scholarly journals Excellent Lithium Metal Anode Performance via In Situ Interfacial Layer Induced by Li6.75La3Zr1.75Ta0.25O12@Amorphous Li3OCl Composite Solid Electrolyte

2019 ◽  
pp. 4781-4798 ◽  
Author(s):  
Yijun Tian ◽  
Keyword(s):  
Solid Electrolyte ◽  
Interfacial Layer ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Composite Solid Electrolyte ◽  
Composite Solid

scholarly journals Artificial dual solid-electrolyte interfaces based on in situ organothiol transformation in lithium sulfur battery

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Wei Guo ◽  
Wanying Zhang ◽  
Yubing Si ◽  
Donghai Wang ◽  
Yongzhu Fu ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
Interface Reaction ◽  
Interfacial Instability ◽  
Anode Surface ◽  
Commercial Application ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Anode ◽  
Lithium Sulfur

AbstractThe interfacial instability of the lithium-metal anode and shuttling of lithium polysulfides in lithium-sulfur (Li-S) batteries hinder the commercial application. Herein, we report a bifunctional electrolyte additive, i.e., 1,3,5-benzenetrithiol (BTT), which is used to construct solid-electrolyte interfaces (SEIs) on both electrodes from in situ organothiol transformation. BTT reacts with lithium metal to form lithium 1,3,5-benzenetrithiolate depositing on the anode surface, enabling reversible lithium deposition/stripping. BTT also reacts with sulfur to form an oligomer/polymer SEI covering the cathode surface, reducing the dissolution and shuttling of lithium polysulfides. The Li–S cell with BTT delivers a specific discharge capacity of 1,239 mAh g−1 (based on sulfur), and high cycling stability of over 300 cycles at 1C rate. A Li–S pouch cell with BTT is also evaluated to prove the concept. This study constructs an ingenious interface reaction based on bond chemistry, aiming to solve the inherent problems of Li–S batteries.

Dendrite-free lithium–metal batteries at high rate realized using a composite solid electrolyte with an ester–PO4 complex and stable interphase

2019 ◽  
Vol 7 (40) ◽  
pp. 23173-23181 ◽  
Author(s):  
Zhaoshuai Zhang ◽  
Long Zhang ◽  
Yanyan Liu ◽  
Tingting Yang ◽  
Zhiwen Wang ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
Coulombic Efficiency ◽  
Rate Capability ◽  
High Rate ◽  
Lithium Metal ◽  
Galvanostatic Cycling ◽  
Lithium Metal Batteries ◽  
Composite Solid Electrolyte ◽  
Composite Solid

PO43−–ester interactions realize dendrite-free Li deposition in PCL–LAGP, evidenced by galvanostatic cycling and in situ TEM observations. The corresponding battery achieves high coulombic efficiency ∼100% and a rate capability ≥10C.

An in situ photopolymerized composite solid electrolyte from halloysite nanotubes and comb-like polycaprolactone for high voltage lithium metal batteries

2021 ◽  
Vol 9 (15) ◽  
pp. 9826-9836
Author(s):  
Hongli Xu ◽  
Wei Ye ◽  
Qingrong Wang ◽  
Bing Han ◽  
Jun Wang ◽  
...  
Keyword(s):  
Solid Electrolyte ◽  
High Voltage ◽  
Halloysite Nanotubes ◽  
Lithium Metal ◽  
Lithium Metal Batteries ◽  
Composite Solid Electrolyte ◽  
Composite Solid

The HNT and comb-like PCL-based composite solid electrolyte enables LMBs with extremely stable cycling and high safety.

Stabilize lithium metal anode through in-situ forming a multi-component composite protective layer

2021 ◽  
pp. 129911
Author(s):  
Saisai Li ◽  
Yun Huang ◽  
Wenhao Ren ◽  
Xing Li ◽  
Mingshan Wang ◽  
...  
Keyword(s):  
Protective Layer ◽  
Lithium Metal ◽  
Metal Anode ◽  
In Situ Forming ◽  
Lithium Metal Anode
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