scholarly journals Flaming Oxidation of Reduced CeO2-ZrO2 Solid Solution in the Near-Room-Temperature Range.

2002 ◽  
Vol 110 (1286) ◽  
pp. 899-903 ◽  
Author(s):  
Tsuyoshi SASAKI ◽  
Yoshio UKYO ◽  
Akihiko SUDA ◽  
Masahiro SUGIURA ◽  
Kotaro KURODA ◽  
...  
Keyword(s):  
Solid Solution ◽  
Room Temperature ◽  
Temperature Range

scholarly journals Структура, диэлектрические и магнитодиэлектрические свойства керамики мультиферроика 0.5BiFeO-=SUB=-3-=/SUB=--0.5PbFe-=SUB=-0.5-=/SUB=-Nb-=SUB=-0.5-=/SUB=-O-=SUB=-3-=/SUB=-

2020 ◽  
Vol 62 (10) ◽  
pp. 1677
Author(s):  
А.В. Павленко ◽  
К.М. Жидель ◽  
Л.А. Шилкина
Keyword(s):  
Magnetic Field ◽  
Solid Solution ◽  
Dielectric Loss ◽  
Constant Magnetic Field ◽  
Room Temperature ◽  
Magnetoelectric Effect ◽  
Dielectric Characteristics ◽  
Temperature Range ◽  
Cubic Structure

The structure, dielectric characteristics, and magnetoelectric effect of multiferroic 0.5BiFeO3–0.5PbFe0.5Nb0.5O3 ceramics were studied. Ceramics are found to be pure. At room temperature, ceramics has a cubic structure close to а = 3.999(5) Å, which remains in the temperature range of 20–600 оС. It was shown that 0.5BiFeO3–0.5PbFe0.5Nb0.5O3 solid solution at Т < 200 оС combines both ferroelectric and antiferromagnetic properties. At room temperature in a constant magnetic field of 0.86 T, magnetodielectric coefficient and dielectric loss in the material are –0.4 % and –0.5 %, respectively.

Subsolidus data for the join Ca2SiO4—CaMgSiO4 and the stability of merwinite

1956 ◽  
Vol 31 (233) ◽  
pp. 187-194 ◽  
Author(s):  
Della M. Roy
Keyword(s):  
Solid Solution ◽  
Room Temperature ◽  
X Ray Diffraction ◽  
X Ray ◽  
Temperature Range ◽  
Infra Red ◽  
Pure Phases ◽  
The Stability ◽  
End Members ◽  
Unique Compound

SummaryA study of phase equilibria among the orthosilicates on the Ca2SiO4—CaMgSiO4 join was undertaken with the use of hydrothermal techniques in the temperature range 600–900°C. at water pressures from 1000 to 15000 psi. Monticellite, merwinite, and Ca2SiO4 crystallize as pure phases throughout this temperature range, and intermediate compositions contain mixtures of the end members. Powder X-ray diffraction data obtained on the mixtures indicate no change in lattice dimensions from the end members. Hence, very little or no solid solution is indicated at these temperatures. Ca2SiO4 was crystallized as the γ-form below 675°C. (at 2000 psi) and the β-form above this temperature (presumably having inverted from the α′-form on cooling to room temperature). Infra-red absorption spectra obtained on the compounds γ-Ca2SiO4, β-Ca2SiO4, merwinite, and monticellite show characteristic differences in the pattern within the 9–13 micron region. All the data thus appear to confirm merwinite as a unique compound stable in the temperature range studied.

scholarly journals Preparation of Li3PS4–Li3PO4 Solid Electrolytes by Liquid-Phase Shaking for All-Solid-State Batteries

2021 ◽  
Vol 2 (1) ◽  
pp. 39-48
Author(s):  
Nguyen H. H. Phuc ◽  
Takaki Maeda ◽  
Tokoharu Yamamoto ◽  
Hiroyuki Muto ◽  
Atsunori Matsuda
Keyword(s):  
Solid Solution ◽  
Solid State ◽  
Liquid Phase ◽  
Room Temperature ◽  
Reaction Medium ◽  
Magic Angle Spinning ◽  
Resonance Spectroscopy ◽  
Synthesis Methods ◽  
Magic Angle ◽  
Angle Spinning

A solid solution of a 100Li3PS4·xLi3PO4 solid electrolyte was easily prepared by liquid-phase synthesis. Instead of the conventional solid-state synthesis methods, ethyl propionate was used as the reaction medium. The initial stage of the reaction among Li2S, P2S5 and Li3PO4 was proved by ultraviolet-visible spectroscopy. The powder X-ray diffraction (XRD) results showed that the solid solution was formed up to x = 6. At x = 20, XRD peaks of Li3PO4 were detected in the prepared sample after heat treatment at 170 °C. However, the samples obtained at room temperature showed no evidence of Li3PO4 remaining for x = 20. Solid phosphorus-31 magic angle spinning nuclear magnetic resonance spectroscopy results proved the formation of a POS33− unit in the sample with x = 6. Improvements of ionic conductivity at room temperature and activation energy were obtained with the formation of the solid solution. The sample with x = 6 exhibited a better stability against Li metal than that with x = 0. The all-solid-state half-cell employing the sample with x = 6 at the positive electrode exhibited a better charge–discharge capacity than that employing the sample with x = 0.

Ethanol conversion over Ga2O3-ZrO2 solid solution: empirical evidences of the reaction pathway, the surface acid–base property, and role of isolated gallium ion

2021 ◽  
Author(s):  
Takashi Yamamoto ◽  
Akihito Kurimoto ◽  
Riona Sato ◽  
Shoki Katada ◽  
Hirotaka Mine ◽  
...  
Keyword(s):  
Solid Solution ◽  
Reaction Pathway ◽  
Ethanol Conversion ◽  
Acid Base ◽  
Base Property ◽  
Temperature Range ◽  
Acid Base Property

Ethanol conversion by Ga2O3-ZrO2 solid solution was examined in the temperature range 573–773 K, and acetone/isobutene formation was confirmed under cofeeding of H2O vapor. The reaction pathway was empirically investigated...

Temperature dependence of chlorine-35 N.Q.R. in 2,6-Dichlorophenol

1978 ◽  
Vol 31 (4) ◽  
pp. 791 ◽  
Author(s):  
R Chandramani ◽  
SP Basavaraju ◽  
N Devaraj
Keyword(s):  
Temperature Dependence ◽  
Room Temperature ◽  
Temperature Range ◽  
Temperature Coefficients ◽  
Brown's Method

Chlorine n.q.r, in 2,6-dichlorophenol has been investigated at temperatures from 77 K to room temperature. Two resonance lines due to chemically inequivalent sites have been observed throughout this temperature range. Torsional frequencies of the molecule have been calculated at temperatures from 77 to 300 K according to Bayer's theory and Brown's method. Also the temperature coefficients of the torsional frequencies have been calculated.

Microstructure and wear resistance of Cuss-toughened Cr5Si3/CrSi metal silicide alloys

2005 ◽  
Vol 20 (5) ◽  
pp. 1122-1130 ◽  
Author(s):  
Y.X. Yin ◽  
H.M. Wang
Keyword(s):  
Solid Solution ◽  
Wear Resistance ◽  
Sliding Wear ◽  
Room Temperature ◽  
Wear Test ◽  
Melting Process ◽  
Dry Sliding Wear ◽  
Metal Silicide ◽  
X Ray Diffraction ◽  
X Ray

Wear-resistant Cu-based solid-solution-toughened Cr5Si3/CrSi metal silicide alloy with a microstructure consisting of predominantly the dual-phase primary dendrites with a Cr5Si3 core encapsulated by CrSi phase and a small amount of interdendritic Cu-based solid solution (Cuss) was designed and fabricated by the laser melting process using Cr–Si–Cu elemental powder blends as the precursor materials. The microstructure of the Cuss-toughened Cr5Si3/CrSi metal silicide alloy was characterized by optical microscopy, powder x-ray diffraction, and energy dispersive spectroscopy. The Cuss-toughened silicide alloys have excellent wear resistance and low coefficient of friction under room temperature dry sliding wear test conditions with hardened 0.45% C carbon steel as the sliding–mating counterpart.

scholarly journals PSEUDO-GAP FEATURES OF INTRINSIC TUNNELING IN (HgBr2)-Bi2212 SINGLE CRYSTALS

1999 ◽  
Vol 13 (29n31) ◽  
pp. 3758-3763 ◽  
Author(s):  
AUGUST YURGENS ◽  
DAG WINKLER ◽  
TORD CLAESON ◽  
SEONG-JU HWANG ◽  
JIN-HO CHOY
Keyword(s):  
Temperature Dependence ◽  
Single Crystals ◽  
Room Temperature ◽  
Unit Cell ◽  
Superconducting Gap ◽  
Axis Direction ◽  
Temperature Range ◽  
Dynamic Conductance

The c-axis tunneling properties of both pristine Bi2212 and its HgBr 2 intercalate have been measured in the temperature range 4.2-250 K. Lithographically patterned 7-10 unit-cell heigh mesa structures on the surfaces of these single crystals were investigated. Clear SIS-like tunneling curves for current applied in the c-axis direction have been observed. The dynamic conductance d I/ d V(V) shows both sharp peaks corresponding to a superconducting gap edge and a dip feature beyond the gap, followed by a wide maximum, which persists up to a room temperature. Shape of the temperature dependence of the c-axis resistance does not change after the intercalation suggesting that a coupling between CuO 2-bilayers has little effect on the pseudogap.

NQR and Crystal Structure of 4,5-Dichloroimidazole, C3H2N2Cl2

1992 ◽  
Vol 47 (1-2) ◽  
pp. 177-181 ◽  
Author(s):  
Shi-Qi Dou ◽  
Alarich Weiss
Keyword(s):  
Crystal Structure ◽  
Phase Transition ◽  
Temperature Dependence ◽  
Room Temperature ◽  
Unit Cell ◽  
Space Group ◽  
Temperature Range ◽  
Temperature Coefficients ◽  
Group D

AbstractThe two line 35Cl NQR spectrum of 4,5-dichloroimidazole was measured in the temperature range 77≦ T/K ≦ 389. The temperature dependence of the NQR frequencies conforms with the Bayer model and no phase transition is indicated in the curves v ( 35Cl)= f(T). Also the temperature coefficients of the 35Cl NQR frequencies are "normal". At 77 K the 35Cl NQR frequencies are 37.409 MHz and 36.172 MHz and at 389 K 35.758 MHz and 34.565 MHz. The compound crystallizes at room temperature with the tetragonal space group D44-P41212, Z = 8 molecules per unit cell; at 295 K : a = 684.2(5) pm, c = 2414.0(20) pm. The relations between the crystal structure and the NQR spectrum are discussed.

Gold nanoresistors with near-constant resistivity in the cryogenic-to-room temperature range

2011 ◽  
Vol 110 (2) ◽  
pp. 023303 ◽  
Author(s):  
M. M. A. Yajadda ◽  
I. Levchenko ◽  
K. Ostrikov
Keyword(s):  
Room Temperature ◽  
Temperature Range
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