scholarly journals Hierarchically Flower-Like Cobalt Oxide@Doped-Sn Carbon Nanofiber with Core-Shell structure as Anodes for Lithium Ion Battery

Author(s):  
Hong Wang ◽  
e-Polymers ◽  
2020 ◽  
Vol 20 (1) ◽  
pp. 491-499 ◽  
Author(s):  
Fan Wang ◽  
Shouzhi Zhang ◽  
Jiawei Zhang ◽  
Manshu Han ◽  
Guoxiang Pan ◽  
...  

AbstractFlexible energy devices with high energy density and long cycle life are considered to be promising applications in portable electronics. In this study, silicon/carbon nanofiber (Si@CNF) core–shell electrode has been prepared by the coaxial electrospinning method. The precursors of polyimide (PI) were for the first time used to form the core–shell structure of Si@CNF, which depicts outstanding flexibility and mechanical strength. The effect of doping concentrations of silicon (Si) nanoparticles embedded in the fiber is investigated as a binder-free anode for lithium-ion batteries. A 15 wt% doped composite electrode demonstrates superior performance, with an initial reversible capacity of 621 mA h g−1 at the current density of 100 mA g−1 and a high capacity retention up to 200 cycles. The excellent cycling performance is mainly due to the carbonized PI core–shell structure, which not only can compensate for the insulation property of Si but also has the ability to buffer the volume expansion during the repeated charge–discharge process.


2015 ◽  
Vol 176 ◽  
pp. 689-693 ◽  
Author(s):  
Yang Liu ◽  
Min Zhang ◽  
Ying Li ◽  
Yemin Hu ◽  
Mingyuan Zhu ◽  
...  

Carbon ◽  
2016 ◽  
Vol 98 ◽  
pp. 582-591 ◽  
Author(s):  
Junxiong Wu ◽  
Xianying Qin ◽  
Cui Miao ◽  
Yan-Bing He ◽  
Gemeng Liang ◽  
...  

Nanoscale ◽  
2018 ◽  
Vol 10 (16) ◽  
pp. 7343-7351 ◽  
Author(s):  
Dongheun Kim ◽  
Nan Li ◽  
Chris J. Sheehan ◽  
Jinkyoung Yoo

The charging rate-dependent degradation of lithium ion battery anodes based on Si/Ge core/shell nanowire heterostructure was observed. Si/Ge core/shell structure was preserved at the charging rate of 0.8 A g−1. On the other hand, compositional intermixing and loss of Si occurs at the charging rate of 20 A g−1.


Silicon ◽  
2017 ◽  
Vol 10 (4) ◽  
pp. 1443-1450 ◽  
Author(s):  
Xiaoqiao Hu ◽  
Shimin Huang ◽  
Xianhua Hou ◽  
Hedong Chen ◽  
Haiqing Qin ◽  
...  

RSC Advances ◽  
2018 ◽  
Vol 8 (17) ◽  
pp. 9094-9102 ◽  
Author(s):  
Pengfei Wu ◽  
Changqing Guo ◽  
Jiangtao Han ◽  
Kairui Yu ◽  
Xichao Dong ◽  
...  

Double core shell structure can not only improve the efficiency of lithium transport, but also effectively alleviate volume expansion.


2014 ◽  
Vol 2 (36) ◽  
pp. 15094-15101 ◽  
Author(s):  
Nguyen Trung Hieu ◽  
Jungdon Suk ◽  
Dong Wook Kim ◽  
Jun Seo Park ◽  
Yongku Kang

Core–shell Si–CNT@C nanofibers as anodes in LIBs can minimize the volume change and improve the conductivity, enhancing the battery performance.


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