scholarly journals Electrochemical Oxidation of Sulphite in Neutral Media on Platinum Anode

Author(s):  
Andreea-Floriana Enache ◽  
Author(s):  
Mihaela-Alexandra Labosel ◽  
Delia-Andrada Duca ◽  
Nicolae Vaszilcsin ◽  
Mircea Laurentiu Dan

2008 ◽  
Vol 11 (2) ◽  
Author(s):  
Aida Kesraoui Abdessalem ◽  
Nihal Oturan ◽  
Nizar Bellakhal ◽  
Mohamed Dachraoui ◽  
Mehmet A. Oturan

AbstractThe mineralization of pesticides chlortoluron, carbofuran and bentazone aqueous solutions in acidic medium of pH 3 was studied by electro-Fenton process using a carbon felt cathode and a platinum anode. This advanced oxidation process allows the formation of hydroxyl radical (


2011 ◽  
Vol 47 (2) ◽  
pp. 234-237 ◽  
Author(s):  
M. D. Vedenyapina ◽  
A. O. Terent’ev ◽  
M. M. Platonov ◽  
A. M. Skundin ◽  
A. A. Vedenyapin ◽  
...  

1970 ◽  
Vol 9 (1) ◽  
pp. 53-59
Author(s):  
Sanjeev Kumar

In the present study, 5-substituted-2-amino-1,3,4-oxadiazoles (4a-k) have been synthesized by the electrochemical oxidation of semicarbazones (3a-k) using platinum anode at room temperature under controlled potential electrolysis in an undivided cell assembly. The structural assignment of these compounds (4a-k) has been made on the basis of elemental analysis, IR, 1H NMR and 13C NMR. The synthesized compounds were screened for their inhibiting activity against Klebsilla penumoniae, Escherichia coli, Bassilus subtilis and Streptococcus aureus and antifungal activity against Aspergillus niger and Crysosporium pannical and results have been compared with the standard antibacterial agents, Streptomycin and antifungal drug, Griseofulvin. The Compounds exhibited significant antibacterial activity and antifungal activity. Key words: Electrochemical oxidation; controlled potential; 5-substituted-2-amino-1,3,4-oxadiazole; semicarbazone; antimicrobial agents DOI: 10.3329/dujps.v9i1.7434 Dhaka Univ. J. Pharm. Sci. 9(1): 53-59 2010 (June)


Author(s):  
Yanyan Qin ◽  
Yanping Cui ◽  
Zhengwei Zhou ◽  
Ya Gao ◽  
Lidan Lei ◽  
...  

Abstract To explore the electrochemical conversion of arsenic at different voltages and pH, an open separated electrolytic cell with a platinum anode and a graphite cathode was selected for this paper. The form and concentration of arsenic in the anodic cell and cathodic cell were detected. Experimental results proved that at 40.0 V, As(III) in an acid electrolyte in the cathodic cell was firstly mainly reduced to AsH3 with trace As(0) as intermediate. As the electrolysis time arrived at 27 min, pH in the cathodic cell jumped suddenly from acidity to alkalinity, accompanied by the majority of the remaining As(III) converting to As(V) for an instant. As time went on, As(III) and As(V) remained almost unchanged at the ratio of 1:3, and the reduction of As(III) became extremely weak in the alkaline environment. When pH in the cathodic tank was adjusted to keep it acid, As(III) was eventually converted to AsH3. Compared with high voltage, at a low voltage of 1.0 V the cathode failed to achieve the potential of As(III) reduction and As(III) was eventually oxidized to As(V) in the acid catholyte. Electrochemical oxidation of As(III) in the open cathodic cell was likely caused by in-situ generation of peroxide from electrochemical reduction of O2. Theoretical support for electrochemical oxidation of As(III) on a carbon cathode in neutral and weak alkaline media is provided in this study.


2014 ◽  
Vol 272 ◽  
pp. 303-310 ◽  
Author(s):  
Rui Zhang ◽  
Weixin Lv ◽  
Guanghua Li ◽  
Mohammed Adnan Mezaal ◽  
Xiaojing Li ◽  
...  

1981 ◽  
Vol 46 (13) ◽  
pp. 3278-3284 ◽  
Author(s):  
Miroslav Janda ◽  
Jan Šrogl ◽  
Petr Holý

Electrochemical oxidation of 1-methylindole (I), 1,3-dimethylindole (II) and 1,2-dimethylindole (III) on a platinum anode in methanol, containing ammonium bromide, was studied. A more profound oxidation as compared with benzofuran or benzothiophene derivatives is indicated by the obtained products: 1-methyl-2,2-bis(1-methylindol-3-yl)-3-indolinone (IV), 1,1'-dimethyl-Δ3,3-biindolin-2,2'-dione (V), 3,3-dibromo-1-methyl-2-indolinone (VI), 3,3,5-tribromo-1-methyl-2-indolinone (VII), 3-bromo-1-methyl-2,3-indoledione (VIII), 3-methoxy-1,3-dimethyl-2-indolinone (IX), 3-hydroxy-1,3-dimethyl-2-indolinone (X), 3,5-dibromo-1,3-dimethyl-2-indolinone (XI) and 3-bromo-1,2-dimethylindole (XII). The ratio of the products can be significantly influenced by the electrolysis conditions. The oxidation takes place in positions 2 and 3 of the indole molecule, the position 2 influencing decisively the oxidation path.


THE BULLETIN ◽  
2019 ◽  
Vol 2 (378) ◽  
Author(s):  
Abduali Baeshov ◽  
Gulnar Aibolova ◽  
Elmira Tuleshova ◽  
M. A. Ozler

2014 ◽  
Vol 5 (3) ◽  
pp. 73-81 ◽  
Author(s):  
S. Durga ◽  
K. Ponmani ◽  
S. Kiruthika ◽  
B. Muthukumaran

Sign in / Sign up

Export Citation Format

Share Document