<sub>2</sub>-recombination side-reactions.

Strong coupling: resonant effects

2017 ◽  
Author(s):  
Alexey V. Kavokin ◽  
Jeremy J. Baumberg ◽  
Guillaume Malpuech ◽  
Fabrice P. Laussy
Keyword(s):  
Strong Coupling ◽  
Experimental Studies ◽  
Strong Coupling Regime ◽  
Theoretical Studies ◽  
Stimulated Scattering ◽  
Quantum Theories ◽  
Pump Probe ◽  
Exciton Polaritons ◽  
Linear Optical Properties ◽  
Experimental And Theoretical Studies

This chapter presents experimental studies performed on planar semiconductor microcavities in the strong-coupling regime. The first section reviews linear experiments performed in the 1990s that evidence the linear optical properties of cavity exciton-polaritons. The chapter is then focused on experimental and theoretical studies of resonantly excited microcavity emission. We mainly describe experimental configuations in which stimulated scattering was observed due to formation of a dynamical condensate of polaritons. Pump-probe and cw experiments are described in addition. Dressing of the polariton dispersion and bistability of the polariton system due to inter-condensate interactions are discussed. The semiclassical and the quantum theories of these effects are presented and their results analysed. The potential for realization of devices is also discussed.

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