Carbonatite-Like Rock in a Dike of the Aikhal Kimberlite Pipe: Comparison with Carbonatites of the Nomokhtookh Site (Anabar Area)

2021 ◽  
Vol 62 (6) ◽  
pp. 605-618
Author(s):  
S.I. Kostrovitsky ◽  
D.A. Yakovlev ◽  
L.F. Suvorova ◽  
E.I. Demonterova
Keyword(s):  
Trace Element ◽  
Genetic Relationship ◽  
Kimberlite Pipe ◽  
Sr Isotope ◽  
Accessory Minerals ◽  
Fine Grained ◽  
Incompatible Elements ◽  
Open Issue ◽  
Carbonate Composition ◽  
Kimberlite Field

Abstract ––A dike of rock similar in composition to carbonatites has been found in the Aikhal diamondiferous pipe of the Alakit–Markha field of the Yakutian kimberlite province (YaKP). The fine-grained rock of essentially carbonate composition (dolomite and calcite) rich in thin-platy phlogopite contains minerals typical of carbonatites: monazite, baddeleyite, and pyrochlore. In the high contents and distribution of incompatible elements the rock differs significantly from kimberlites and is transitional from kimberlites to carbonatites. The content of incompatible elements in this rock is 3–5 times lower than that in carbonatite breccias of the pipes in the Staraya Rechka kimberlite field of the YaKP (Nomokhtookh site). The compositions of accessory trace element minerals from the Aikhal dike rock and the Nomokhtookh carbonatite breccias are compared. An assumption is made that the high contents of incompatible elements in the carbonatite-like rock, which caused the crystallization of accessory minerals, are due to the differentiation of kimberlite melt/fluid. The high Sr isotope ratios indicate that the rock altered during hydrothermal and metasomatic processes. The obtained data on the composition of the carbonatite-like rock cannot serve as an argument for the genetic relationship between the Aikhal kimberlites and typical carbonatites. The genetic relationship between kimberlites and carbonatites in the northern fields of the YaKP remains an open issue.

scholarly journals Genetic relationship between post-caldera and caldera-forming magmas from Aso volcano, SW Japan: Constraints from Sr isotope and trace element compositions

2011 ◽  
Vol 106 (2) ◽  
pp. 114-119 ◽  
Author(s):  
Masaya MIYOSHI ◽  
Tomoyuki SHIBATA ◽  
Masako YOSHIKAWA ◽  
Takashi SANO ◽  
Taro SHINMURA ◽  
...  
Keyword(s):  
Trace Element ◽  
Genetic Relationship ◽  
Sr Isotope ◽  
Aso Volcano ◽  
Sw Japan

In-situ trace element analysis of monazite and other fine-grained accessory minerals by EPMA

2008 ◽  
Vol 254 (3-4) ◽  
pp. 197-215 ◽  
Author(s):  
Michael J. Jercinovic ◽  
Michael L. Williams ◽  
Edward D. Lane
Keyword(s):  
Trace Element ◽  
Trace Element Analysis ◽  
Element Analysis ◽  
Accessory Minerals ◽  
Fine Grained

Age and Composition of Zircons From the Devonian Petrivske Kimberlite Pipe of the Azov Domain, the Ukrainian Shield

2021 ◽  
Vol 43 (4) ◽  
pp. 50-55
Author(s):  
L.V. SHUMLYANSKYY ◽  
V. KAMENETSKY ◽  
B.V. BORODYNYA
Keyword(s):  
Trace Elements ◽  
Trace Element ◽  
Continental Crust ◽  
Kimberlite Pipe ◽  
Zircon Crystal ◽  
Precambrian Rock ◽  
Weighted Mean ◽  
Terrigenous Rocks ◽  
Devonian Age ◽  
Isotope Systematics

Results of a study of U-Pb and Hf isotope systematics and trace element concentrations in five zircon crystals separated from the Devonian Petrivske kimberlite are reported in the paper. Four zircons have yielded Paleoproterozoic and Archean ages, while one zircon grain gave a Devonian age of 383.6±4.4 Ma (weighted mean 206Pb/238U age). The Precambrian zircons have been derived from terrigenous rocks of the Mykolaivka Suite that is cut by kimberlite, or directly from the Precambrian rock complexes that constitute continental crust in the East Azov. The Devonian zircon crystal has the U-Pb age that corresponds to the age of kimberlite emplacement. It is 14 m.y. younger than zircon megacrysts found in the Novolaspa kimberlite pipe in the same area. In addition, Petrivske zircon is richer in trace elements than its counterparts from the Novolaspa pipe. Petrivske and Novolaspa zircons crystallized from two different proto-kimberlite melts, whereas the process of kimberlite formation was very complex and possibly included several episodes of formation of proto-kimberlite melts, separated by extended (over 10 M.y.) periods of time.

XVII.—The Major Ultrabasic and Basic Intrusions of St Kilda, Outer Hebrides

1967 ◽  
Vol 66 (17) ◽  
pp. 419-444 ◽  
Author(s):  
R. R. Harding
Keyword(s):  
Trace Element ◽  
Major Element ◽  
Layered Intrusion ◽  
Fine Grained ◽  
Outer Hebrides ◽  
Crystal Accumulation

AbstractThe structures and mineralogy of the Tertiary ultrabasic and basic intrusions are described. The ultrabasic rocks are thought to be remnants of a layered intrusion which once extended from Hirta to Boreray, and which probably formed by crystal accumulation. The eucrites may represent higher levels of this intrusion. A 350 feet-thick, fine-grained margin is described from the East Glen Bay Gabbro. The metamorphism of the ultrabasic and eucritic rocks, and the formation of the Glacan Mor Complex, probably occurred in a basic environment, before intrusion of the first acid rocks on St. Kilda. Five major-element and twenty-two trace-element analyses are presented.

scholarly journals Parental magma composition of the Main Zone of the Bushveld Complex: Evidence from in-situ LA-ICP-MS trace element analysis of silicate minerals in the cumulate rocks

2020 ◽  
Author(s):  
Shenghong Yang ◽  
Wolfgang D. Maier ◽  
Belinda Godel ◽  
Sarah-Jane Barnes ◽  
Eero Hanski ◽  
...  
Keyword(s):  
Trace Elements ◽  
Trace Element ◽  
Bushveld Complex ◽  
Trace Element Analysis ◽  
Parental Magma ◽  
Main Zone ◽  
Element Analysis ◽  
Silicate Minerals ◽  
Incompatible Elements

<p>In-situ trace element analysis of cumulus minerals may provide a clue to the parental magma from which the minerals crystallized. However, this is hampered by effects of the trapped liquid shift (TLS). In the Main Zone (MZ) of the Bushveld Complex, the Ti content in plagioclase grains shows a clear increase from core to rim, whereas most other elements (e.g., rare earth elements (REEs), Zr, Hf, Pb) do not. This is different from the prominent intra-grain variation of all trace elements in silicate minerals in mafic dikes and smaller intrusion, which have a faster cooling rate. We suggest that crystal fractionation of trapped liquid occurred in the MZ of Bushveld and the TLS may have modified the original composition of the cumulus minerals for most trace elements except Ti during slow cooling. Quantitative model calculations suggest that the influence of the TLS depends on the bulk partition coefficient of the element. The effect on highly incompatible elements is clearly more prominent ­­than on moderately incompatible and compatible elements because of different concentration gradients between cores and rims of cumulate minerals. This is supported by the following observations in the MZ of Bushveld: 1) positive correlation between Cr, Ni and Mg# of clinopyroxene and orthopyroxene, 2) negative correlation between moderately incompatible elements (e.g., Mn and Sc in clinopyroxene and orthopyroxene, Sr, Ba, Eu in plagioclase), but 3) poor correlation between highly incompatible elements and Mg# of clinopyroxene and orthopyroxene or An# of plagioclase. Modeling suggests that the extent of the TLS for a trace element is also dependent on the initial fraction of the primary trapped liquid, with strong TLS occurring if the primary trapped liquid fraction is high. This is supported by the positive correlation between highly incompatible trace element abundances in cumulus minerals and whole-rock Zr contents.</p><p>We have calculated the composition of the parental magma of the MZ of the Bushveld Complex. The compatible and moderately incompatible element contents of the calculated parental liquid are generally similar to those of the B3 marginal rocks, but different from the B1 and B2 marginal rocks. For the highly incompatible elements, we suggest that the use of the sample with the lowest whole-rock Zr content and the least degree of TLS is the best approach to obtain the parental magma composition. Based on calculation, we propose that a B3 type liquid is the most likely parental magma to the MZ of the Bushveld Complex.</p>

Age and Geochemical Studies of the Snyder Breccia, Coastal Labrador

1975 ◽  
Vol 12 (3) ◽  
pp. 361-370 ◽  
Author(s):  
Jackson M. Barton Jr. ◽  
Erika S. Barton
Keyword(s):  
Trace Element ◽  
North Atlantic ◽  
Layered Intrusion ◽  
Basement Complex ◽  
Fine Grained ◽  
The North ◽  
Isotopic Analyses ◽  
The Matrix ◽  
The North Atlantic ◽  
Geochemical Studies

The Snyder breccia is composed of angular to subrounded xenoliths of migmatites and amphibolites in a very fine grained matrix. It is apparently intrusive into the metasediments of the Snyder Group exposed at Snyder Bay, Labrador. The Snyder Group unconformably overlies a migmatitic and amphibolitic basement complex and is intruded by the Kiglapait layered intrusion. K–Ar ages indicate that the basement complex is Archean in age (> 2600 m.y. old) and that the Kiglapait layered intrusion was emplaced prior to 1280 m.y. ago. Major and trace element analyses of the matrix of the Snyder breccia indicate that while it was originally of tonalitic composition, later it locally underwent alteration characterized by loss of sodium and strontium and gain of potassium, rubidium and barium. Rb–Sr isotopic analyses show that this alteration occurred about 1842 m.y. ago, most probably contemporaneously with emplacement of the breccia. The Snyder Group thus was deposited sometime between 2600 and 1842 m.y. ago and may be correlative with other Aphebian successions preserved on the North Atlantic Archean craton.

Mineral assemblage within secondary crystallized melt inclusions in olivine of mantle xenoliths from the Bultfontein kimberlite pipe (Kaapvaal craton, South Africa)

2021 ◽  
Author(s):  
Alexey Tarasov ◽  
Igor Sharygin ◽  
Alexander Golovin ◽  
Anna Dymshits ◽  
Dmitriy Rezvukhin
Keyword(s):  
Melt Inclusions ◽  
Basic Research ◽  
Kimberlite Pipe ◽  
Mantle Xenoliths ◽  
Mantle Minerals ◽  
Source Regions ◽  
Basic Research Grant ◽  
Carbonate Composition ◽  
First Time ◽  
Ca Carbonate

<p>For the first time, snapshots of crystallized melts in olivine of sheared garnet peridotite xenoliths from the Bultfontein kimberlite pipe have been studied. This type of xenoliths represents the deepest mantle rocks derived from the base of lithosphere (at depths from 110 to 230 km for various ancient cratons). According to different models, such type of inclusions (secondary) in mantle minerals can be interpreted as relics of the most primitive (i.e., close-to-primary) kimberlite melt that infiltrated into sheared garnet peridotites. In general, these secondary inclusions are directly related to kimberlite magmatism that finally formed the Bultfontein diamond deposits. The primary/primitive composition of kimberlite melt is poorly constrained because kimberlites are ubiquitously contaminated by xenogenic material and altered by syn/post-emplacement hydrothermal processes. Thus, the study of these inclusions helps to significantly advance in solving numerous problems related to the kimberlite petrogenesis.</p><p>The unexposed melt inclusions were studied by using a confocal Raman spectroscopy. In total, fifteen daughter minerals within the inclusions were identified by this method. Several more phases give distinct Raman spectra, but their determination is difficult due to the lack of similar spectra in the databases. Various carbonates and carbonates with additional anions, alkali sulphates, phosphates and silicates were determined among daughter minerals in the melt inclusions: calcite CaCO<sub>3</sub>, magnesite MgCO<sub>3</sub>, dolomite CaMg(CO<sub>3</sub>)<sub>2</sub>, eitelite Na<sub>2</sub>Mg(CO<sub>3</sub>)<sub>2</sub>, nyerereite (Na,K)<sub>2</sub>Ca(CO<sub>3</sub>)<sub>2</sub>, gregoryite (Na,K,Ca)<sub>2</sub>CO<sub>3</sub>, K-Na-Ca-carbonate (K,Na)<sub>2</sub>Ca(CO<sub>3</sub>)<sub>2</sub>, northupite Na<sub>3</sub>Mg(CO<sub>3</sub>)<sub>2</sub>Cl, bradleyite Na<sub>3</sub>Mg(PO<sub>4</sub>)(CO<sub>3</sub>), burkeite Na<sub>6</sub>(CO<sub>3</sub>)(SO<sub>4</sub>)<sub>2</sub>, glauberite Na<sub>2</sub>Ca(SO<sub>4</sub>)<sub>2</sub>, thenardite Na<sub>2</sub>SO<sub>4</sub>, aphthitalite K<sub>3</sub>Na(SO<sub>4</sub>)<sub>2</sub>, apatite Ca<sub>5</sub>(PO<sub>4</sub>)<sub>3</sub>(OH,Cl,F) and tetraferriphlogopite KMg<sub>3</sub>FeSi<sub>3</sub>O<sub>10</sub>(F,Cl,OH). Note that carbonates are predominant among the daughter minerals in the melt inclusions. Moreover, there are quite a lot of alkali-rich daughter minerals within the inclusions as well. During the last decade, some research groups using different approaches proposed a model of carbonate/alkali‑carbonate composition of kimberlite melts in their source regions. This model contradicts to the generally accepted ultramafic silicate nature of parental kimberlite liquids. This study is a direct support of a new model of carbonatitic composition of kimberlite melts and also shows that alkali contents in kimberlite petrogenesis are usually underestimated.</p><p>This work was supported by the Russian Foundation for Basic Research (grant No. 20-35-70058).</p>

Norito e charnoenderbitos da borda do maciço intrusivo de Venda Nova, Espírito Santo

2002 ◽  
Vol 25 ◽  
pp. 99-124
Author(s):  
Julio Cezar Mendes ◽  
Cristina Maria Wiedemann ◽  
Ian McReath
Keyword(s):  
Calc Alkaline ◽  
Espírito Santo ◽  
Fine Grained ◽  
Massive Structure ◽  
Incompatible Elements ◽  
Residual Phase ◽  
Depleted Mantle ◽  
Espirito Santo ◽  
Porphyritic Texture ◽  
Narrow Ring

An irregular and narrow ring of charnoenderbites and norite envelopes gabbros and syenomonzonites in the Venda Nova inversely zoned pluton, Espírito Santo. The former have an almost massive structure, with foliation only locally well marked. The norite is a fine-grained cumulatic rock with granular hypidiomorphic to intergranular texture. The medium-grained charnoenderbites comprise enderbites, Opx-quartzdiorites and Opx-granodiorites. They are leucocratic to mesocratic with granular hypidiomorphic to porphyritic texture. Ortho and clinopyroxene are present in the both lithotypes. Subsolidus textures occur in the norite and charnoenderbites. The whole rock chemistry separates two different sequences: a basic one, with tholeiitic affinities, correspond to the noritic cumulate, and an intermediary one, medium-K calc-alkaline, comprising the charnoenderbites. They show clearly different chemical signature when compared to the alkalic affinity rocks of the inner domain of the pluton. Both the sequences have similar geochemical characteristics: they are metaluminous, Ca, Fe and Al enriched, and have low to moderate incompatible elements contents. Normal to depleted mantle protolith is inferred for both sequences, and garnet probably was a residual phase during the mantle partial melting.

The Witwatersrand pyrites and metamorphism

1983 ◽  
Vol 47 (345) ◽  
pp. 473-479 ◽  
Author(s):  
D. K. Hallbauer ◽  
K. von Gehlen
Keyword(s):  
Trace Element ◽  
Fluid Inclusions ◽  
Depositional Environment ◽  
Volcanic Rocks ◽  
Source Rocks ◽  
Fine Grained ◽  
Mineral Inclusions ◽  
Ore Minerals ◽  
Hand Specimen

AbstractEvidence obtained from morphological and extensive trace element studies, and from the examination of mineral and fluid inclusions in Witwatersrand pyrites, shows three major types of pyrite: (i) detrital pyrite (rounded pyrite crystals transported into the depositional environment); (ii) synsedimentary pyrite (round and rounded aggregates of fine-grained pyrite formed within the depositional environmen); and (iii) authigenic pyrite (newly crystallized and/or recrystallized pyrite formed after deposition). The detrital grains contain mineral inclusions such as biotite, feldspar, apatite, zircon, sphene, and various ore minerals, and fluid inclusions with daughter minerals. Most of the inclusions are incompatible with an origin by sulphidization. Recrystallized authigenic pyrite occurs in large quantities but only in horizons or localities which have been subjected to higher temperatures during the intrusion or extrusion of younger volcanic rocks. Important additional findings are the often substantial amounts of pyrite and small amounts of particles of gold found in Archaean granites (Hallbauer, 1982) as possible source rocks for the Witwatersrand detritus. Large differences in Ag and Hg content between homogeneous single gold grains within a hand specimen indicate a lack of metamorphic homogenization. The influence of metamorphism on the Witwatersrand pyrites can therefore be described as only slight and generally negligible.

Sign in / Sign up

Export Citation Format

Share Document