scholarly journals Characterization of quasi-solid electrolytes based on Li3PS4 glass with organic carbonate additives

2020 ◽  
Vol 128 (9) ◽  
pp. 653-655
Author(s):  
Kei SHIMAMOTO ◽  
Atsushi SAKUDA ◽  
Akitoshi HAYASHI ◽  
Masahiro TATSUMISAGO
Keyword(s):  
Solid Electrolytes ◽  
Organic Carbonate

Preparation and Characterization of Cation-Substituted Na3SbS4 Solid Electrolytes

2020 ◽  
Vol 3 (12) ◽  
pp. 11706-11712
Author(s):  
Fumika Tsuji ◽  
Naoki Masuzawa ◽  
Atsushi Sakuda ◽  
Masahiro Tatsumisago ◽  
Akitoshi Hayashi
Keyword(s):  
Solid Electrolytes

Mechanosynthesis, Radiation-Thermal Modification and Characterization of Nanostructured Scandia Stabilized Zirconia Ceramics

2008 ◽  
Vol 1122 ◽  
Author(s):  
Vladimir V. Zyryanov ◽  
Nikolay F. Uvarov ◽  
Artem S. Ulihin ◽  
Vladislav A. Sadykov
Keyword(s):  
Solid Electrolytes ◽  
Room Temperature ◽  
Complex Impedance ◽  
Impedance Method ◽  
Sintering Aids ◽  
Zirconia Ceramics ◽  
Operation Temperature ◽  
Cubic Structure ◽  
Xrd Patterns

AbstractSSZ-based ceramics were obtained by sintering of nanopowders derived at room temperature by mechanochemical synthesis from refined technical grade ZrO2 nano-precursors. RT-treatment by 2.5 MeV electrons up to 1563 K was used for the modification of ceramics. Powders and ceramics were characterized by XRD, Raman, SEM and EDS, TEM, SIMS techniques. The phase composition of Zr0.89Sc0.1Ce0.01O1.95 ceramics was very close to cubic structure but better fitting of XRD patterns was obtained for rhombohedral lattice. Conductivity of solid electrolytes for IT SOFC was studied by complex impedance method. To stabilize cubic structure and increase conductivity at operation temperature of To ∼ 1000 K, the composition of SSZ solid electrolyte was optimized by addition of yttria and sintering aids. The interaction of admixtures with minor dopants leading to intergrain phase was revealed. During fast sintering, ceramics keep a memory about inhomogeneous disordered solid solutions in a form of nanostructuring. Conductivity data indicate nanostructuring of ceramics too: activation energies of bulk and grain boundary conductivities are close (Eb ∼ 0.9 eV, Egb ∼ 1.05 eV). Annealing of ceramics at high temperatures increases conductivity at To and promotes grain growth.

Synthesis and characterization of GDC solid electrolytes obtained by solid state sintering of multilayer thin films

2011 ◽  
Vol 184 (1) ◽  
pp. 14-18 ◽  
Author(s):  
Saulius Burinskas ◽  
Vytautas Adomonis ◽  
Julius Dudonis ◽  
Giedrius Laukaitis ◽  
Virgilijus Minialga ◽  
...  
Keyword(s):  
Thin Films ◽  
Solid State ◽  
Solid Electrolytes ◽  
Synthesis And Characterization ◽  
Multilayer Thin Films ◽  
Solid State Sintering

Preparation and Characterization of Solid Electrolytes Based on TiP2O7Pyrophosphate

2015 ◽  
Vol 479 (1) ◽  
pp. 101-109 ◽  
Author(s):  
V. Venckutė ◽  
P. Dobrovolskis ◽  
T. Šalkus ◽  
A. Kežionis ◽  
A. Dindune ◽  
...  
Keyword(s):  
Solid Electrolytes

Structural properties and presence of protons in Ba0.9Gd0.1Zr1−x−ySnxInyO3−(y−0.1)∕2 perovskites

2016 ◽  
Vol 09 (04) ◽  
pp. 1641005 ◽  
Author(s):  
Wojciech Skubida ◽  
Konrad Świerczek
Keyword(s):  
Crystal Structure ◽  
High Temperature ◽  
Solid Electrolytes ◽  
Dominant Role ◽  
Spectroscopy Analysis ◽  
High Temperature Xrd ◽  
Thermogravimetric Studies ◽  
Perovskite Type ◽  
Mass Spectroscopy Analysis

In this work, structural characterization of selected perovskite-type compounds from Ba[Formula: see text]Gd[Formula: see text]Zr[Formula: see text]SnxInyO[Formula: see text] group is given, including high temperature XRD measurements. An evidence of water incorporation into the crystal structure of the materials in a form of OH[Formula: see text] is discussed on a basis of thermogravimetric studies, with mass spectroscopy analysis of the gases released from samples on heating/cooling. As expected, oxygen non-stoichiometry was found to play a dominant role concerning possibility of water uptake. In addition, a rather strong affinity of the materials towards CO2 was documented, which seems to be a problem concerning possible application of the compounds as proton conducting solid electrolytes.

Sign in / Sign up

Export Citation Format

Share Document