scholarly journals Effect of Electroplating Bath Composition on Corrosion Resistance of Deposited Cobalt Films

2020 ◽  
pp. 11137-11149
Author(s):  
Li Jiang ◽  
Keyword(s):  
Corrosion Resistance ◽  
Bath Composition ◽  
Cobalt Films

scholarly journals Electrodeposition of Copper and Brass Coatings with Olive-Like Structure

Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1762
Author(s):  
Artur Maciej ◽  
Natalia Łatanik ◽  
Maciej Sowa ◽  
Izabela Matuła ◽  
Wojciech Simka
Keyword(s):  
Corrosion Resistance ◽  
Cathodic Current Density ◽  
Bath Composition ◽  
Cathodic Current ◽  
Corrosion Properties ◽  
Fine Grained ◽  
Electrodeposited Coating ◽  
Copper Zinc ◽  
New Generation ◽  
First Time

One method of creating a brass coating is through electrodeposition, which is most often completed in cyanide galvanic baths. Due to their toxicity, many investigations focused on the development of more environmentally friendly alternatives. The purpose of the study was to explore a new generation of non-aqueous cyanide-free baths based on 1-ethyl-3-methylimidazolium acetate ionic liquids. The study involved the formation of copper, zinc, and brass coatings. The influence of the bath composition, cathodic current density, and temperature was determined. The obtained coatings were characterized in terms of their morphology, chemical composition, phase composition, roughness, and corrosion resistance. It was found that the structure of the obtained coatings is strongly dependent on the process parameters. The three main structure types observed were as follows: fine-grained, porous, and olive-like. To the best knowledge of the authors, it is the first time the olive-like structure was observed in the case of an electrodeposited coating. The Cu-Zn coatings consisted of 19–96 at. % copper and exhibited relatively good corrosion resistance. A significant improvement of corrosion properties was found in the case of copper and brass coatings with the olive-like structure.

EIS Study of Molybdate Conversion Coatings Formed on AZ91D Magnesium Alloy

2011 ◽  
Vol 189-193 ◽  
pp. 279-285
Author(s):  
Li Ping Wu ◽  
Zhong Dong Yang
Keyword(s):  
Corrosion Resistance ◽  
Charge Transfer ◽  
Magnesium Alloy ◽  
Charge Transfer Resistance ◽  
Conversion Coating ◽  
Conversion Coatings ◽  
Bath Composition ◽  
Optimum Conditions ◽  
Transfer Resistance ◽  
Az91d Magnesium Alloy

An environmentally friendly molybdate conversion coating based surface treatment was developed for AZ91D magnesium alloy. The EIS technique was employed to study the effects of the conversion bath composition and temperature on the corrosion protection performance of molybdate conversion coatings on AZ91D magnesium alloys. The optimum conditions under which obtained conversion coatings showed the best corrosion resistance were determined. The Nyquist results showed that the value of charge transfer resistance increased by 22.5 times for the sample treated in the optimized molybdate conversion bath.

Electroless Ni-Co-P Coatings on Sintered Nd-Fe-B Magnets with Improved Corrosion Resistance

2009 ◽  
Vol 75 ◽  
pp. 53-56 ◽  
Author(s):  
Tian Yu Ma ◽  
Hua Gen Ying ◽  
Mi Yan
Keyword(s):  
Magnetic Properties ◽  
Corrosion Resistance ◽  
Corrosion Current Density ◽  
Permanent Magnets ◽  
Corrosion Current ◽  
Operating Conditions ◽  
Slight Reduction ◽  
Bath Composition ◽  
Nacl Solution ◽  
Electroless Ni

Electroless Ni-Co-P coatings have been deposited on sintered Nd-Fe-B permanent magnets by optimizing the bath composition and operating conditions. The corrosion resistance of coated Nd-Fe-B magnets was significantly improved and corresponding corrosion current density Icorr in 3.5 wt. % NaCl solution decreased by two orders of magnitude. Coated with 12μm-thick Ni-Co-P, Nd-Fe-B magnets possessed slight reduction in magnetic properties, with a modest loss of remanence (Br) by 3.9 % and coercivity (iHC) by 4.5 %.

scholarly journals Electrodeposition of Copper and Brass Coatings with Olive-like Structure

2021 ◽  
Author(s):  
Artur Maciej ◽  
Natalia Łatanik ◽  
Maciej Sowa ◽  
Wojciech Simka
Keyword(s):  
Corrosion Resistance ◽  
Cathodic Current Density ◽  
Bath Composition ◽  
Cathodic Current ◽  
Corrosion Properties ◽  
Fine Grained ◽  
Electrodeposited Coating ◽  
Copper Zinc ◽  
New Generation ◽  
First Time

One method of creating a brass coating is through electrodeposition, which is most often completed in cyanide galvanic baths. Because of the toxicity of cyanides, many are working on the development of cyanide-free baths, which are promising but not satisfactory to replace the classic methods. The purpose of the study was to explore a new generation of non-aqueous cyanide-free baths based on 1-ethyl-3-methylimidazolium acetate ionic liquids. The study involved the formation of copper, zinc, and brass coatings. The influence of the bath composition, cathodic current density, and temperature was determined. The obtained coatings were characterized by their morphology, chemical composition, roughness, and corrosion resistance. It was found that the structure of the obtained coatings is strongly dependent on the process parameters. The three main structures observed were fine-grained, porous, and olive-like. To the best knowledge of the authors, it is the first time the olive-like structure was observed in the case of an electrodeposited coating. The Cu-Zn coatings consisted of 19–96 at.% copper and exhibited relatively strong corrosion resistance. High improvement of corrosion properties was found in the case of copper and brass coatings with an olive-like structure.

Microstructures of Ti-1.5 w/o Ni Alloys with Mo and A1 Additions

1975 ◽  
Vol 33 ◽  
pp. 54-55
Author(s):  
Anna C. Fraker
Keyword(s):  
Corrosion Resistance ◽  
Beneficial Effect ◽  
Crevice Corrosion ◽  
Local Corrosion ◽  
Precipitate Size ◽  
Ni Alloys

Small amounts of nickel are added to titanium to improve the crevice corrosion resistance but this results in an alloy which has sheet fabrication difficulties and is subject to the formation of large Ti2Ni precipitates. These large precipitates can serve as local corrosion sites; but in a smaller more widely dispersed form, they can have a beneficial effect on crevice corrosion resistance. The purpose of the present work is to show that the addition of a small amount of Mo to the Ti-1.5Ni alloy reduces the Ti2Ni precipitate size and produces a more elongated grained microstructure. It has recently been reported that small additions of Mo to Ti-0.8 to lw/o Ni alloys produce good crevice corrosion resistance and improved fabrication properties.

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