HIGH SPEED MELT SPINNING OF NYLON 6

1981 ◽  
Vol 37 (4) ◽  
pp. T143-T152 ◽  
Author(s):  
Jiro Shimizu ◽  
Norimasa Okui ◽  
Takeshi Kikutani ◽  
Akihiro Ono ◽  
Akira Takaku
Keyword(s):  
High Speed ◽  
Melt Spinning ◽  
Nylon 6

Effect of molecular weight on high-speed melt spinning of nylon 6

1986 ◽  
Vol 31 (7) ◽  
pp. 2203-2229 ◽  
Author(s):  
Kiyohito Koyama ◽  
Jogendra Suryadevara ◽  
Joseph E. Spuriell
Keyword(s):  
Molecular Weight ◽  
High Speed ◽  
Melt Spinning ◽  
Nylon 6

scholarly journals Fiber Formation and Structural Development of HBA/HNA Thermotropic Liquid Crystalline Polymer in High-Speed Melt Spinning

Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1134
Author(s):  
Bo Seok Song ◽  
Jun Young Lee ◽  
Sun Hwa Jang ◽  
Wan-Gyu Hahm
Keyword(s):  
Mechanical Properties ◽  
Shear Rate ◽  
High Speed ◽  
Melt Spinning ◽  
Liquid Crystalline Polymer ◽  
Liquid Crystalline ◽  
Crystalline Polymer ◽  
Fiber Formation ◽  
Structural Development ◽  
Thermotropic Liquid Crystalline Polymer

High-speed melt spinning of thermotropic liquid crystalline polymer (TLCP) resin composed of 4-hydroxybenzoic acid (HBA) and 2-hydroxy-6-napthoic acid (HNA) monomers in a molar ratio of 73/27 was conducted to investigate the characteristic structure development of the fibers under industrial spinning conditions, and the obtained as-spun TLCP fibers were analyzed in detail. The tensile strength and modulus of the fibers increased with shear rate in nozzle hole, draft in spin-line and spinning temperature and exhibited the high values of approximately 1.1 and 63 GPa, respectively, comparable to those of industrial as-spun TLCP fibers, at a shear rate of 70,000 s−1 and a draft of 25. X-ray diffraction demonstrated that the mechanical properties of the fibers increased with the crystalline orientation factor (fc) and the fractions of highly oriented crystalline and non-crystalline anisotropic phases. The results of structure analysis indicated that a characteristic skin–core structure developed at high drafts (i.e., spinning velocity) and low spinning temperatures, which contributed to weakening the mechanical properties of the TLCP fibers. It is supposed that this heterogeneous structure in the cross-section of the fibers was induced by differences in the cooling rates of the skin and core of the fiber in the spin-line.

High-Speed Melt Spinning of Sheath-Core Bicomponent Polyester Fibers: High and Low Molecular Weight Poly(ethylene Terephthalate) Systems

1997 ◽  
Vol 67 (9) ◽  
pp. 684-694 ◽  
Author(s):  
J. Radhakrishnan ◽  
Takeshi Kikutani ◽  
Norimasa Okui
Keyword(s):  
Molecular Weight ◽  
High Speed ◽  
Melt Spinning ◽  
Ethylene Terephthalate ◽  
Maxwell Model ◽  
Low Molecular Weight ◽  
Structural Development ◽  
Solidification Temperature ◽  
Poly Ethylene Terephthalate ◽  
Poly Ethylene

Sheath-core bicomponent spinning of high molecular weight poly (ethylene terephthalate) (hmpet, IV = 1.02 dl/g) and low molecular weight pet (lmpet, IV = 0.65 dl/g) is done at a take-up velocity range of 1 to 7 km/min. The structures of the individual components in the as-spun bicomponent fibers are characterized. Orientation and orientation-induced crystallization of the hmpet component are enhanced, while those of the lmpet component are suppressed in comparison to corresponding single component spinning. Numerical simulation with the Newtonian model shows that elongational stress in the hmpet component is enhanced and that of the lmpet decreases during high-speed bicomponent spinning. The difference in elongational viscosity is the main factor influencing the mutual interaction between hmpet and lmpet, which in turn affect spinline dynamics, solidification temperature, and structural development in high-speed bicomponent spinning. Simulation with an upper-convected Maxwell model shows that considerable stress relaxation can occur in the lmpet component if the hmpet component solidifies before lmpet. A mechanism for structural development is also proposed, based on the simulation results and structural characterization data.

scholarly journals HIGH SPEED MELT SPINNING OF POLYESTER/ETHER POLY(ETHYLENE-1, 2-DIPHENOXYETHANE-p, p′-DICARBOXYLATE)

1986 ◽  
Vol 42 (7) ◽  
pp. T379-T388 ◽  
Author(s):  
Jiro Shimizu ◽  
Norimasa Okui ◽  
Yoshitaka Imai ◽  
Akira Takaku
Keyword(s):  
High Speed ◽  
Melt Spinning ◽  
Poly Ethylene

Fine structure formation and physical properties of poly(butylene terephthalate) fibres in high-speed melt spinning

e-Polymers ◽  
2003 ◽  
Vol 3 (1) ◽  
Author(s):  
Hee Lee Sun ◽  
Hou Kim Kyoung ◽  
Kikutani Takeshi ◽  
Hok Cho Hyun
Keyword(s):  
Fine Structure ◽  
Physical Properties ◽  
Structure Formation ◽  
High Speed ◽  
Melt Spinning ◽  
Mechanical Analysis ◽  
Scanning Calorimetry ◽  
Butylene Terephthalate ◽  
Initial Modulus ◽  
Higher Temperature

Abstract Poly(butylene terephthalate) (PBT) fibres were obtained by high-speed melt spinning up to a take-up velocity of 8 km/min. Fine structure formation and physical properties of these fibres were investigated. The increase of take-up velocity caused raises in both density and birefringence. In wide-angle X-ray diffraction equatorial profiles, the increase of take-up velocity can be observed in the (010) and (100) reflections of β-crystals; the reflection peaks are the sharpest at a take-up velocity of 6 km/min. The initial modulus of the fibres arises when the fraction of β-crystals is increased, while the tenacity depends more on the fraction of α-crystals, i.e., the total crystallinity. Thermal properties of high-speed spun PBT fibres were measured with differential scanning calorimetry, dynamic mechanical and thermo-mechanical analysis, etc. Endothermic curves become sharper with increasing take-up velocity, and endothermic melting peaks are shifted to higher temperature. Crystal structures are well developed in fibres obtained at higher take-up velocities. The tan δ peaks of PBT fibres tend to shift to higher temperature and the peak intensity is decreased with increasing take-up velocity, i.e., the packing density of PBT fibres is high when the take-up velocity and thus the orientation of amorphous regions is increased. The shrinkage has a tendency to decrease with increasing take-up velocity.

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