scholarly journals Development of Polymer-based Chemical Sensor to Study the Impact of Polymer Concentration and Freeze-Thaw Cycle on the Detection of Gallic Acid

2020 ◽  
pp. 2307-2325 ◽  
Author(s):  
Sundus Khan ◽  
Keyword(s):  
Gallic Acid ◽  
Chemical Sensor ◽  
Polymer Concentration ◽  
Freeze Thaw ◽  
Thaw Cycle ◽  
Freeze Thaw Cycle ◽  
The Impact

scholarly journals USING SMOS PASSIVE MICROWAVE DATA TO DEVELOP SMAP FREEZE/THAW ALGORITHMS ADAPTED FOR THE CANADIAN SUBARCTIC

2015 ◽  
Vol XL-1-W5 ◽  
pp. 365-368 ◽  
Author(s):  
P. Kalantari ◽  
M. Bernier ◽  
K. C. McDonal ◽  
J. Poulin
Keyword(s):  
Land Cover ◽  
Time Series Data ◽  
Passive Microwave ◽  
Soil Freezing ◽  
Series Data ◽  
Freezing And Thawing ◽  
Freeze Thaw ◽  
Thaw Cycle ◽  
Freeze Thaw Cycle ◽  
The Impact

Seasonal terrestrial Freeze/Thaw cycle in Northern Quebec Tundra (Nunavik) was determined and evaluated with passive microwave observations. SMOS time series data were analyzed to examine seasonal variations of soil freezing, and to assess the impact of land cover on the Freeze/Thaw cycle. Furthermore, the soil freezing maps derived from SMOS observations were compared to field survey data in the region near Umiujaq. The objective is to develop algorithms to follow the seasonal cycle of freezing and thawing of the soil adapted to Canadian subarctic, a territory with a high complexity of land cover (vegetation, soil, and water bodies). Field data shows that soil freezing and thawing dates vary much spatially at the local scale in the Boreal Forest and the Tundra. The results showed a satisfactory pixel by pixel mapping for the daily soil state monitoring with a > 80% success rate with in situ data for the HH and VV polarizations, and for different land cover. The average accuracies are 80% and 84% for the soil freeze period, and soil thaw period respectively. The comparison is limited because of the small number of validation pixels.

scholarly journals The importance of freeze/thaw cycles on lateral tracer transport in ice-wedge polygons

2021 ◽  
Author(s):  
Elchin Jafarov ◽  
Daniil Svyatsky ◽  
Dylan Harp ◽  
Brent Newman ◽  
David Moulton ◽  
...  
Keyword(s):  
Climate Models ◽  
Lateral Flow ◽  
The Arctic ◽  
Tracer Transport ◽  
Lateral Transport ◽  
Dissolved Carbon ◽  
Freeze Thaw ◽  
Thaw Cycle ◽  
Freeze Thaw Cycle ◽  
The Impact

Abstract. A significant portion of the Arctic coastal plain is classified as polygonal tundra and plays a vital role in soil carbon cycling. Recent research suggests that lateral transport of dissolved carbon could exceed vertical carbon releases to the atmosphere. However, the details of lateral subsurface flow in polygonal tundra have not been well studied. We incorporated a subsurface transport process into an existing state-of-art hydrothermal model. The model captures the physical effects of freeze/thaw cycles on lateral flow in polygonal tundra. The new modeling capability enables non-reactive tracer movement within subsurface. We utilized this new capability to investigate the impact of freeze/thaw cycle on lateral flow in the polygon polygonal tundra. Our study indicates the important role of freeze/thaw cycle and freeze-up effect on lateral tracer transport, suggesting that dissolved species could be transported from the middle of the polygon to the sides within a couple of thaw seasons. Introducing carbon lateral transport in the climate models could substantially reduce the uncertainty associated with the impact of thawing permafrost.

scholarly journals Numerical Simulation of the Effect of Freeze–Thaw Cycles on the Durability of Concrete in a Salt Frost Environment

Coatings ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1198
Author(s):  
Hao Li ◽  
Yuan Zhang ◽  
Haolong Guo
Keyword(s):  
Numerical Simulation ◽  
Bending Moment ◽  
Temperature Curve ◽  
Concrete Durability ◽  
Freezing And Thawing ◽  
Freeze Thaw ◽  
Thaw Cycle ◽  
Freeze Thaw Cycle ◽  
The Impact ◽  
Erosion Environment

In order to improve the accuracy of the analysis of the impact of freeze–thaw cycle on concrete durability in a salt freezing environment, the numerical simulation of the impact of the freeze–thaw cycle on concrete durability in a salt freezing erosion environment is studied in this paper. Firstly, considering the influence of axial force and bending moment on the relationship between bending moment and curvature, a concrete fiber beam column model is established. Then, according to the joint influence of temperature field, stress field and seepage field on concrete in the process of freezing and thawing, the control differential equation of the freezing and thawing cycle is established. The freeze–thaw damage section is divided, the non-uniform distribution of freeze–thaw damage is determined, and the division of the freeze–thaw damage section is completed. According to the linear relationship between freeze–thaw damage degree, relative dynamic elastic modulus, freeze–thaw cycle times and position variables, the durability of concrete is numerically simulated, and the attenuation law of bond strength at different section depths after freeze–thaw is determined. The results show that the temperature curve simulated by the design method is consistent with the actually measured temperature curve, which can better reduce the temperature change of the inner core of the test block during freezing and thawing, and the relative dynamic elastic modulus is in good agreement with the actual value, which can prove that the method in this paper has certain practical application value. It is expected to provide some reference for solving the durability problem of concrete in a salt frost erosion environment and the optimal design of concrete structures.

scholarly journals Breast Cancer Cryoablation: Assessment of the Impact of Fundamental Procedural Variables in an In Vitro Human Breast Cancer Model

2020 ◽  
Vol 14 ◽  
pp. 117822342097236
Author(s):  
Kristi K Snyder ◽  
Robert G Van Buskirk ◽  
John G Baust ◽  
John M Baust
Keyword(s):  
Breast Cancer ◽  
Cell Death ◽  
Human Breast Cancer ◽  
Human Breast ◽  
Freeze Thaw ◽  
Thaw Cycle ◽  
Freeze Thaw Cycle ◽  
The Impact ◽  
Mcf 7

Introduction: Breast cancer is the most prominent form of cancer and the second leading cause of death in women behind lung cancer. The primary modes of treatment today include surgical excision (lumpectomy, mastectomy), radiation, chemoablation, anti-HER2/neu therapy, and/or hormone therapy. The severe side effects associated with these therapies suggest a minimally invasive therapy with fewer quality of life issues would be advantageous for treatment of this pervasive disease. Cryoablation has been used in the treatment of other cancers, including prostate, skin, and cervical, for decades and has been shown to be a successful minimally invasive therapeutic option. To this end, the use of cryotherapy for the treatment of breast cancer has increased over the last several years. Although successful, one of the challenges in cryoablation is management of cancer destruction in the periphery of the ice ball as the tissue within this outer margin may not experience ablative temperatures. In breast cancer, this is of concern due to the lobular nature of the tumors. As such, in this study, we investigated the level of cell death at various temperatures associated with the margin of a cryogenic lesion as well as the impact of repetitive freezing and thawing methods on overall efficacy. Methods: Human breast cancer cells, MCF-7, were exposed to temperatures of −5°C, −10°C, −15°C, −20°C, or −25°C for 5-minute freeze intervals in a single or repeat freeze-thaw cycle. Samples were thawed with either passive or active warming for 5 or 10 minutes. Samples were assessed at 1, 2, and 3 days post-freeze to assess cell survival and recovery. In addition, the modes of cell death associated with freezing were assessed over the initial 24-hour post-thaw recovery period. Results: Exposure of MCF-7 cells to −5°C and −10°C resulted in minimal cell death regardless of the freeze/thaw conditions. Freezing to a temperature of −25°C resulted in complete cell death 1 day post-thaw with no cell recovery in all freeze/thaw scenarios evaluated. Exposure to a single freeze event resulted in a gradual increase in cell death at −15°C and −20°C. Application of a repeat freeze-thaw cycle (dual 5-minute freeze) resulted in an increase in cell death with complete destruction at −20°C and near complete death at −15°C (day 1 survival: single −15°C freeze/thaw = 20%; repeated −15°C freeze/thaw = 4%). Analysis of thaw interval time (5 vs 10 minute) demonstrated that the shorter 5-minute thaw interval between freezes resulted in increased cell destruction. Furthermore, investigation of thaw rate (active vs passive thawing) demonstrated that active thawing resulted in increased cell survival thereby less effective ablation compared with passive thawing (eg, −15°C 5/10/5 procedure survival, passive thaw: 4% vs active thaw: 29%). Conclusions: In summary, these in vitro findings suggest that freezing to temperatures of 25°C results in a high degree of breast cancer cell destruction. Furthermore, the data demonstrate that the application of a repeat freeze procedure with a passive 5-minute or 10-minute thaw interval between freeze cycles increases the minimal lethal temperature to the −15°C to −20°C range. The data also demonstrate that the use of an active thawing procedure between freezes reduces ablation efficacy at temperatures associated with the iceball periphery. These findings may be important to improving future clinical applications of cryoablation for the treatment of breast cancer.

Analysis of Coarse Saline Soil Salt Expansion Characteristics with Different Freeze-Thaw Cycle

2013 ◽  
Vol 671-674 ◽  
pp. 1169-1173
Author(s):  
Qiu Mei Zhang ◽  
Jin Tao Tang ◽  
Xiao Hua Yang
Keyword(s):  
Saline Soil ◽  
Engineering Properties ◽  
Overburden Pressure ◽  
Highway Projects ◽  
Temperature Changes ◽  
Freeze Thaw ◽  
Thaw Cycle ◽  
Freeze Thaw Cycle ◽  
The Impact ◽  
Soil Area

Salt expansion deformation of the saline soil is a common form of the roadbed disease in Saline Soil Area. Salt expansion of saline soil refers to volume expansion by the impact of periodic climate changes in nature. Particle distribution characteristics, compaction characteristics, salt composition and salinity and so on are studied to evaluate the basic engineering properties of saline soil in the location of the project. Seven freeze-thaw cycles test and (no) load single-cooling test are designed to clarify the relation between salt expansion and temperature changes, moisture content, overburden pressure. The results provide design and construction experiences for high-grade highway projects in natural coarse saline soil area.

scholarly journals Effect of freeze–thaw cycle on physical and mechanical properties and damage characteristics of sandstone

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Longxiao Chen ◽  
Kesheng Li ◽  
Guilei Song ◽  
Deng Zhang ◽  
Chuanxiao Liu
Keyword(s):  
Mechanical Properties ◽  
Shear Failure ◽  
Triaxial Compression ◽  
Physical And Mechanical Properties ◽  
Freeze Thaw ◽  
Damage Characteristics ◽  
Large Pore ◽  
Natural Rock ◽  
Thaw Cycle ◽  
Freeze Thaw Cycle

AbstractRock deterioration under freeze–thaw cycles is a concern for in-service tunnel in cold regions. Previous studies focused on the change of rock mechanical properties under unidirectional stress, but the natural rock mass is under three dimensional stresses. This paper investigates influences of the number of freeze–thaw cycle on sandstone under low confining pressure. Twelve sandstone samples were tested subjected to triaxial compression. Additionally, the damage characteristics of sandstone internal microstructure were obtained by using acoustic emission (AE) and mercury intrusion porosimetry. Results indicated that the mechanical properties of sandstone were significantly reduced by freeze–thaw effect. Sandstone’ peak strength and elastic modulus were 7.28–37.96% and 6.38–40.87% less than for the control, respectively. The proportion of super-large pore and large pore in sandstone increased by 19.53–81.19%. We attributed the reduced sandstone’ mechanical properties to the degenerated sandstone microstructure, which, in turn, was associated with increased sandstone macropores. The macroscopic failure pattern of sandstone changed from splitting failure to shear failure with an increasing of freeze–thaw cycles. Moreover, the activity of AE signal increased at each stage, and the cumulative ringing count also showed upward trend with the increase of freeze–thaw number.

Non-linear creep damage model of sandstone under freeze-thaw cycle

2021 ◽  
Vol 28 (3) ◽  
pp. 954-967
Author(s):  
Jie-lin Li ◽  
Long-yin Zhu ◽  
Ke-ping Zhou ◽  
Hui Chen ◽  
Le Gao ◽  
...  
Keyword(s):  
Damage Model ◽  
Creep Damage ◽  
Freeze Thaw ◽  
Thaw Cycle ◽  
Linear Creep ◽  
Non Linear ◽  
Freeze Thaw Cycle ◽  
Creep Damage Model

scholarly journals Strength and Microscopic Damage Mechanism of Yellow Sandstone with Holes under Freezing and Thawing

2020 ◽  
Vol 2020 ◽  
pp. 1-13 ◽  
Author(s):  
Huren Rong ◽  
Jingyu Gu ◽  
Miren Rong ◽  
Hong Liu ◽  
Jiayao Zhang ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Pore Size ◽  
Power Function ◽  
Damage Mechanism ◽  
Uniaxial Compression Test ◽  
Freezing And Thawing ◽  
Freeze Thaw ◽  
Thaw Cycle ◽  
Freeze Thaw Cycle ◽  
Microscopic Damage

In order to study the damage characteristics of the yellow sandstone containing pores under the freeze-thaw cycle, the uniaxial compression test of saturated water-stained yellow sandstones with different freeze-thaw cycles was carried out by rock servo press, the microstructure was qualitatively analyzed by Zeiss 508 stereo microscope, and the microdamage mechanism was quantitatively studied by using specific surface area and pore size analyzer. The mechanism of weakening mechanical properties of single-hole yellow sandstone was expounded from the perspective of microstructure. The results show the following. (1) The number of freeze-thaw cycles and single-pore diameter have significant effects on the strength and elastic modulus of the yellow sandstone; the more the freeze-thaw cycles and the larger the pore size, the lower the strength of the yellow sandstone. (2) The damage modes of the yellow sandstone containing pores under the freeze-thaw cycle are divided into five types, and the yellow sandstone with pores is divided into two areas: the periphery of the hole and the distance from the hole; as the number of freeze-thaw cycles increases, different regions show different microscopic damage patterns. (3) The damage degree of yellow sandstone is different with freeze-thaw cycle and pore size. Freeze-thaw not only affects the mechanical properties of yellow sandstone but also accelerates the damage process of pores. (4) The damage of the yellow sandstone by freeze-thaw is logarithmic function, and the damage of the yellow sandstone is a power function. The damage equation of the yellow sandstone with pores under the freezing and thawing is a log-power function nonlinear change law and presents a good correlation.

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