Sedimentological and diagenetical conditions of the impact level of the Cretaceous/Tertiary boundary in Tunisia; no anoxia required

2000 ◽  
Vol 171 (6) ◽  
pp. 629-636 ◽  
Author(s):  
Nicolas Tribovillard ◽  
Christian Dupuis ◽  
Eric Robin

Abstract The Ain Settara section (Kalaat-Senan area, Tunisia) shows a well-exposed and expanded Cretaceous/Tertiary (K/T) boundary that can be divided into several units of contrasted lithologies. The bolide impact level is identified thanks to the occurrence of a peak of iridium and Ni-rich spinel abundance. The impact level is a jarosite nodule-rich horizon upon which the emphasis is placed: the jarosite nodules, initially present as pyrite nodules, may be interpreted as reflecting reducing depositional conditions at the K/T boundary. Trace metal geochemistry indicates that depositional conditions were not reducing and that the nodules must not have formed during earliest diagenesis. Consequently, water column-scaled anoxia cannot be put forward to account for the mass extinctions observed at the K/T boundary at Ain Settara.

1993 ◽  
Vol 28 (1) ◽  
pp. 83-110 ◽  
Author(s):  
Richard E. Farrell ◽  
Jae E. Yang ◽  
P. Ming Huang ◽  
Wen K. Liaw

Abstract Porewater samples from the upper Qu’Appelle River basin in Saskatchewan, Canada, were analyzed to obtain metal, inorganic ligand and amino add profiles. These data were used to compute the aqueous speciation of the metals in each porewater using the computer program GEOCHEM-PC. The porewaters were classified as slightly to moderately saline. Metal concentrations reflected both the geology of the drainage basin and the impact of anthropogenic activities. Whereas K and Na were present almost entirely as the free aquo ions, carbonate equilibria dominated the speciation of Ca. Mg and Mn (the predominant metal ligand species were of the type MCO3 (s). MCO30. and MHCO3+). Trace metal concentrations were generally within the ranges reported for non-polluted freshwater systems. Whereas the speciation of the trace metals Cr(III) and Co(II) was dominated by carbonate equilibria, Hg(II)-, Zn(II)- and Fe(II)-speciation was dominated by hydroxy-metal complexes of the type M(OH)+ and M(OH)2°. The speciation of Fe(III) was dominated by Fe(OH)3 (s). In porewaters with high chloride concentrations (> 2 mM), however, significant amounts of Hg(II) were bound as HgCl20 and HgClOH0. The aqueous speciation of Al was dominated by Al(OH)4− and Al2Si2O4(OH)6 (s). Total concentrations of dissolved free amino acids varied from 15.21 to 25.17 umole L−1. The most important metal scavenging amino acids were histidine (due to high stability constants for the metal-histidine complexes) and tryptophan (due to its relatively high concentration in the porewaters. i.e., 5.96 to 7.73 umole L−1). Secondary concentrations of various trace metal-amino add complexes were computed for all the porewaters, but metal-amino acid complexes dominated the speciation of Cu(II) in all the porewaters and Ni(II) in two of the porewaters.


2021 ◽  
Vol 11 (11) ◽  
pp. 4934
Author(s):  
Viola Rossano ◽  
Giuliano De Stefano

Computational fluid dynamics was employed to predict the early stages of the aerodynamic breakup of a cylindrical water column, due to the impact of a traveling plane shock wave. The unsteady Reynolds-averaged Navier–Stokes approach was used to simulate the mean turbulent flow in a virtual shock tube device. The compressible flow governing equations were solved by means of a finite volume-based numerical method, where the volume of fluid technique was employed to track the air–water interface on the fixed numerical mesh. The present computational modeling approach for industrial gas dynamics applications was verified by making a comparison with reference experimental and numerical results for the same flow configuration. The engineering analysis of the shock–column interaction was performed in the shear-stripping regime, where an acceptably accurate prediction of the interface deformation was achieved. Both column flattening and sheet shearing at the column equator were correctly reproduced, along with the water body drift.


2006 ◽  
Vol 103 (47) ◽  
pp. 17822-17827 ◽  
Author(s):  
C. L. Dupont ◽  
S. Yang ◽  
B. Palenik ◽  
P. E. Bourne

2021 ◽  
Author(s):  
Alexandra Gogou ◽  
Constantine Parinos ◽  
Spyros Stavrakakis ◽  
Emmanouil Proestakis ◽  
Maria Kanakidou ◽  
...  

<p>Biotic and abiotic processes that form, alter, transport, and remineralize particulate organic carbon, silicon, calcium carbonate, and other minor and trace chemical species in the water column are central to the ocean’s ecological and biogeochemical functioning and of fundamental importance to the ocean carbon cycle. Sinking particulate matter is the major vehicle for exporting carbon from the sea surface to the deep sea. During its transit towards the sea floor, most particulate organic carbon (POC) is returned to inorganic form and redistributed in the water column. This redistribution determines the surface concentration of dissolved CO<sub>2</sub>, and hence the rate at which the ocean can absorb CO<sub>2</sub> from the atmosphere. The ability to predict quantitatively the depth profile of remineralization is therefore critical to deciphering the response of the global carbon cycle to natural and human-induced changes.</p><p>Aiming to investigate the significant biogeochemical and ecological features and provide new insights on the sources and cycles of sinking particulate matter, a mooring line of five sediment traps was deployed from 2006 to 2015 (with some gap periods) at 5 successive water column depths (700, 1200, 2000, 3200 and 4300 m) in the SE Ionian Sea, northeastern Mediterranean (‘NESTOR’ site). We have examined the long-term records of downward fluxes for Corg, N<sub>tot</sub>, δ<sup>13</sup>Corg and δ<sup>15</sup>N<sub>tot</sub>, along with the associated ballast minerals (opal, lithogenics and CaCO<sub>3</sub>), lipid biomarkers, Chl-a and PP rates, phytoplankton composition, nutrient dynamics and atmospheric deposition.  </p><p>The satellite-derived seasonal and interannual variability of phytoplankton metrics (biomass and phenology) and atmospheric deposition (meteorology and air masses origin) was examined for the period of the sediment trap experiment. Regarding the atmospheric deposition, synergistic opportunities using Earth Observation satellite lidar and radiometer systems are proposed (e.g. Cloud‐Aerosol Lidar with Orthogonal Polarization - CALIOP, Moderate Resolution Imaging Spectroradiometer - MODIS), aiming towards a four‐dimensional exploitation of atmospheric aerosol loading (e.g. Dust Optical Depth) in the study area.</p><p>Our main goals are to: i) develop a comprehensive knowledge of carbon fluxes and associated mineral ballast fluxes from the epipelagic to the mesopelagic and bathypelagic layers, ii) elucidate the mechanisms governing marine productivity and carbon export and sequestration to depth and iii) shed light on the impact of atmospheric forcing and deposition in respect to regional and large scale circulation patterns and climate variability and the prevailing oceanographic processes (internal variability).</p><p>Acknowledgments</p><p>We acknowledge support of this work by the Action ‘National Network on Climate Change and its Impacts – <strong>CLIMPACT</strong>’, funded by the Public Investment Program of Greece (GSRT, Ministry of Development and Investments).</p>


2018 ◽  
Vol 18 (05) ◽  
pp. 440-444
Author(s):  
Noel Pérez ◽  
Jorge Luis Velazco-Vargas ◽  
Osmel Martin ◽  
Rolando Cardenas ◽  
Jesús Martínez-Frías

AbstractThe potential of a mass asteroid impact on Earth to disturb the chemosynthetic communities at global scale is discussed. Special emphasis is made on the potential influence on anammox communities and their implications in the nitrogen biogeochemical cycle. According to our preliminary estimates, anammox communities could be seriously affected as a consequence of global cooling and the large process of acidification usually associated with the occurrence of this kind of event. The scale of affectations could vary in a scenario like the Chicxulub as a function of the amount of soot, depth of the water column and the deposition rate for sulphates assumed in each case. The most severe affectations take place where the amount of soot and sulphates produced during the event is higher and the scale of time of settlements for sulphates is short, of the order of 10 h. In this extreme case, the activity of anammox is considerably reduced, a condition that may persist for several years after the impact. Furthermore, the impact of high levels of other chemical compounds like sulphates and nitrates associated with the occurrence of this kind of event are also discussed.


Author(s):  
Frances M. Judge ◽  
Eoin Lyden ◽  
Michael O'Shea ◽  
Brian Flannery ◽  
Jimmy Murphy

Abstract This research presents a methodology for carrying out uncertainty analysis on measurements made during wave basin testing of an oscillating water column wave energy converter. Values are determined for Type A and Type B uncertainty for each parameter of interest, and uncertainty is propagated using the Monte Carlo method to obtain an overall Expanded Uncertainty with a 95% confidence level associated with the Capture Width Ratio of the device. An analysis into the impact of reflections on the experimental results reveals the importance of identifying the incident and combined wave field at each measurement location used to determine device performance, in order to avoid misleading results.


SciVee ◽  
2007 ◽  
Author(s):  
Christopher Dupont ◽  
Song Yang ◽  
Brian Palenik ◽  
Philip Bourne

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