scholarly journals In situ-Mercury Film Electrode for Simultaneous Determination of Lead and Cadmium Using Nafion Coated New Coumarin Schiff Base as Chelating-Adsorbent

Author(s):  
Nelson Nuñez-Dallos ◽  
2013 ◽  
Vol 10 (4) ◽  
pp. 498-504 ◽  
Author(s):  
Lorena Martiniano ◽  
Joseany Almeida ◽  
Glene Cavalcante ◽  
Edmar Marques ◽  
Teresa Fonseca ◽  
...  

Fuel ◽  
2013 ◽  
Vol 103 ◽  
pp. 1164-1167 ◽  
Author(s):  
Lorena C. Martiniano ◽  
Vivia R. Abrantes ◽  
Sakae Y. Neto ◽  
Edmar P. Marques ◽  
Teresa C.O. Fonseca ◽  
...  

2004 ◽  
Vol 380 (1) ◽  
pp. 135-140 ◽  
Author(s):  
Marcelo Firmino de Oliveira ◽  
Adelir Aparecida Saczk ◽  
Leonardo Luiz Okumura ◽  
Andréa Pires Fernandes ◽  
Mercedes de Moraes ◽  
...  

2013 ◽  
Vol 11 (5) ◽  
pp. 736-741 ◽  
Author(s):  
Robert Piech ◽  
Beata Paczosa-Bator

AbstractThe renewable mercury film electrode, applied for the determination of papaverine traces using differential pulse adsorptive stripping voltammetry (DP AdSV) is presented. The calibration graph obtained for papaverine is linear from 1.25 nM (0.42 µg L−1) to 95 nM (32.2 µg L−1) for a preconcentration time of 60 s, with correlation coefficient of 0.998. For the renewable mercury electrode (Hg(Ag)FE) with a surface area of 9.1 mm2 the detection limit for a preconcentration time of 60 s is 0.7 nM (0.24 µg L−1). The repeatability of the method at a concentration level of the analyte as low as 17 µg L−1, expressed as RSD is 3.3% (n=5). The proposed method was successfully applied and validated by studying the recovery of papaverine from drugs, urine and synthetic solution.


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