scholarly journals Castor-Bean Extract as an Inhibitor for Low Carbon Steel Corrosion in Simulated Oilfield Produced Water

2021 ◽  
pp. ArticleID:21083
Author(s):  
Ming Xie ◽  
MRS Advances ◽  
2017 ◽  
Vol 2 (62) ◽  
pp. 3909-3915
Author(s):  
Héctor M. Barbosa Cásarez ◽  
Araceli Espinoza Vázquez ◽  
Francisco J. Rodríguez-Gomez

AbstractPhenylcoumarin glucoside (4-PC) is a compound extracted from the plant Hintona latiflora and was studied as inhibitor for AISI 1018 steel corrosion in 3% NaCl solution using potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) techniques, which may find application as eco-friendly corrosion inhibitors. The 4-PC provides inhibitor properties that protect AISI 1018 low carbon steel against corrosion at low concentrations (5 ppm) obtained by EIS. Polarization studies showed that the inhibitor was of mixed type. The inhibition efficiency by the two electrochemical techniques shows similar results. The inhibitor adsorption was demonstrated to be a combined process (physisorption and chemisorption) according to the Langmuir isotherm.


Author(s):  
Ya.G. Avdeev ◽  
◽  
A.V. Panova ◽  
T.E. Andreeva ◽  
Yu.I. Kuznetsov ◽  
...  

Corrosion of 08PS low-carbon steel was studied in a wide temperature range t = 25—100 °C in 1 M H2SO4 + 1 M H3PO4, 2 M H2SO4 и 2 M H3PO4, inhibited by the binary mixture IFKhAN-92 + KNCS (a molar ratio of components 9:1) and a three-component mixture IFKhAN-92 + KNCS + urotropine (9:1:400), in the presence of high concentrations of Fe(III) and Fe(II) salts, as well as in their joint presence. It is shown that under experimental conditions the corrosion inhibitors under study provide effective protection of steel in 1 M H2SO4 + 1 M H3PO4 even in the presence of Fe(III), Fe(II) salts or their mixtures. The highest protective effects are provided by a three-component inhibitor mixture. Under similar conditions in individual 2 M H3PO4 and, especially, 2 M H2SO4, the protective effects of inhibitors are lower. A stronger deceleration of steel corrosion by composite inhibitors based on IFKhAN-92 in H2SO4 + H3PO4 solutions containing Fe(III) salts in comparison with similar solutions of individual H2SO4, is largely due to the binding of Fe(III) cations by phosphate anions into complexes, that significantly reduces their chemical activity and, as a result the corrosion rate of steel.


2019 ◽  
Vol 3 (1) ◽  
pp. 263-276 ◽  
Author(s):  
Hameed B. Mahood ◽  
Asaad H. Sayer ◽  
Athraa H. Mekky ◽  
Anees A. Khadom

2018 ◽  
Vol 9 (3) ◽  
pp. 238-249 ◽  
Author(s):  
Ill-Min Chung ◽  
Venkatesan Hemapriya ◽  
Kanchana Ponnusamy ◽  
Natarajan Arunadevi ◽  
Subramanian Chitra ◽  
...  

2019 ◽  
Vol 27 (06) ◽  
pp. 1950154 ◽  
Author(s):  
ILL-MIN CHUNG ◽  
VENKATESAN HEMAPRIYA ◽  
PONNUSAMY KANCHANA ◽  
NATARAJAN ARUNADEVI ◽  
SUBRAMANIAN CHITRA ◽  
...  

Eco-friendly biodegradable Rhododendron schlippenbachii (R. schlippenbachii) green inhibitors, R. schlippenbachii methanolic (RSMeOH) extract, which can effectively reduce low carbon steel corrosion rate, were investigated using weight-loss and electrochemical (electrochemical impedance spectroscopy) techniques. The inhibitors exhibited higher efficiency by retarding the corrosion process in 1[Formula: see text]M H2SO4 and the inhibition efficiency is found to be concentration dependent. The reactivity of the predominant phytochemical components of the extract are analyzed. The adsorption of inhibitors on low carbon steel is followed the Langmuir adsorption. The protective inhibitor film formed on the metal surface was confirmed by SEM and AFM techniques.


2021 ◽  
Vol 1046 ◽  
pp. 143-150
Author(s):  
Roland Tolulope Loto

Application of sustainable chemical compounds for corrosion protection of carbon steels employed in H2O formed petrochemical drilling fluid environment (WPDF) is an effective alternative to toxic chemical compounds. The protection performance of calciofon (CF) and rosmarinus officinalis (RS) on low carbon steel (LST) in WPDF was studied with potentiodynamic polarization technique and optical microscopic characterization. Results output depict CF and RS performed adequately at specific inhibitor concentrations with average inhibition performance above 80% for CG and 90% for RS. CG exhibited mixed type inhibition effect compared to RS which exhibited anodic inhibition. The polarization curves obtained in the presence of both compounds showed they induce passivation of LST surface after anodic polarization before breakdown at the transpassive region from the lowest to highest concentration inhibitor concentrations due to their film forming and adsorption characteristics. This observation was corroborated from the protected steel surfaces which contrasts the non-protected control steel specimen which exhibited severe surface deterioration, corrosion pits and numerous furrows.


2019 ◽  
Vol 26 (10) ◽  
pp. 1950066 ◽  
Author(s):  
VENKATESAN HEMAPRIYA ◽  
ILL-MIN CHUNG ◽  
KANDASAMY PARAMESWARI ◽  
SUBRAMANIAN CHITRA ◽  
SEUNG-HYUN KIM ◽  
...  

The inhibitive performance of 2-[(5-phenyl-1,3,4-oxdiazol-2-yl)methyl]-2H-benzo[b] [1,4] thiazin-3-one (POBT) for low carbon steel corrosion in 1 M H2SO4 has been evaluated by non-electrochrmical, and electrochemical measurements. Efficiency of the inhibitor enhanced with inhibitor concentration and declined with rise in temperature. 92.39% inhibition efficiency was attained using 0.1[Formula: see text]mM of POBT. Anticorrosive effect of the inhibitor is owing to the adsorption of POBT molecules on the metal surface. Mono layer adsorption of inhibitor was favored by observing the best fit with Langmuir isotherm. Polarization measurements reveal that the inhibitor behaves as mixed type. Surface analysis by scanning electron microscopy (SEM) and energy dispersive X-ray spectrometry (EDX) confirm the existence of a protective film of POBT on low carbon steel surface. Quantum chemical parameters obtained using density functional theory (DFT) method complements the above results.


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